Protective coating for lithium-containing electrode and methods of making the same
Methods of removing a passivation layer on a lithium-containing electrode and preparing a protective coating on the lithium-containing electrode by applying a graphene source are provided herein. A lithium-containing electrode with the protective coating including graphene and lithium-containing electrochemical cells including the same are also provided herein.
1. A method for preparing a protective coating on an electrode having a first Li-containing surface comprising:
moving a graphene source along the first Li-containing surface of the electrode thereby:
(i) removing a passivation layer present on the first Li-containing surface of the electrode; and
(ii) forming a protective coating adjacent to at least a portion of the first Li-containing surface, wherein the protective coating comprises graphene and wherein the protective coating is bonded to the first Li-containing surface by non-covalent interactions;
wherein the protective coating is formed simultaneously as the passivation layer is removed;
wherein the graphene source is moved along the first Li-containing surface in at least one direction selected from the group consisting of a back and forth direction, a side to side direction, a horizontal direction, a diagonal direction, and a circular direction; and
wherein the graphene source is moved along the first Li-containing surface in the presence of an inert gas and at a pressure of about 100 Pa to about 15 MPa.
2. The method of claim 1 , wherein the protective coating has a thickness of about 0.4 nm to about 200 nm.
3. The method of claim 1 , wherein the graphene source is selected from the group consisting of graphite, a graphene nanoplate, a multilayer graphene, a graphene oxide, carbon black, and a combination thereof.
4. The method of claim 1 , wherein the graphene source is in a form of a paper, or a roll.
5. The method of claim 1 , wherein the passivation layer comprises lithium oxide, lithium carbonate, lithium nitride, lithium hydroxide, or a combination thereof.
6. The method of claim 1 , wherein the graphene source is moved along the first Li-containing surface at a temperature of about 15° C. to about 160° C.
7. The method of claim 1 , wherein Li atoms are not present within the protective coating prior to operation of the electrode.
8. The method of claim 1 , further comprising applying a polymer or polymer precursor to form a polymeric coating adjacent to at least a portion of the protective coating.
9. A method for preparing a protective coating on an electrode having a first Li-containing surface comprising:
moving a graphene source along the first Li-containing surface of the electrode thereby, wherein the graphene source is in a form of a paper or a roll:
(i) removing a passivation layer present on the first Li-containing surface of the electrode; and
(ii) forming a protective coating adjacent to at least a portion of the first Li-containing surface, wherein the protective coating comprises graphene, wherein the protective coating is bonded to the first Li-containing surface by non-covalent interactions, and wherein Li atoms are not present within the protective coating prior to operation of the Li-containing electrode;
wherein the protective coating is formed simultaneously as the passivation layer is removed;
wherein the graphene source is moved along the first Li-containing surface in at least one direction selected from the group consisting of a back and forth direction, a side to side direction, a horizontal direction, a diagonal direction, and a circular direction; and
wherein the graphene source is moved along the first Li-containing surface in the presence of an inert gas and at a pressure of about 100 Pa to about 15 MPa.