IP Library Granted Patent US 11,117,091
Granted Patent B2
US 11,117,091 · App. 16/036,411 · Granted Sep 14, 2021

Separation of a target substance from a fluid or mixture using encapsulated sorbents

Inventors: Roger D. Aines (Livermore, CA); Christopher M. Spadaccini (Oakland, CA); Joshuah K. Stolaroff (Oakland, CA); William L. Bourcier (Livermore, CA); Jennifer A. Lewis (Cambridge, MA); Eric B. Duoss (Dublin, CA); John J. Vericella (Oakland, CA)
Assignees: Lawrence Livermore National Security, LLC; The Board of Trustees of the University of Illinois
B01D53/1475B01D53/1425B01D53/1456B01D53/1468B01D53/1481B01D53/229B01J20/324B01J20/327B01J20/3244B01J20/3295B01D2252/102B01D2252/20421B01D2252/20426B01D2252/20431B01D2252/20484B01D2252/602B01D2258/0283Y02C20/10Y02C20/40
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Quick Facts
Patent No.
US 11,117,091
App. No.
16/036,411
Granted
Sep 14, 2021
Kind
B2
Abstract

Method and apparatus for separating a target substance from a fluid or mixture. Capsules having a coating and stripping solvents encapsulated in the capsules are provided. The coating is permeable to the target substance. The capsules having a coating and stripping solvents encapsulated in the capsules are exposed to the fluid or mixture. The target substance migrates through the coating and is taken up by the stripping solvents. The target substance is separated from the fluid or mixture by driving off the target substance from the capsules.

Claims (13)

1. A capsule for separating carbon dioxide, nitrous oxides, sulfites, or hydrogen sulfide

from a fluid or mixture, comprising:

a capsule body,

a surface layer on said capsule body that is permeable to carbon dioxide, nitrous oxides, sulfites, or hydrogen sulfide,

stripping solvents encapsulated within said capsule body, wherein said stripping solvents are soluble to carbon dioxide, nitrous oxides, sulfites, or hydrogen sulfide and wherein carbon dioxide, nitrous oxides, sulfites, or hydrogen sulfide migrates through said surface layer and is taken up by said stripping solvents separating carbon dioxide, nitrous oxides, sulfites, or hydrogen sulfide from the fluid or mixture, and

a catalyst or enzyme layer between said surface layer and said stripping solvents.

2. The capsule for separating carbon dioxide, nitrous oxides, sulfites, or hydrogen sulfide from a fluid or mixture of claim 1 wherein said surface layer is a surface layer of that includes carbon nanotubes.

3. The capsule for separating carbon dioxide, nitrous oxides, sulfites, or hydrogen sulfide from a fluid or mixture of claim 1 wherein said stripping solvents are primary, secondary, tertiary, and hindered amines, caustic solutions, ionic buffer solutions, ammonia, or other solvents having solubility of carbon dioxide.

4. The capsule for separating carbon dioxide, nitrous oxides, sulfites, or hydrogen sulfide from a fluid or mixture of claim 1 wherein said stripping solvents are amines.

5. The capsule for separating carbon dioxide, nitrous oxides, sulfites, or hydrogen sulfide from a fluid or mixture of claim 1 wherein said surface layer is made of a porous solid.

6. The capsule for separating carbon dioxide, nitrous oxides, sulfites, or hydrogen sulfide from a fluid or mixture of claim 1 wherein said surface layer includes carbon fibers.

7. The capsule for separating carbon dioxide, nitrous oxides, sulfites, or hydrogen sulfide from a fluid or mixture of claim 1 wherein said surface layer includes nanotubes.

8. The capsule for separating carbon dioxide, nitrous oxides, sulfites, or hydrogen sulfide from a fluid or mixture of claim 1 wherein said surface layer is made of polystyrene, polyethylene, polypropylene, or nylon.

Assignments (2)
CONFIRMATORY LICENSE (SEE DOCUMENT FOR DETAILS) Recorded Oct 7, 2020
From: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 053996/0648 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 16, 2018
From: AINES, ROGER D.; SPADACCINI, CHRISTOPHER M.; STOLAROFF, JOSHUAH K.; BOURCIER, WILLIAM L.; DUOSS, ERIC B.
To: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
Reel/Frame 046361/0539 →
Continuity (4)
Division 14341047 · Jul 25, 2014
Division 13312418 · Dec 6, 2011
Provisional Application 61444461 · Feb 18, 2011
Related Publication 20180318755A1 · Nov 8, 2018