IP Library Granted Patent US 11,370,925
Granted Patent B2
US 11,370,925 · App. 16/067,537 · Granted Jun 28, 2022

Infrared fluorescent coatings

Inventors: Michael A. Zalich (Wexford, PA); Paul H. Berdahl (Walnut Creek, CA); Stuart D. Hellring (Pittsburgh, PA); William H. Retsch, Jr. (Allison Park, PA)
Assignee: PPG Industries Ohio, Inc.
C09D5/004B05D5/063B05D7/52B05D7/546C09D5/22C09D7/62C09D127/16C09K11/02C09K11/06C09K11/55C09K11/58C09K11/59C09K11/592C09K11/685G01N21/6428C08K3/013C08K5/0041G01N2021/6439
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Quick Facts
Patent No.
US 11,370,925
App. No.
16/067,537
Granted
Jun 28, 2022
Kind
B2
Abstract

A coating composition includes: (i) a film-forming resin; (ii) an infrared reflective pigment; and (iii) an infrared fluorescent pigment or dye different from the infrared reflective pigment. A multi-layer coating including the coating composition, and a substrate at least partially coated with the coating composition is also disclosed. A method of detecting an article at least partially coated with the coating composition is also disclosed.

Claims (28)

1. A coating composition comprising:

a film-forming resin;

an infrared reflective pigment; and

an infrared fluorescent pigment or dye different from the infrared reflective pigment,

wherein the coating composition, when cured to form a coating and exposed to radiation comprising fluorescence-exciting radiation, emits fluorescence in the infrared spectrum, and

wherein the fluorescence emitted by the infrared fluorescent pigment within the coating can be detected by a sensor.

2. The coating composition of claim 1 , wherein the coating emits fluorescence in the infrared spectrum at a greater intensity compared to the same coating exposed to the radiation comprising fluorescence-exciting radiation except without the infrared fluorescent pigment or dye.

3. The coating composition of claim 1 , wherein the coating composition, when cured to form a coating and exposed to radiation comprising fluorescence-exciting radiation, emits fluorescence in the infrared spectrum at least twice the intensity compared to the same coating exposed to the radiation comprising fluorescence-exciting radiation except without the infrared fluorescent pigment or dye.

4. The coating composition of claim 1 , wherein the sensor has sensitivity in the infrared region of the electromagnetic spectrum.

5. The coating composition of claim 1 , wherein the coating composition is substantially free of an infrared absorbing component.

6. The coating composition of claim 1 , wherein the radiation comprising fluorescence-exciting radiation is produced from sunlight, incandescent light, fluorescent light, xenon light, laser, LED light, or a combination thereof.

7. The coating composition of claim 1 , further comprising a colorant.

8. The coating composition of claim 1 , wherein the infrared reflective pigment reflects at a first wavelength and the infrared fluorescent pigment or dye fluoresces at a second wavelength, and wherein a balance of the coating composition is transparent at the first wavelength and second wavelength.

9. The coating composition of claim 1 , wherein the infrared fluorescent pigment comprises Han purple, Han blue, Egyptian blue, ruby, cadmium containing pigments, indigo, azurite (Cu 3 (CO 3 ) 2 (OH) 2 ), ploss blue, smalt, or a combination thereof.

10. The coating composition of claim 1 , wherein the infrared fluorescent pigment or dye comprises an organic pigment or dye.

11. A multi-layer coating comprising:

a first coating layer comprising a cured infrared reflective coating composition; and

a second coating layer overlying at least a portion of the first coating layer, the second coating layer comprising a cured coating composition according to claim 1 .

12. A substrate at least partially coated with the material of claim 1 .

13. The substrate of claim 12 , wherein the substrate comprises at least a portion of an object in a vehicle's surroundings.

14. A method of detecting an article comprising:

exposing a surface of an article to radiation comprising fluorescence-exciting radiation, the surface being at least partially coated with a coating composition comprising: (i) a film-forming resin, (ii) an infrared reflective pigment, and (iii) an infrared fluorescent pigment or dye different from the infrared reflective pigment; and

detecting fluorescence emitted by the coated surface in the infrared spectrum.

15. The method of claim 14 , wherein the coating composition, when cured to form a coating and exposed to the radiation comprising fluorescence-exciting radiation, emits fluorescence in the infrared spectrum at a greater intensity compared to the same coating exposed to the radiation comprising fluorescence-exciting radiation except without the infrared fluorescent pigment or dye.

16. The method of claim 14 , wherein the fluorescence is detected by a sensor having sensitivity in the infrared region of the electromagnetic spectrum.

17. The method of claim 14 , wherein the radiation comprising fluorescence-exciting radiation is produced from sunlight, incandescent light, fluorescent light, xenon light, laser, LED light, or a combination thereof.

18. The method of claim 14 , wherein the article comprises at least a portion of an object in a vehicle's surroundings.

19. The method of claim 18 , wherein the fluorescence is detected by a sensor on the vehicle.

Assignments (4)
CORRECTIVE ASSIGNMENT TO CORRECT THE INVENTORS ASSIGNING INTEREST PREVIOUSLY RECORDED AT REEL: 057412 FRAME: 0740. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Feb 1, 2022
From: ZALICH, MICHAEL ANDREW; HELLRING, STUART D.; RETSCH, WILLIAM H., JR
To: PPG INDUSTRIES OHIO, INC.
Reel/Frame 058926/0815 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 8, 2021
From: ZALICH, MICHAEL ANDREW; BAXTER, MICHAEL F.; HELLRING, STUART D.; STALKER, JEFFREY LYNN
To: PPG INDUSTRIES OHIO, INC.
Reel/Frame 057412/0740 →
CONFIRMATORY LICENSE Recorded May 17, 2019
From: UNIVERSITY OF CALIF-LAWRENC BERKELEY LAB
To: UNITED STATES DEPARTMENT OF ENERGY
Reel/Frame 049219/0884 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 20, 2018
From: BERDAHL, PAUL H.
To: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
Reel/Frame 047835/0754 →
Continuity (4)
Provisional Application 62272391 · Dec 29, 2015
Provisional Application 62272357 · Dec 29, 2015
Provisional Application 62272377 · Dec 29, 2015
Related Publication 20210163759A1 · Jun 3, 2021
Cited By (1)
US 12,380,306