Solid herbicide compositions containing fluroxypyr-meptyl
The present disclosure concerns herbicide granules and powders containing a high-load of fluroxypyr-meptyl. The granules exhibit good storage stability and good herbicidal efficacy when added to water and applied by spray application to control unwanted plant growth.
1. A coated herbicide powder comprising crystalline particles of fluroxypyr-meptyl coated with a mixture of surfactants comprising:
a) a water soluble nonionic surfactant comprising a polyvinyl alcohol; and
b) a water soluble anionic surfactant comprising a lignosulfonate salt;
wherein;
the coated herbicide powder comprises from about 350 grams active ingredient per kilogram (gai/kg) to about 800 gai/kg of fluroxypyr-meptyl;
the coated herbicide powder comprises from about 1 g/kg to about 100 g/kg of the water soluble nonionic surfactant;
the coated herbicide powder comprises from about 10 g/kg to about 600 g/kg of water soluble nonionic surfactant;
the fluroxypyr-meptyl has a degree of crystallinity of at least 80 percent; and
the coated herbicidal powder does not contain sulfoxaflor or chlorpyrifos.
2. The powder of claim 1 comprising from about 500 gai/kg to about 700 gai/kg of fluroxypyr-meptyl.
3. The powder of claim 1 comprising from about 600 gai/kg to about 700 gai/kg of fluroxypyr-meptyl.
4. The powder of claim 1 , wherein the water soluble nonionic surfactant is a polyvinyl alcohol with a degree of hydrolysis from about 87% to about 99%.
5. The powder of claim 4 in which the polyvinyl alcohol has a degree of hydrolysis from about 87% to about 89%.
6. The powder of claim 1 comprising from about 10 g/kg to about 50 g/kg of the water soluble nonionic surfactant.
7. The powder of claim 1 , wherein the water soluble anionic surfactant is a lignosulfonate salt selected from a sodium lignosulfonate and/or a calcium lignosulfonate.
8. The powder of claim 1 comprising from about 50 g/kg to about 500 g/kg of the water soluble anionic surfactant.
9. The powder of claim 1 comprising from about 100 g/kg to about 400 g/kg of the water soluble anionic surfactant.
10. The powder of claim 1 in which the fluroxypyr-meptyl has a degree of crystallinity of at least 90 percent.
11. The powder of claim 1 in which the fluroxypyr-meptyl has a degree of crystallinity of at least 95 percent.
12. The powder of claim 1 further comprising one or more additional inert ingredients.
13. A high-load, herbicide granule which comprises:
a) crystalline particles of fluroxypyr-meptyl coated with a mixture comprising:
i. a water soluble nonionic surfactant comprising a polyvinyl alcohol; and
ii. a water soluble anionic surfactant comprising a lignosulfonate salt; and
b) particle agglomeration suppressant;
wherein;
the herbicide granule comprises from about 350 grams active ingredient per kilogram (gai/kg) to about 700 gai/kg of fluroxypyr-meptyl;
the herbicide granule comprises from about 1 g/kg to about 100 g/kg of the water soluble nonionic surfactant;
the herbicide granule comprise from about 10 g/kg to about 600 g/kg of the water soluble anionic surfactant;
the fluroxypyr-meptyl has a degree of crystallinity of at least 80 percent; and
the herbicide granule does not contain sulfoxaflor or chlorpyrifos.
14. The granule of claim 13 in which the herbicide granule is a water dispersible granule.
15. The granule of claim 13 comprising from about 350 gai/kg to about 600 gai/kg of fluroxypyr-meptyl.
16. The granule of claim 13 comprising from about 400 gai/kg to about 550 gai/kg of fluroxypyr-meptyl.
17. The granule of claim 13 , wherein the water soluble nonionic surfactant is a polyvinyl alcohol with a degree of hydrolysis from about 87% to about 99%.
