Positive electrode material and lithium-ion battery
The examples of the present application provide a positive electrode material and a lithium-ion battery. The positive electrode material comprises: a substrate material; and a coating material formed on at least one part of a surface of the substrate material; the general formula of the substrate material being Li x Co y M 1-y O 2 , wherein 1.0≤x≤1.2, 0.8≤y≤1.0 and M is at least one selected from the group consisting of Mg, Ti, Al, Zr, Ni, Mn; the coating material includes Y 2 O 3 and at least two selected from the group consisting of La 2 O 3 , ZrO 2 and CeO 2 . The examples of the present application enable the battery prepared by the provided positive electrode material to have a lower storage expansion ratio, a higher capacity retention ratio, and improved cycle performance at a high charge cutoff voltage by the interaction of at least three kinds of oxides.
1. A positive electrode material, comprising:
a substrate material; and
a coating material formed on at least one part of a surface of the substrate material;
the general formula of the substrate material being Li x Co y M 1-y O 2 , wherein 1.0≤x≤1.2, 0.8≤y≤1.0 and M is at least one selected from the group consisting of Mg, Ti, Al, Zr, Ni, Mn;
the coating material includes Y 2 O 3 and at least two selected from the group consisting of La 2 O 3 , ZrO 2 and CeO 2 ,
wherein a solid solution is arranged between the substrate material and the coating material.
2. The positive electrode material according to claim 1 , wherein the general formula of the substrate material is LiCo y M 1-y O 2 , wherein 0.8≤y≤1.0 and M is at least one selected from the group consisting of Mg, Ti, Al, Zr and Ni.
3. The positive electrode material according to claim 1 , wherein the content of the element Y in the positive electrode material is 200 to 2000 ppm; the content of the element La in the positive electrode material is 0 to 3000 ppm; the content of the element Ce in the positive electrode material is 0 to 2000 ppm; the content of the element Zr in the positive electrode material is 0 to 2500 ppm.
4. The positive electrode material according to claim 1 , wherein the coating material comprises Y 2 O 3 , La 2 O 3 and ZrO 2 .
5. The positive electrode material according to claim 4 , wherein the content of the element Y in the positive electrode material is 200 to 2000 ppm, the content of the element La in the positive electrode material is 20 to 3000 ppm, the content of the element Zr in the positive electrode material is 20 to 2500 ppm.
6. The positive electrode material according to claim 1 , wherein the coating material comprises Y 2 O 3 , La 2 O 3 , ZrO 2 and CeO 2 .
7. The positive electrode material according to claim 1 , wherein the coating material comprises Y 2 O 3 , La 2 O 3 and ZrO 2 without CeO 2 ; the content of the element Y in the positive electrode material is 200 to 2000 ppm, the content of the element La in the positive electrode material is 20 to 3000 ppm, the content of the element Zr in the positive electrode material is 20 to 2500 ppm.
8. A positive electrode, comprising:
a positive current collector; and
a positive electrode material arranged on the positive current collector;
wherein the positive electrode material comprising:
a substrate material; and
a coating material formed on at least one part of a surface of the substrate material;
the general formula of the substrate material being Li x Co y M 1-y O 2 , wherein 1.0≤x≤1.2, 0.8≤y≤1.0 and M is at least one selected from the group consisting of Mg, Ti, Al, Zr, Ni, Mn;
the coating material includes Y 2 O 3 and at least two selected from the group consisting of La 2 O 3 , ZrO 2 and CeO 2 ,
wherein a solid solution is arranged between the substrate material and the coating material.
9. The positive electrode according to claim 8 , wherein the general formula of the substrate material is LiCo y M 1-y O 2 , wherein 0.8≤y<1.0 and M is at least one selected from the group consisting of Mg, Ti, Al, Zr and Ni.
10. The positive electrode according to claim 8 , wherein the content of the element Y in the positive electrode material is 200 to 2000 ppm; the content of the element La in the positive electrode material is 0 to 3000 ppm; the content of the element Ce in the positive electrode material is 0 to 2000 ppm; the content of the element Zr in the positive electrode material is 0 to 2500 ppm.
11. The positive electrode according to claim 10 , wherein the content of the element Y in the positive electrode material is 200 to 2000 ppm, the content of the element La in the positive electrode material is 20 to 3000 ppm, the content of the element Zr in the positive electrode material is 20 to 2500 ppm.
12. The positive electrode according to claim 8 , wherein the coating material comprises Y 2 O 3 , La 2 O 3 and ZrO 2 .
13. The positive electrode according to claim 8 , wherein the coating material comprises Y 2 O 3 , La 2 O 3 , ZrO 2 and CeO 2 .
14. The positive electrode according to claim 8 , wherein the coating material comprises Y 2 O 3 , La 2 O 3 and ZrO 2 without CeO 2 ; the content of the element Y in the positive electrode material is 200 to 2000 ppm, the content of the element La in the positive electrode material is 20 to 3000 ppm, the content of the element Zr in the positive electrode material is 20 to 2500 ppm.
15. A lithium-ion battery, characterized by comprising the positive electrode according to claim 8 .