High thermal expansion glass composites and uses thereof
View Patent ↗The present invention relates to glass composites, including filled glass composites and uses thereof. In particular examples, the composites provide improved thermal expansion characteristics. Also described are methods of forming such composites, such as by adding a particle filler to a glass mixture.
1. A filled glass composite comprising:
from about 70 wt. % to about 90 wt. % of SiO 2 ;
from about 3 wt. % to about 14 wt. % of Li 2 O;
from about 0.8 wt. % to about 7 wt. % of Al 2 O 3 ;
from about 0.4 wt. % to about 7 wt. % of K 2 O;
from about 0.4 wt. % to about 5 wt. % of P 2 O 5 ;
from about 0.2 wt. % to about 7 wt. % of B 2 O 3 ; and
from about 0.1 wt. % to about 5 wt. % of ZnO;
wherein the composition further comprises of from about 2 wt. % to about 10 wt. % of the SiO 2 as a high quartz phase and about 2 wt. % to about 10 wt. % of the SiO 2 as a tridymite phase.
2. The composite of claim 1 , comprising:
from about 70 wt. % to about 90 wt. % of SiO 2 ;
from about 3 wt. % to about 10 wt. % of Li 2 O;
from about 0.8 wt. % to about 6 wt. % of Al 2 O 3 ;
from about 0.4 wt. % to about 6 wt. % of K 2 O;
from about 0.4 wt. % to about 4 wt. % of P 2 O 5 ;
from about 0.2 wt. % to about 5 wt. % of B 2 O 3 ; and
from about 0.1 wt. % to about 4 wt. % of ZnO.
3. The composite of claim 2 , comprising:
from about 80 wt. % to about 90 wt. % of SiO 2 ;
from about 5 wt. % to about 10 wt. % of Li 2 O;
from about 1.5 wt. % to about 3 wt. % of Al 2 O 3 ;
from about 1 wt. % to about 2 wt. % of K 2 O;
from about 1 wt. % to about 2 wt. % of P 2 O 5 ;
from about 0.5 wt. % to about 1 wt. % of B 2 O 3 ; and
from about 0.1 wt. % to about 2 wt. % of ZnO.
4. The composite of claim 1 , further comprising of from about 10 wt. % to about 35 wt. % of the SiO 2 as a cristobalite phase and/or of from about 3 wt. % to about 10 wt. % of the SiO 2 as a low quartz phase.
5. The composite of claim 1 , wherein a crystalline phase of the composite comprises of from about 0.5 wt % to about 5 wt. % in a Li 2 Si 2 O 5 form.
6. The composite of claim 1 , further comprising a coefficient of thermal expansion of from about 16 ppm/° C. to about 18 ppm/° C.
7. The composite of claim 1 , wherein the composite is provided as a glass-ceramic preform or a glass-ceramic seal.