Infrared fluorescent coating compositions

1. A multi-layer coating comprising:

a first coating layer comprising a cured infrared reflective coating composition; and

a second coating layer overlaying at least a portion of the first coating layer, the second coating layer comprising a cured coating composition, wherein the coating composition comprises:

a film-forming resin;

an infrared reflective pigment; and

an infrared fluorescent pigment different from the infrared reflective pigment,

wherein the infrared fluorescent pigment comprises an alkaline earth copper silicate, Sr(La, Li)CuSi 4 Si 4 O 10 , Ba(La, Li)CuSi 4 O 10 , ruby, azurite (Cu 3 (CO 3 ) 2 (OH) 2 ), ploss blue, smalt, or a combination thereof, wherein the alkaline earth copper silicate is selected from the group consisting of Egyptian blue (CaCuSi 4 O 10 ), Han blue (BaCuSi 4 O 10 ), Han purple (BaCuSi 2 O 6 ), SrCuSi 4 O 10 , and combinations thereof,

wherein the infrared fluorescent pigment has an average particle size of from 100 nm to 10 microns,

wherein the coating composition is substantially free of infrared fluorescent pigments having an average particle size of more than 10 microns,

wherein the infrared reflective pigment reflects at a first wavelength and the infrared fluorescent pigment fluoresces at a second wavelength,

wherein the infrared reflective pigment does not substantially absorb the second wavelength,

wherein the balance of the coating composition is transparent at the first wavelength and the second wavelength, and

wherein, when the coating composition is cured to form a coating and exposed to the radiation comprising fluorescence-exciting radiation, the coating has an effective solar reflectance (ESR) of at least 0.25.

2. The multi-layer coating of claim 1 , wherein, when the coating composition is cured to form a coating and exposed to the radiation comprising fluorescence-exciting radiation, a temperature of the coating at a time (t 1 ) after being exposed to the radiation comprising fluorescence-exciting radiation is lower compared to the same coating exposed to the radiation comprising fluorescence-exciting radiation except without the infrared fluorescent pigment at the time (t 1 ) after being exposed to the radiation comprising fluorescence-exciting radiation.

3. The multi-layer coating of claim 1 , further comprising a colorant.

4. The multi-layer coating of claim 1 , wherein the radiation comprising fluorescence-exciting radiation is produced from sunlight, incandescent light, fluorescent light, xenon light, laser, LED light, or a combination thereof.

5. The multi-layer coating of claim 1 , wherein the infrared fluorescent pigment absorbs visible radiation.

6. The multi-layer coating of claim 1 , wherein the infrared fluorescent pigment absorbs visible radiation such that the coating composition exhibits a dark color.

7. The multi-layer coating of claim 1 , wherein the infrared reflective pigment and the infrared fluorescent pigment each comprise from 1 to 40 weight % of the coating composition, based on total solids weight of the coating composition.

8. The multi-layer coating of claim 1 , wherein the infrared fluorescent pigment fluoresces in the near-infrared region.

9. A substrate at least partially coated with the multi-layer coating of claim 1 .

10. The substrate of claim 9 , wherein the substrate comprises at least a portion of a building substrate.

11. The substrate of claim 10 , wherein the building substrate comprises at least a portion of an exterior panel, roofing material, or industrial substrate.

12. The substrate of claim 9 , wherein the substrate comprises a metallic or non-metallic portion.

13. A method of reducing the temperature of an article comprising:

applying a coating composition to at least a portion of a surface of an article, the coating composition comprising (i) a film-forming resin, (ii) an infrared reflective pigment, and (iii) an infrared fluorescent pigment different from the infrared reflective pigment; and

curing the coating composition to form a coating on the article,

wherein the infrared fluorescent pigment comprises an alkaline earth copper silicate, Sr(La, Li)CuSi 4 O 10 , Ba(La, Li)CuSi 4 O 10 , ruby, azurite (Cu 3 (CO 3 ) 2 (OH) 2 ), ploss blue, smalt, or some combination thereof, wherein the alkaline earth copper silicate is selected from the group consisting of Egyptian blue (CaCuSi 4 O 10 ), Han blue (BaCuSi 4 O 10 ), Han purple (BaCuSi 2 O 6 ), SrCuSi 4 O 10 , and combinations thereof,

wherein the infrared reflective pigment and the infrared fluorescent pigment each comprise from 1 to 40 weight % of the coating composition, based on total solids weight of the coating composition, wherein the infrared reflective pigment and the infrared fluorescent pigment are included in the coating composition in an effective amount such that, when the coating composition is cured to form a coating and exposed to the radiation comprising fluorescence-exciting radiation, the coating has an effective solar reflectance (ESR) of at least 0.25.

14. The method of claim 13 , wherein, when the coating composition is cured to form a coating and exposed to the radiation comprising fluorescence-exciting radiation, a temperature of the coating at a time (t 1 ) after being exposed to the radiation comprising fluorescence-exciting radiation is lower compared to the same coating exposed to the radiation comprising fluorescence-exciting radiation except without the infrared fluorescent pigment at the time (t 1 ) after being exposed to the radiation comprising fluorescence-exciting radiation.

15. The method of claim 13 , wherein the radiation comprising fluorescence-exciting radiation is produced from sunlight, incandescent light, fluorescent light, xenon light, laser, LED light, or a combination thereof.

16. The method of claim 13 , wherein the article comprises at least a portion of a building substrate.

17. The method of claim 16 , wherein the building substrate comprises at least a portion of an exterior panel, roofing material, or industrial substrate.