Increased resonant frequency potassium-doped hexagonal ferrite
Disclosed herein are embodiments of an enhanced resonant frequency hexagonal ferrite material and methods of manufacturing. The hexagonal ferrite material can be Y-phase strontium hexagonal ferrite material. In some embodiments, strontium can be substituted out for a trivalent or tetravalent ion composition including potassium, thereby providing for advantageous properties.
1. A method of doping a Y-phase hexagonal ferrite material, the method comprising:
identifying a Y-phase hexagonal ferrite material having a composition Sr 2 Co 2x Fe 12 O 22 ;
substituting at least some strontium of the Y-phase hexagonal ferrite material with potassium; and
substituting at least some cobalt of the Y-phase hexagonal ferrite material with a trivalent ion, the substituting of the potassium and the trivalent ion forming a doped Y-phase hexagonal ferrite material having a composition Sr 2-x K x Co 2-x M x Fe 12 O 22 , M being the trivalent ion and the value of x being 0<x≤1.5.
2. The method of claim 1 wherein M is selected from the group consisting of Sc, Mn, In, Cr, Ga, Co, Ni, Fe, Yb, and any of the lanthanide ions.
3. The method of claim 1 wherein 0.2<x<0.7.
4. The method of claim 1 wherein the potassium comes from potassium carbonate.
5. The method of claim 1 wherein the doped Y-phase hexagonal material has a composition of Sr 1.75 K 0.25 Co 1.75 Sc 0.25 Fe 12 O 22 .
6. The method of claim 5 wherein a loss factor of the doped Y-phase hexagonal material is below 0.5 at 1 GHz.
7. The method of claim 5 wherein a permeability of the doped Y-phase hexagonal material is greater than 3.
8. The method of claim 1 wherein the doped Y-phase hexagonal material has a composition of Sr 1.75 K 0.5 Co 1.5 Sc 0.5 Fe 12 O 22 .
9. The method of claim 1 wherein the doped Y-phase hexagonal material has a composition of Sr 1.75 K 0.25 Co 1.75 In 0.25 Fe 12 O 22 .
10. The method of claim 9 wherein a loss factor of the doped Y-phase hexagonal material is below 0.5 at 1 GHz.
11. The method of claim 9 wherein a permeability of the doped Y-phase hexagonal material is greater than 3.
12. The method of claim 1 wherein the doped Y-phase hexagonal material has a composition of Sr 1.5 K 0.5 Co 1.5 In 0.5 Fe 12 O 22 .
13. The method of claim 1 wherein the doped Y-phase hexagonal material has a loss factor of approximately 1 at 1 GHz.
14. A method of doping a Y-phase hexagonal ferrite material, the method comprising:
identifying a Y-phase hexagonal ferrite material having a composition Sr 2 Co 2 Fe 12 O 22 ;
substituting at least some strontium of the Y-phase hexagonal ferrite material with potassium; and
substituting at least some cobalt of the Y-phase hexagonal ferrite material with a tetravalent ion, the substituting of the potassium and the tetravalent ion forming a doped Y-phase hexagonal ferrite material having a composition Sr 2-2x K 2x Co 2-x N x Fe 12 O 22 , N being the tetravalent ion and the value of x being 0<x≤0.75.
15. The method of claim 14 wherein N is selected from the group consisting of Si, Ge, Ti, Zr, Sn, Ce, Pr, Hf, and Tb.
16. The method of claim 14 wherein N is Ge.
17. The method of claim 14 wherein 0.2<x<0.5.
18. The method of claim 14 wherein the potassium comes from potassium carbonate.