18. The granule of claim 17 in which the polyvinyl alcohol has a degree of hydrolysis from about 87% to about 89%.
19. The granule of claim 13 comprising from about 10 g/kg to about 50 g/kg of the water soluble nonionic surfactant.
20. The granule of claim 13 , wherein the water soluble anionic surfactant is a lignosulfonate salt selected from a sodium lignosulfonate and/or a calcium lignosulfonate.
21. The granule of claim 13 comprising from about 50 g/kg to about 500 g/kg of the water soluble anionic surfactant.
22. The granule of claim 13 comprising from about 100 g/kg to about 400 g/kg of the water soluble anionic surfactant.
23. The granule of claim 13 , wherein the particle agglomeration suppressant is an ionic compound selected from the group including an inorganic salt of an inorganic acid, an inorganic salt of an organic acid, and a nitrogen-containing compound such as a nitrogen fertilizer.
24. The granule of claim 23 in which the particle agglomeration suppressant is selected from the group including ammonium sulfate, ammonium nitrate, and potassium chloride.
25. The granule of claim 13 , wherein the particle agglomeration suppressant is in an amount from about 20 g/kg to about 300 g/kg.
26. The granule of claim 25 comprising from about 20 g/kg to about 200 g/kg of the particle agglomeration suppressant.
27. The granule of claim 25 comprising from about 50 g/kg to about 150 g/kg of the particle agglomeration suppressant.
28. The granule of claim 13 further comprising one or more additional inert ingredients.
29. The granule of claim 13 in which the fluroxypyr-meptyl has a degree of crystallinity of at least 90 percent.
30. The granule of claim 13 in which the fluroxypyr-meptyl has a degree of crystallinity of at least 95 percent.
31. A high-load, herbicide granule obtainable by a process comprising:
a) drying an oil-in-water emulsion comprising molten fluroxypyr-meptyl, a water soluble nonionic surfactant comprising a polyvinyl alcohol and a water soluble anionic surfactant comprising a lignosulfonate salt, to provide a coated herbicide powder comprising crystalline particles of fluroxypyr-meptyl coated with a mixture of the nonionic surfactant and the anionic surfactant, or
dry-milling a solid mixture comprising fluroxypyr-meptyl, a water soluble anionic surfactant, a particle agglomeration suppressant, and, optionally, a water soluble nonionic surfactant, to provide a dry-milled herbicide powder;
b) adding a particle agglomeration suppressant to the coated herbicide powder prepared in step a); and
c) granulating the dry-milled herbicide powder prepared in step a) or the powder prepared in step b), and water
wherein;
the water soluble nonionic surfactant, if not added to the dry milled herbicide powder in a step a), is added to the dry-milled herbicide powder as a solution in water is step c);
the herbicide granule comprises from about 350 grams active ingredient per kilogram (gai/kg) to about 700 gai/kg of fluroxypyr-meptyl;
the herbicide granule comprises from about 1 g/kg to about 100 g/kg of the water soluble nonionic surfactant;
the herbicide granule comprises from about 10 g/kg to about 600 g/kg of the water soluble anionic surfactant;
the fluroxypyr-meptyl has a degree of crystallinity of at least 80 percent; and
the herbicide granule does not contain sulfoxaflor or chlorpyrifos.
32. The granule of claim 31 in which the high-load herbicide granule is a water dispersible granule.
33. The granule of claim 31 comprising from about 350 gai/kg to about 600 gai/kg of fluroxypyr-meptyl.
34. The granule of claim 33 comprising from about 400 gai/kg to about 550 gai/kg of fluroxypyr-meptyl.
35. The granule of claim 31 , wherein the water soluble nonionic surfactant is a polyvinyl alcohol with a degree of hydrolysis from about 87% to about 99%.
36. The granule of claim 35 in which the polyvinyl alcohol has a degree of hydrolysis from about 87% to about 89%.
37. The granule of claim 31 comprising from about 10 g/kg to about 50 g/kg of the water soluble nonionic surfactant.
38. The granule of claim 31 , wherein the water soluble anionic surfactant is a lignosulfonate salt selected from a sodium lignosulfonate and/or a calcium lignosulfonate.
