Thermoelectric composite material comprising MXene and method for manufacturing the same
Disclosed is a thermoelectric composite material includes a thermoelectric material including crystal grains; and a MXene inserted at boundaries of the crystal grains consisting of the thermoelectric material. Accordingly, the thermoelectric composite material may have a reduced thermal conductivity and an increased electrical conductivity. Furthermore, mechanical properties of the thermoelectric composite material may be improved. Thus, the thermoelectric composite material may improve the thermoelectric ability of a thermoelectric module including the same. A method of manufacturing the thermoelectric composite material includes coating MXene on a surface of a thermoelectric material powder including crystal grains; and sintering the thermoelectric material powder coated with the MXene to form a sintered body including the MXene inserted at boundaries of the crystal grains consisting of the thermoelectric material.
1. A thermoelectric composite material, comprising:
a thermoelectric material comprising crystal grains; and
a MXene inserted at boundaries of the crystal grains consisting of the thermoelectric material.
2. The thermoelectric composite material of claim 1 , wherein the thermoelectric material includes a material selected from the group consisting of a chalcogenide, an antimonide, a silicide, a half-Heusler compound, an oxide, and combinations thereof.
3. The thermoelectric composite material of claim 1 , wherein the thermoelectric material includes a material selected from the group consisting of a Bi—Te compound, a Sb—Te compound, a Bi—Te—Se compound, a Bi—Sb—Te compound, a Bi—Sb—Te—Se compound, and combinations thereof.
4. The thermoelectric composite material of claim 1 , wherein the MXene is an inorganic compound having a two-dimensional shape and is represented by:
M n+1 X n ,
where M represents Ti, Zr, Hf, V, Cr, Mn, Sc, Mo, Nb, Ta or a combination thereof, X represents C, N or a combination thereof, and where n is a natural number of 1 to 3.
5. The thermoelectric composite material of claim 1 , wherein the MXene forms a continuous thin film surrounding the crystal grains.
6. The thermoelectric composite material of claim 1 , wherein the MXene is irregularly disposed along the boundaries of the crystal grains.
7. A method of manufacturing a thermoelectric composite material, the method comprising:
coating MXene on a surface of a thermoelectric material powder comprising crystal grains; and
sintering the thermoelectric material powder coated with the MXene to form a sintered body including the MXene inserted at boundaries of the crystal grains consisting of the thermoelectric material.
8. The method of claim 7 , wherein the thermoelectric material powder includes a material selected from the group consisting of a chalcogenide, an antimonide, a silicide, a half-Heusler compound, an oxide, and combinations thereof.
9. The method of claim 7 , wherein the thermoelectric material powder includes a material selected from the group consisting of a Bi—Te compound, a Sb—Te compound, a Bi—Te—Se compound, a Bi—Sb—Te compound, a Bi—Sb—Te—Se compound, and combinations thereof.
10. The method of claim 7 , wherein the MXene is an inorganic compound having a two-dimensional shape and represented by:
M n+1 X n ,
where M represents Ti, Zr, Hf, V, Cr, Mn, Sc, Mo, Nb, Ta or a combination thereof, X represents C, N or a combination thereof, and n is a natural number of 1 to 3.
11. The method of claim 7 , wherein coating the MXene on the surface of the thermoelectric material powder comprises:
mixing and stirring the thermoelectric material powder, the MXene and a solvent to provide a mixture; and
drying the mixture.
12. The method of claim 11 , wherein the solvent includes an alcohol-based solvent.
13. The method of claim 11 , wherein a content of the MXene is present in an amount ranging from 0.01% by weight to 1% by weight based on total weight of the thermoelectric material powder and the MXene.