Non-noble metal based electro-catalyst compositions for proton exchange membrane based water electrolysis and methods of making
The invention provides electro-catalyst compositions for an anode electrode of an acid mediated proton exchange membrane-based water electrolysis system. The compositions include a noble metal component selected from the group consisting of iridium oxide, ruthenium oxide, rhenium oxide and mixtures thereof, and a non-noble metal component selected from the group consisting of tantalum oxide, tin oxide, niobium oxide, titanium oxide, tungsten oxide, molybdenum oxide, yttrium oxide, scandium oxide, cooper oxide, zirconium oxide, nickel oxide and mixtures thereof. Further, the non-noble metal component can include a dopant. The dopant can be at least one element selected from Groups III, V, VI and VII of the Periodic Table. The compositions can be prepared using any solution based methods involving a surfactant approach or a sol gel approach. Further, the compositions are prepared using noble metal and non-noble metal precursors. Furthermore, a thin film containing the compositions can be deposited onto a substrate to form the anode electrode.
1. An electro-catalyst composition for an anode electrode of a proton exchange membrane-based water electrolysis system, comprising:
a noble metal component of iridium oxide;
a non-noble metal component selected from the group consisting of tantalum oxide, tin oxide, niobium oxide, titanium oxide, tungsten oxide, molybdenum oxide, yttrium oxide, scandium oxide, copper oxide, zirconium oxide, nickel oxide and mixtures thereof;
optionally, a dopant; and
the electro-catalyst composition having one of the following general formulas:
Ir 1-2x Sn x M x O 2 and Ir 1-2x Sn x M x O 2 :D,
wherein M represents Nb, Ta, Ti, W, Mo, Y, Sc, Cu, Zr, Ni and mixtures thereof, D represents at least one element of Groups III, V, VI and VII of the Periodic Table, and x is a value from greater than 0 to 49.5% based on weight of the composition,
wherein the electro-catalyst composition is in a form selected from an oxide alloy and a solid solution, and
wherein the electro-catalyst composition exhibits an electronic structure that mimics a noble metal oxide electro-catalyst composition absent of a non-noble metal.
2. The composition of claim 1 , wherein the dopant is selected from the group consisting of fluorine, chlorine, bromine, iodine, sulfur, selenium, tellurium and mixtures thereof.
3. The composition of claim 1 , wherein the dopant is present in an amount from greater than 0 to 20 weight percent based on weight of the composition.
4. The composition of claim 1 , wherein the non-noble metal component and the noble metal component form a complete solid solution.
5. The composition of claim 1 , wherein the composition is in the form of a nanocrystalline thin film, nanorods, nanoplates, nanoshells, nanoflakes, nanorods, nanospheres, or any nano-scale morphology coated on a current collector substrate.