Activation of inert metal components to catalysts
Processes for transforming an inert metal component into an active metal catalyst are provided. Apparatus and methods using active metal catalyst prepared according the process described herein are also provided.
1. A method of preparing a catalytic metal component, comprising;
constructing an inert metal component; wherein the inert metal component is constructed by additive manufacturing; and
exposing the inert metal component to a cyclic oxidative and reducing environment for a sufficient number of cycles to activate the inert metal component.
2. The method of claim 1 , wherein the metal component comprises a metal alloy.
3. The method of claim 2 , wherein the metal alloy comprises a Group 10 element.
4. The method of claim 3 , wherein the Group 10 element comprises one of nickel, platinum, and palladium.
5. The method of claim 2 , wherein the metal alloy is one of an Inconel, Hastelloy, and Monel variant.
6. The method of claim 1 , wherein the inert metal component has the geometry of one of a monolith, sphere, bead, pellet, extrudate, trilobe, quadralobe, cube, ring, 1-hole, 2-hole, 3-hole, 4-hole, saddle, cross-web, and wire mesh.
7. The method of claim 6 , wherein the inert metal component is a monolith.
8. The method of claim 1 , wherein the oxidative environment comprises at least one of oxygen, carbon dioxide, carbon monoxide, water, combustion byproducts, peroxide, ozone, permanganate, organic acids, halides, or combinations thereof.
9. The method of claim 1 , wherein the reducing environment comprises at least one of methane, ethane, propane, butane, ethylene, propylene, butylene, acetylene, methylacetylene-propadiene (MAPD), hydrogen, carbon monoxide, hydrides, hydrogen sulfide, or combinations thereof.
10. The method of claim 1 , wherein the exposing the metal monolith to a cyclic oxidative and reducing environment includes 5 to 300 cycles.
11. The method of claim 10 , wherein the exposing the metal monolith to a cyclic oxidative and reducing environment includes 20 to 250 cycles.
12. The method of claim 1 , wherein the reducing environment comprises steam and hydrocarbons.
13. The method of claim 12 , wherein the hydrocarbons comprise at least one of methane, ethane, propane, butane, gasoline, and whole crude.
14. The method of claim 1 , wherein the reducing environment comprises CO 2 and hydrocarbons.
15. The method of claim 1 , wherein the oxidative environment comprises O 2 .
16. The method of claim 1 , wherein the oxidative environment comprises O 2 and N 2 .