Thermoplastic compositions containing nanoscale-sized particle additives for laser direct structuring and methods for the manufacture and use thereof
This invention relates generally to a thermoplastic compositions and, more particularly, to compositions comprising a polymer matrix and comprising a filler composition. To that end, according to the aspects of the invention, a thermoplastic composition is disclosed that generally comprises a polymer matrix and at least one filler composition. The polymer matrix generally comprises at least one polycarbonate or polyamide. The filler composition generally comprises at least one laser direct structuring additive with a mean particle size of less than 1 μm and may additionally optionally comprise flame retardants, stabilizers and process aids.
1. A polymer composition for use in a laser direct structuring process comprising:
a first polycarbonate polymer;
a copper chromium oxide laser directed structuring additive; and,
an impact modifier component in an amount of from about 10 wt % to about 25 wt %;
wherein the laser direct structuring additive comprises a mean particle size of equal to or less than 1 μm in an amount of greater than 0 wt % to 15 wt %, and
wherein the impact modifier is acrylonitrile butadiene styrene (ABS), methacrylate butadiene styrene (MBS), polycarbonate-siloxane copolymer, or a combination thereof; and,
wherein the composition does not include titanium dioxide.
2. The polymer composition according to claim 1 , wherein the polymer composition further comprises a polycarbonate-polysiloxane copolymer.
3. The polymer composition according to any one of claims 1 - 2 , wherein the polymer composition further comprises a second polycarbonate polymer.
4. The polymer composition according to claim 3 , wherein the second polycarbonate polymer comprises a branched polycarbonate.
5. The polymer composition according to claim 1 , wherein the polymer composition further comprises a flame retardant additive.
6. The polymer composition according to claim 5 , wherein the flame retardant additive comprises BPADP or phosphazene, or a combination thereof.
7. The polymer composition according to claim 1 , wherein the polymer composition further comprises a reinforcing filler.
8. The polymer composition according to claim 7 , wherein the reinforcing filler comprises a glass fiber, a carbon fiber, or a mineral filler, or a combination thereof.
9. The polymer composition according to claim 1 , wherein the impact modifier component comprises one or more of an acrylonitrile butadiene styrene (“ABS”) copolymer, a methacrylate butadiene styrene (“MBS”) copolymer, and a bulk polymerized ABS (“BABS”) copolymer.
10. The polymer composition according to claim 9 , wherein the impact modifier component is the bulk polymerized ABS copolymer.
11. The polymer composition according to claim 10 , wherein the bulk polymerized ABS copolymer is present in an amount from about 10 wt % to about 25 wt %.
12. The polymer composition according to claim 10 , wherein the bulk polymerized ABS copolymer has a butadiene content of from about 13 wt % to about 18 wt %.
13. The polymer composition according to claim 9 , wherein the impact modifier component is the methacrylate butadiene styrene copolymer.
14. The polymer composition according to claim 9 , wherein the impact modifier component is the acrylonitrile butadiene styrene copolymer.
15. A method for the manufacture of an article comprising
molding an article from the composition of claim 1 ,
exposing the LDS additive to a laser to form an activated area, and
plating a metal layer onto the activated area.
16. The method according to claim 15 , wherein the polymer composition further comprises a polycarbonate-polysiloxane copolymer.
17. The method according to claim 16 , wherein the polymer composition further comprises a second polycarbonate polymer.
18. The method according to claim 17 , wherein the second polycarbonate polymer comprises a branched polycarbonate.
19. The method according to claim 15 , wherein the polymer composition further comprises a second polycarbonate polymer.
20. The method according to claim 19 , wherein the second polycarbonate polymer comprises a branched polycarbonate.
21. The method according to claim 15 , wherein the polymer composition further comprises a flame retardant additive.
22. The method according to claim 21 , wherein the flame retardant additive comprises BPADP or phosphazene, or a combination thereof.
23. An article comprising
the polymer composition of claim 1 ,
a laser activated area, and
a metal layer plated on the laser activated area.
24. The polymer composition according to claim 1 , wherein the laser direct structuring additive consists of a copper chromium oxide.
25. The polymer composition according to claim 1 , wherein:
the first polycarbonate polymer is a bisphenol A polycarbonate, ranging in molecular weight from 15,000 to 40,000 on weight average molecular weight;
the polymer composition further comprises a second polycarbonate polymer, and wherein the second polycarbonate polymer is a branched polycarbonate polymer;
and,
the laser direct structuring additive comprises a mean particle size of equal to or less than 0.6 μm.