Anion exchange resin, electrolyte membrane, binder for forming electrode catalyst layer, fuel cell electrode catalyst layer and fuel cell
An anion exchange resin capable of producing an electrolyte membrane, a binder for forming an electrode catalyst layer and a fuel cell electrode catalyst layer, which have improved electrical properties; an electrolyte membrane and a binder for forming an electrode catalyst layer produced from the anion exchange resin; and a fuel cell having the electrolyte membrane or the electrode catalyst layer.
1. An anion exchange resin, comprising:
a divalent hydrophobic group being composed of three or more aromatic rings which are connected to each other via carbon-carbon bond; and
a divalent hydrophilic group being composed of one aromatic ring, or being composed of a plurality of aromatic rings which are connected to each other via a linking group and/or carbon-carbon bond, wherein the linking group is a divalent hydrocarbon group, a divalent silicon-containing group, a divalent nitrogen-containing group, a divalent phosphorus-containing group, a divalent oxygen-containing group, or a divalent sulfur-containing group, and at least one of the linking group or the aromatic ring comprises an anion exchange group;
wherein the anion exchange resin comprises a hydrophobic unit being composed of the hydrophobic group alone, or being composed of a plurality of hydrophobic groups repeated via ether bond, thioether bond, or carbon-carbon bond;
wherein the anion exchange resin comprises a hydrophilic unit being composed of the hydrophilic group alone, or being composed of a plurality of hydrophilic groups repeated via ether bond, thioether bond, or carbon-carbon bond; and
wherein the hydrophobic unit and the hydrophilic unit are connected via ether bond, thioether bond, or carbon-carbon bond;
wherein the hydrophilic group comprises a linear oligophenylene group as shown in the following formula (2):
(In the formula, x represents an integer of 3 to 8).
2. The anion exchange resin according to claim 1 , wherein the hydrophilic group is composed of a plurality of aromatic rings which are connected to each other via a linking group and/or carbon-carbon bond, wherein the linking group is a divalent hydrocarbon group, a divalent silicon-containing group, a divalent nitrogen-containing group, a divalent phosphorus-containing group, a divalent oxygen-containing group, or a divalent sulfur-containing group, and at least one of the linking group or the aromatic ring is connected to an anion exchange group via a divalent saturated hydrocarbon group having a carbon number of 2 or more.
3. The anion exchange resin according to claim 2 , wherein the hydrophilic group comprises a fluorene residue as shown in the following formula (3a):
(In the formula, Ion and Ion′ are the same or different and represent an anion exchange group; and y and z are the same or different and represent an integer of 2 to 20).
4. An electrolyte membrane, comprising the anion exchange resin according to claim 1 .
5. A binder for forming an electrode catalyst layer, comprising the anion exchange resin according to claim 1 .
6. The anion exchange resin according to claim 1 , wherein the hydrophilic group is composed of a plurality of aromatic rings which are connected to each other via a linking group and/or carbon-carbon bond, wherein the linking group is a divalent hydrocarbon group, a divalent silicon-containing group, a divalent nitrogen-containing group, a divalent phosphorus-containing group, a divalent oxygen-containing group, or a divalent sulfur-containing group, and at least one of the linking group or the aromatic ring is connected to an anion exchange group via a divalent saturated hydrocarbon group having a carbon number of 2 or more.
7. The anion exchange resin according to claim 6 , wherein the hydrophilic group comprises a fluorene residue as shown in the following formula (3a).
(In the formula, Ion and Ion′ are the same or different and represent an anion exchange group; and y and z are the same or different and represent an integer of 2 to 20).
8. The electrolyte membrane according to claim 4 , wherein the hydrophilic group comprises a linear oligophenylene group as shown in the following formula (2).
(In the formula, x represents an integer of 3 to 8).
9. The electrolyte membrane according to claim 4 , wherein the hydrophilic group is composed of a plurality of aromatic rings which are connected to each other via a linking group and/or carbon-carbon bond, wherein the linking group is a divalent hydrocarbon group, a divalent silicon-containing group, a divalent nitrogen-containing group, a divalent phosphorus-containing group, a divalent oxygen-containing group, or a divalent sulfur-containing group, and at least one of the linking group or the aromatic ring is connected to an anion exchange group via a divalent saturated hydrocarbon group having a carbon number of 2 or more.
10. The electrolyte membrane according to claim 8 , wherein the hydrophilic group comprises a fluorene residue as shown in the following formula (3a):
(In the formula, Ion and Ion′ are the same or different and represent an anion exchange group; and y and z are the same or different and represent an integer of 2 to 20).
11. The binder for forming an electrode catalyst layer according to claim 5 , wherein the hydrophilic group comprises a linear oligophenylene group as shown in the following formula (2):
(In the formula, x represents an integer of 3 to 8).
12. The binder for forming an electrode catalyst layer according to claim 5 , wherein the hydrophilic group is composed of a plurality of aromatic rings which are connected to each other via a linking group and/or carbon-carbon bond, wherein the linking group is a divalent hydrocarbon group, a divalent silicon-containing group, a divalent nitrogen-containing group, a divalent phosphorus-containing group, a divalent oxygen-containing group, or a divalent sulfur-containing group, and at least one of the linking group or the aromatic ring is connected to an anion exchange group via a divalent saturated hydrocarbon group having a carbon number of 2 or more.
13. The binder for forming an electrode catalyst layer according to claim 12 , wherein the hydrophilic group comprises a fluorene residue as shown in the following formula (3a).
(In the formula, Ion and Ion′ are the same or different and represent an anion exchange group; and y and z are the same or different and represent an integer of 2 to 20).