IP Library Granted Patent US 10,865,134
Granted Patent B2
US 10,865,134 · App. 15/995,379 · Granted Dec 15, 2020

Glass

Inventors: Kensuke Nagai (Tokyo, JP); Tetsuya Nakashima (Tokyo, JP); Yutaka Kuroiwa (Tokyo, JP); Hiroyuki Hijiya (Tokyo, JP); Masamichi Tanida (Tokyo, JP); Akio Koike (Tokyo, JP); Manabu Nishizawa (Tokyo, JP); Kazuo Tsubota (Tokyo, JP); Toshihide Kurihara (Tokyo, JP); Hidemasa Torii (Tokyo, JP)
Assignees: AGC Inc.; TSUBOTA LABORATORY, INC.
C03C4/085C03C3/083C03C3/085C03C3/087C03C3/091C03C3/095G02B5/208C03C2204/00
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Quick Facts
Patent No.
US 10,865,134
App. No.
15/995,379
Granted
Dec 15, 2020
Kind
B2
Abstract

A wavelength-selective transmissive glass has a light transmittance T more than 315 nm and 400 nm or less at a wavelength of more than 315 nm and 400 nm or less represented by the formula shown below of 1% or more in terms of a plate thickness of 6 mm and a light transmittance T 315 nm or less at a wavelength of 315 nm or less represented by the formula shown below of 60% or less in terms of a plate thickness of 6 mm. A k is a weighting factor at a wavelength k (nm) for calculating T (light transmittance) defined in ISO-9050:2003, and T k is a transmittance at the wavelength k (nm) in terms of a plate thickness of 6 mm: T more than 315 nm and 400 nm or less =(Σ k=more than 315 400 A k ×T k )/(Σ k=more than 315 400 A k ) T 315 nm or less =(Σ k=300 315 A k ×T k )/(Σ k=300 315 A k ).

Claims (25)

1. A wavelength-selective transmissive glass, comprising, as represented by mass % based on oxides,

a total iron content represented by Fe 2 O 3 of from 0.04 to 0.15%, from 0.35 to 0.45% of CeO 2 , from 0 to 0.2% of TiO 2 , and from 0 to 0.2% of SnO 2 , wherein CeO 2 +3×TiO 2 +6×SnO 2 is from 0.41 to 0.5, and a value of Fe-Redox is from 25 to 65%,

wherein a glass matrix composition comprises from 60 to 80%, of SiO 2 , from 0 to 7%, of Al 2 O 3 , from 0 to 10% of MgO, from 4 to 20% of CaO, from 7 to 20% of Na 2 O, from 0 to 10% of K 2 O, and 0.5% or less of B 2 O 3 ,

having a light transmittance T more than 315 nm and 400 nm or less at a wavelength of from more than 315 nm to 400 nm represented by the following formula of 1% or more in terms of a plate thickness of 6 mm and a light transmittance T 315 nm or less at a wavelength of 315 nm or less represented by the following formula of 60% or less in terms of a plate thickness of 6 mm:

T more than 315 nm and 400 nm or less =(Σ k=more than 315 400 A k ×T k )/(Σ k=more than 315 400 A k )

T 315 nm or less =(Σ k=300 315 A k ×T k )/(Σ k=300 315 A k ),

wherein A k is a weighting factor at a wavelength k in nm for calculating T which is light transmittance defined in ISO-9050:2003, and T k is a transmittance at the wavelength k in nm in terms of a plate thickness of 6 mm, and

having a dominant wavelength Dw measured using light source A of 460 to 510 nm in terms of a plate thickness of 6 mm.

2. The wavelength-selective transmissive glass according to claim 1 , comprising, as represented by mass % based on oxides:

from 65 to 75% of SiO 2 , from 0 to 5% of Al 2 O 3 , from 0 to 6% of MgO, from 5 to 12% of CaO, from 10 to 16% of Na 2 O, from 0 to 3% of K 2 O as a glass matrix composition, and

wherein [MgOH+CaO] is from 5 to 15% and [Na 2 O+K 2 O] is from 10 to 16%.

3. The wavelength-selective transmissive glass according to claim 1 , wherein [MgO+CaO] is from 5 to 15%.

4. The wavelength-selective transmissive glass according to claim 1 , wherein [Na 2 O+K 2 O] is from 10 to 16%.

5. The wavelength-selective transmissive glass according to claim 1 , having the T more than 315 nm and 400 nm or less of from 18 to 70% in terms of a plate thickness of 6 mm and T 315 nm or less of 1% or less in terms of a plate thickness of 6 mm.

6. The wavelength-selective transmissive glass according to claim 5 , having the T more than 315 nm and 400 nm or less of from 50 to 68% in terms of a plate thickness of 6 mm and T 315 nm or less of 0.1% or less in terms of a plate thickness of 6 mm.

7. The wavelength-selective transmissive glass according to claim 1 , having a light transmittance T 360 to 400 nm at a wavelength of from 360 to 400 nm represented by the following formula of 1% or more in terms of a plate thickness of 6 mm:

T 360-400 nm =(Σ k=360 400 A k ×T k )/(Σ k=360 400 A k ),

wherein A k is a weighting factor at a wavelength k in nm for calculating light transmittance T defined in ISO-9050:2003, and T k is a transmittance at the wavelength k in nm in terms of a plate thickness of 6 mm.

8. The wavelength-selective transmissive glass according to claim 7 , having the T 360 to 400 nm of from 19 to 92% in terms of a plate thickness of 6 mm.

9. The wavelength-selective transmissive glass according to claim 8 , having the T 360 to 400 nm of from 70 to 90% in terms of a plate thickness of 6 mm.

10. The wavelength-selective transmissive glass according to claim 1 , having a light transmittance T 400 to 760 nm at a wavelength of from 400 to 760 nm represented by the following formula of 1% or more in terms of a plate thickness of 6 mm:

T 400-760 nm =(Σ k=400 760 A′ k ×T k )/(Σ k=400 760 A′ k ),

wherein A′ k is a weighting factor at a wavelength k in nm for calculating visible light transmittance using light source D65, T_D65 defined in ISO-9050:2003, and T k is a transmittance at the wavelength k in nm in terms of a plate thickness of 6 mm.

11. The wavelength-selective transmissive glass according to claim 10 , having the T 400 to 760 nm of from 40 to 92% in terms of a plate thickness of 6 mm.

12. The wavelength-selective transmissive glass according to claim 11 , having the T 400 to 760 nm of from 80 to 92% in terms of a plate thickness of 6 mm.

Assignments (2)
CHANGE OF NAME Recorded Sep 7, 2018
From: ASAHI GLASS COMPANY, LIMITED
To: AGC INC.
Reel/Frame 047278/0081 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 1, 2018
From: NAGAI, KENSUKE; NAKASHIMA, TETSUYA; KUROIWA, YUTAKA; HIJIYA, HIROYUKI; TANIDA, MASAMICHI; KOIKE, AKIO; NISHIZAWA, MANABU; TSUBOTA, KAZUO; KURIHARA, TOSHIHIDE; TORII, HIDEMASA
To: ASAHI GLASS COMPANY, LIMITED; TSUBOTA LABORATORY, INC.
Reel/Frame 045960/0442 →
Priority Claims (1)
JP 2015-235799 · Dec 2, 2015 · national
Continuity (2)
Continuation PCTJP2016085853 · Dec 2, 2016
Related Publication 20180297888A1 · Oct 18, 2018