Sandwich gasification process for high-efficiency conversion of carbonaceous fuels to clean syngas with zero residual carbon discharge
The present invention discloses a gasifier and/or a gasification process that provides a long, uniform temperature zone in the gasifier, regardless of the particle size, chemical composition, and moisture content of the fuel by sandwiching a reduction zones between two oxidation zones. The gasifier and/or gasification process has a char that is more energy-dense and almost devoid of moisture that affords for an additional (or char) oxidation zone with a temperature that is higher than a first oxidation zone which is closer to a evaporation and devolatilization zone. As such, the additional (or char) oxidation zone contributes to augmenting the reduction zone temperature, thereby providing a favorable dual impact in improving syngas composition and near-complete conversion of the tar.
1. A mixed-mode gasification process comprising:
providing a gasifier having a fuel injection port, an ash or residue extraction port, an outer periphery, and at least the following zones: a first exothermic oxidation zone, a second exothermic oxidation zone, a third exothermic oxidation zone, a first endothermic reduction zone located directly next to and sandwiched between the first and second exothermic oxidation zones, and a second endothermic reduction zone located directly next to and sandwiched between the second and third exothermic oxidation zones, the first exothermic oxidation zone located on a side of the gasifier next to the fuel injection port and upstream from the first and second endothermic reduction zones, the second and third exothermic oxidation zones located on a side of the gasifier next to the ash or residue extraction port;
the process further comprising providing an annular space or chamber that extends around the outer periphery for receiving at least one fuel, wherein said annular space or chamber is located at the side of the gasifier next to the fuel injection port; wherein the at least one fuel is devolatilized in the annular space or chamber to form devolatilized products which are injected into the gasifier upstream of the first oxidation zone for further conversion with the help of an oxidizer or carrier gas, and wherein the process further comprises providing an evaporation and devolatilization zone located upstream of the first exothermic oxidation zone.
2. The process of claim 1 , wherein the second and third exothermic oxidation zones have a temperature that is higher than the first exothermic oxidation zone.
3. The process of claim 2 , wherein the gasifier further comprises at least two different gasification medium injection zones.
4. The process of claim 3 , further comprising providing at least two separate gasification medium.
5. The process of claim 4 , further comprising providing one or multiple fuel streams to the gasifier.
6. The process of claim 5 , further comprising devolatilizing the one or multiple fuel streams to form a char.
7. The process of claim 6 , further comprising providing a portion of the char to the second and third exothermic oxidation zones.
8. The process of claim 7 , further comprising providing one of the at least two separate gasification medium to the second and third exothermic oxidation zones to oxidize the char.
9. The process of claim 1 , wherein the evaporation and devolatilization zone is adjacent to the first exothermic oxidation zone.
10. The process of claim 1 , further comprising providing multiple lances to the first exothermic oxidation zone and providing multiple lances to a bottom section of the gasifier.
11. The process of claim 10 , wherein said lances provide an oxidizer, wherein multiple sandwiching zones are created, each sandwiching zone comprising an endothermic reduction zone located directly next to and sandwiched between two separate exothermic oxidation zones, and wherein said lances avoid fuel bridging and provide uniform oxidizer injection.
12. The process of claim 1 , further comprising providing one or more lances to the first exothermic oxidation zone and providing one or more lances to a bottom section of the gasifier.
13. The process of claim 12 , wherein said lances provide an oxidizer, wherein multiple sandwiching zones are created, each sandwiching zone comprising an endothermic reduction zone located directly next to and sandwiched between two separate exothermic oxidation zones.
14. The process of claim 13 , wherein said lances avoid fuel bridging and provide uniform oxidizer injection.