IP Library › Granted Patent US 10,703,894
Granted Patent B2
US 10,703,894 · App. 16/059,285 · Granted Jul 7, 2020

Heat-resistant crosslinked resin formed body and method for producing the same, silane master batch, master batch mixture and formed body thereof, and heat-resistant product

Inventors: Masaki Nishiguchi (Tokyo, JP); Hidekazu Hara (Tokyo, JP); Arifumi Matsumura (Tokyo, JP)
Assignee: FURUKAWA ELECTRIC CO., LTD.
C08L27/06C08J3/005C08J3/247C08K3/013C08K3/2279C08K3/26C08K3/36C08K5/14C08K5/5419C08L11/00C08L15/02C08L27/08C08L101/00C08L101/04C09D127/06H01B3/006H01B3/443C08J2311/00C08J2323/28C08K2003/2224C08K2003/2227C08K2003/265C08L2203/202C08L2310/00C08L2312/08H01B7/28H01B7/29
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Quick Facts
Patent No.
US 10,703,894
App. No.
16/059,285
Granted
Jul 7, 2020
Kind
B2
Abstract

A method that has a step (a) of melt-kneading 0.003 to 0.3 part by mass of an organic peroxide, 0.5 to 400 parts by mass of an inorganic filler, and more than 2 parts by mass and 15.0 parts by mass or less of a silane coupling agent, with respect to 100 parts by mass of a resin containing a halogen-containing resin, at a temperature equal to or higher than a decomposition temperature of the organic peroxide, to prepare a silane master batch; a heat-resistant crosslinked resin formed body obtained by the method, a silane master batch, a mixture and a formed body thereof, and a heat-resistant product.

Claims (18)

1. A method for producing a heat-resistant crosslinked resin formed body, comprising:

(a) melt-kneading 0.003 to 0.3 part by mass of an organic peroxide, 0.5 to 400 parts by mass of an inorganic filler, and more than 2 parts by mass and 15.0 parts by mass or less of a silane coupling agent, with respect to 100 parts by mass of a resin containing a halogen-containing resin, at a temperature equal to or higher than a decomposition temperature of the organic peroxide, to prepare a silane master batch;

(b) mixing the silane master batch obtained in the step (a) with a silanol condensation catalyst, and then forming the resultant mixture; and

(c) bringing the formed body obtained in the step (b) into contact with moisture, to cause crosslinking.

2. The method for producing the heat-resistant crosslinked resin formed body described in claim 1 , wherein a content of the organic peroxide is 0.005 to 0.1 part by mass.

3. The method for producing the heat-resistant crosslinked resin formed body described in claim 1 , wherein a content of the silane coupling agent is 3 to 12.0 parts by mass.

4. The method for producing the heat-resistant crosslinked resin formed body described claim 1 , wherein a content of the silane coupling agent is 4 to 12.0 parts by mass.

5. The method for producing the heat-resistant crosslinked resin formed body described in claim 1 , wherein the silane coupling agent is vinyltrimethoxysilane or vinyltriethoxysilane.

6. The method for producing the heat-resistant crosslinked resin formed body described in claim 1 , wherein the inorganic filler is silica, aluminum hydroxide, magnesium hydroxide, calcium carbonate or antimony trioxide, or any combination of these.

7. The method for producing the heat-resistant crosslinked resin formed body described in claim 1 , wherein melt-kneading in the step (a) is performed by using an enclosed mixer.

8. A silane master batch for use in producing a master batch mixture prepared by mixing 0.003 to 0.3 part by mass of an organic peroxide, 0.5 to 400 parts by mass of an inorganic filler, and more than 2 parts by mass and 15.0 parts by mass or less of a silane coupling agent, with respect to 100 parts by mass of a resin containing a halogen-containing resin, and a silanol condensation catalyst,

wherein the silane master batch is obtained by melt-kneading all or part of the resin; the organic peroxide, the inorganic filler and the silane coupling agent, at a temperature equal to or higher than a decomposition temperature of the organic peroxide.

9. A master batch mixture, comprising the silane master batch described in claim 8 and a silanol condensation catalyst.

10. A formed body, formed by introducing the master batch mixture obtained by dry-blending the silane master batch described in claim 8 and a silanol condensation catalyst, into a forming machine.

11. A heat-resistant crosslinked resin formed body, produced according to the method for producing the heat-resistant crosslinked resin formed body described in claim 1 .

12. The heat-resistant crosslinked resin formed body described in claim 11 , formed by crosslinking the halogen-containing resin with the inorganic filler through a silanol bond.

13. A heat-resistant product, comprising the heat-resistant crosslinked resin formed body described in claim 11 .

14. The heat-resistant product described in claim 13 , wherein the heat-resistant crosslinked resin formed body is a coating of an electric wire or an optical fiber cable.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 9, 2018
From: NISHIGUCHI, MASAKI; HARA, HIDEKAZU; MATSUMURA, ARIFUMI
To: FURUKAWA ELECTRIC CO., LTD.
Reel/Frame 046596/0733 →
Priority Claims (1)
JP 2016-024489 · Feb 12, 2016 · national
Continuity (2)
Continuation PCTJP2017004944 · Feb 10, 2017
Related Publication 20180346702A1 · Dec 6, 2018