39. The granule of claim 31 comprising from about 50 g/kg to about 500 g/kg of the water soluble anionic surfactant.
40. The granule of claim 31 comprising from about 100 g/kg to about 400 g/kg of the water soluble anionic surfactant.
41. The granule of claim 31 , wherein the particle agglomeration suppressant is an ionic compound selected from the group including an inorganic salt of an inorganic acid, an inorganic salt of an organic acid, and a nitrogen-containing compound such as a nitrogen fertilizer.
42. The granule of claim 41 in which the particle agglomeration suppressant is selected from the group including ammonium sulfate, ammonium nitrate, and potassium chloride.
43. The granule of claim 41 comprising from about 20 g/kg to about 300 g/kg of the particle agglomeration suppressant.
44. The granule of claim 43 comprising from about 20 g/kg to about 200 g/kg of the particle agglomeration suppressant.
45. The granule of claim 43 comprising from about 50 g/kg to about 150 g/kg of the particle agglomeration suppressant.
46. The granule of claim 31 further comprising one or more additional inert ingredients.
47. The granule of claim 31 in which the fluroxypyr-meptyl has a degree of crystallinity of at least 90 percent.
48. The granule of claim 31 in which the fluroxypyr-meptyl has a degree of crystallinity of at least 95 percent.
49. A method of controlling undesirable vegetation comprising applying to the vegetation or an area adjacent to the vegetation, or applying to the soil to prevent the emergence of the vegetation, a herbicidally effective amount of a spray solution in water containing the granule of claim 13 .
50. A method of preparing the coated herbicide powder of claim 1 comprising:
a) preparing a heated oil phase containing molten fluroxypyr-meptyl;
b) preparing a heated aqueous containing the water soluble nonionic surfactant and the water soluble anionic surfactant;
c) adding the heated, liquid oil phase prepared in step a) to the heated aqueous phase prepared in step b) under high shear homogenization to provide a microemulsion; and
d) drying the microemulsion prepared in step c) to provide the coated herbicide powder.
51. A method of preparing the high-load herbicide granule of claim 31 comprising crystalline particles of fluroxypyr-meptyl coated with a mixture comprising: a water soluble nonionic surfactant; and a water soluble anionic surfactant and a particle agglomeration suppressant, comprising:
a) mixing the dry-milled herbicide powder of claim 31 with one or more inert ingredients to provide a second herbicide powder;
b) adding water with mixing to the second herbicide powder prepared in step a) to provide a wetted powder or dough;
c) granulating the wetted powder or dough prepared in step b) by extrusion to provide wet granules; and
d) drying the wet granules prepared in step c) to provide the high-load, herbicide granule.
52. A method of preparing the high-load herbicide granule of claim 13 comprising:
a) providing a coated herbicide powder of comprising crystalline particles of fluroxypyr-meptyl coated with a mixture of surfactants comprising:
a water soluble nonionic surfactant comprising a polyvinyl alcohol; and
a water soluble anionic surfactant comprising a lignosulfonate salt;
wherein;
the coated herbicide powder comprises from about 350 grams active ingredient per kilogram (gai/kg) to about 800 gai/kg of fluroxypyr-meptyl;
the herbicide granule comprises from about 1 g/kg t about 100 g/kg of the water soluble nonionic surfactant;
the herbicide granule comprises from about 10 g/kg to about 600 g/kg of the water soluble anionic surfactant;
the fluroxypyr-meptyl has a degree of crystallinity of at least 80 percent; and
the herbicide granule does not contain sulfoxaflor or chlorpyrifos;
b) mixing the coated herbicide powder of step a) with one or more inert ingredients to provide a second herbicide powder;
c) adding water with mixing to the second herbicide powder prepared in step b) to provide a wetted powder or dough;
d) granulating the wetted powder or dough prepared in step c) by extrusion to provide wet granules; and
e) drying the wet granules prepared in step d) to provide the high-load, herbicide granule.