IP Library Granted Patent US 10,456,813
Granted Patent B1
US 10,456,813 · App. 16/061,689 · Granted Oct 29, 2019

Non-aqueous stripping composition and a method of stripping an organic coating from a substrate

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Quick Facts
Patent No.
US 10,456,813
App. No.
16/061,689
Granted
Oct 29, 2019
Kind
B1
Abstract

To achieve efficient stripping of organic coatings from sensitive substrate without affecting the substrate surface, a novel non-aqueous stripping composition and method are provided. The stripping composition comprises: A. at least one high-boiling solvent selected from the group, consisting of alcohols having general chemical formula R—OH, wherein R is a C 4 -C 30 hydrocarbon group, wherein the high-boiling solvent has a boiling point of at least 100° C.; B—at least one high-boiling co-solvent selected from the group, consisting of high-boiling glycols, glycol ethers and amine compounds, wherein the high-boiling co-solvent has a boiling point of at least 100° C.; and C—at least one pH-active agent either selected from the group, consisting of acid compounds or selected from the group, consisting of hydroxide compounds.

Claims (36)

1. A non-aqueous stripping composition, comprising:

A—at least one high-boiling solvent at a concentration from 70% by weight to 95% by weight selected from the group, consisting of alcohols having general chemical formula R—OH, wherein R is a C 4 -C 30 hydrocarbon group, wherein the high-boiling solvent has a boiling point of at least 100° C.;

B—at least one high-boiling co-solvent at a concentration from 2% by weight to 20% by weight selected from the group, consisting of high-boiling glycols, glycol ethers and amine compounds, wherein the high-boiling co-solvent has a boiling point of at least 100° C.; and

C—at least one pH-active agent at a concentration from 0.01% by weight to 5% by weight selected from the group, consisting of acid compounds or selected from the group, consisting of hydroxide compounds.

2. The stripping composition of claim 1 , wherein

B—the at least one high-boiling co-solvent is selected from the group, consisting of amine compounds, wherein the high-boiling co-solvent has a boiling point of at least 100° C.; and

C—at least one pH-active agent selected from the group, consisting of acid compounds or selected from the group, consisting of hydroxide compounds.

3. The stripping composition of claim 1 , wherein

B—the at least one high-boiling co-solvent is selected from the group, consisting of high-boiling glycols and glycol ethers, wherein the high-boiling co-solvent has a boiling point of at least 100° C.; and

C—at least one pH-active agent selected from the group, consisting of acid compounds.

4. The stripping composition of claim 1 , wherein the composition further comprises at least one surfactant.

5. The stripping composition of claim 4 , wherein the at least one surfactant is a non-ionic surfactant or a non-ionic/anionic surfactant mixture.

6. The stripping composition of claim 1 , wherein the at least one high-boiling solvent is a compound wherein R is arylalkyl.

7. The stripping composition of claim 1 , wherein the at least one high-boiling solvent is benzyl alcohol.

8. The stripping composition of claim 1 , wherein the at least one high-boiling co-solvent is a glycol ether or tertiary amine compound.

9. The stripping composition of claim 1 , wherein the at least one high-boiling co-solvent is a diethylene glycol ether or triethylene glycol ether or tetraethylene glycol ether.

10. The stripping composition of claim 1 , wherein the at least one high-boiling co-solvent is diethylene glycol butylether.

11. The stripping composition of claim 1 , wherein the at least one high-boiling co-solvent is triethanol amine.

12. The stripping composition of claim 1 , wherein the at least one pH-active agent is an organic acid.

13. The stripping composition of claim 1 , wherein the at least one pH-active agent is lactic acid.

14. The stripping composition of claim 1 , wherein the water content in the composition is less than 0.5% by weight.

15. A method of stripping an organic coating from a substrate, said method comprising the following method steps:

a—providing the non-aqueous stripping composition of claim 1 ;

b—bringing the substrate into contact with the stripping composition; and

c—removing the organic coating from the substrate, while the stripping composition is maintained at a stripping temperature which is from at least 30° C. to at most below the boiling point of any one of components which are comprised in the stripping composition.

16. The method of claim 15 , wherein the substrate is an aluminium, magnesium, zinc, stainless steel, or engineering plastics substrate.

17. The method of claim 15 , wherein the operation temperature of the stripping composition is from 65° C. to 85° C.

18. The method of claim 15 , wherein the substrate is coated with organic coatings selected from epoxy coatings, polyester coatings, polyurethane coatings, acrylic coatings, and powder coatings.

19. A method of stripping organic coatings selected from epoxy coatings, polyester coatings, polyurethane coatings, acrylic coatings, and powder coatings from a substrate made of steel, galvanized steel, zinc die-cast, wrought and die-cast aluminum alloys, brass, copper products, aluminum, aluminum die-cast products, brass, bronze, copper, titanium, magnesium, or a plated substrate, said method comprising the following method steps:

a—providing the non-aqueous stripping composition of claim 1 ;

b—bringing the substrate into contact with the stripping composition; and

c—removing the organic coating from the substrate, while the stripping composition is maintained at a stripping temperature which is from at least 30° C. to at most below the boiling point of any one of components which are comprised in the stripping composition.

20. A method of cleaning or stripping organic materials selected from grease and oils or mixture thereof from a substrate made of steel, galvanized steel, zinc die-cast, wrought and die-cast aluminum alloys, brass, copper products, aluminum, aluminum die-cast products, brass, bronze, copper, titanium, magnesium, or a plated substrate, said method comprising the following method steps:

a—providing the non-aqueous stripping composition of claim 1 ;

b—bringing the substrate into contact with the stripping composition; and

c—removing the grease and oils or mixture thereof from the substrate, while the stripping composition is maintained at a stripping temperature which is from at least 30° C. to at most below the boiling point of any one of components which are comprised in the stripping composition.

Assignments (3)
RELEASE OF SECURITY INTEREST Recorded Aug 18, 2022
From: GOLDMAN SACHS BANK USA, AS COLLATERAL AGENT
To: ATOTECH DEUTSCHLAND GMBH & CO. KG (F/K/A ATOTECH DEUTSCHLAND GMBH); ATOTECH USA, LLC
Reel/Frame 061521/0103 →
SECURITY INTEREST Recorded Mar 18, 2021
From: ATOTECH DEUTSCHLAND GMBH; ATOTECH USA, LLC
To: GOLDMAN SACHS BANK USA, AS COLLATERAL AGENT
Reel/Frame 055650/0093 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 13, 2018
From: JOSHI, NAYAN H.
To: ATOTECH DEUTSCHLAND GMBH
Reel/Frame 046066/0420 →