Compound for organic electric element, organic electric element comprising the same, and electronic device thereof

1. A compound of Formula 1:

wherein,

S ring is a C 4 heterocyclic group comprising S,

N ring is a C 4 heterocyclic group comprising N,

R 1 to R 3 are each independently selected from the group consisting of deuterium, tritium, halogen, a cyano group, a nitro group, a C 6 -C 60 aryl group, a fluorenyl group, a C 2 -C 60 heterocyclic group containing at least one heteroatom selected from the group consisting of O, N, S, Si, and P, a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring, a C 1 -C 50 alkyl group, a C 2 -C 20 alkenyl group, a C 2 -C 20 alkynyl group, -L a -N(R a )(R b ), a C 1 -C 30 alkoxyl group and a C 6 -C 30 aryloxy group, and neighboring groups are optionally linked to each other to form at least one ring,

m, n and o are each an integer of 0 to 4, and when each of them is an integer of 2 or more, each of the plurality of R 1 to R 3 may be the same or different from each other,

L 1 is selected from the group consisting of a single bond, a C 6 -C 60 arylene group, a fluorenylene group, a C 2 -C 60 heterocyclic group containing at least one heteroatom selected from the group consisting of O, N, S, Si, and P, and a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring,

Z is represented by the following formula,

wherein,

X and Y are each independently a single bond, O or S, and one of X and Y is a a single bond and the other is O or S,

R 4 is selected from the group consisting of deuterium, tritium, halogen, a cyano group, a nitro group, a C 6 -C 60 aryl group, a fluorenyl group, a C 2 -C 60 heterocyclic group containing at least one heteroatom selected from the group consisting of O, N, S, Si, and P, a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring, a C 1 -C 50 alkyl group, a C 2 -C 20 alkenyl group, a C 2 -C 20 alkynyl group, -L a -N(R a )(R b ), a C 1 -C 30 alkoxyl group and a C 6 -C 30 aryloxy group,

p is an integer of 0 to 4, when p is an integer of 2 or more, the plurality of R 4 may be the same or different from each other, and neighboring groups are optionally linked to each other to form at least one ring,

Ar 1 is selected from the group consisting of a C 6 -C 60 aryl group, a fluorenyl group, a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring, and a C 2 -C 60 heterocyclic group containing at least one heteroatom selected from the group consisting of O, N, S, Si, and P,

L a is selected from the group consisting of a single bond, a C 6 -C 60 arylene group, a fluorenylene group, a C 2 -C 60 heterocyclic group containing at least one heteroatom selected from the group consisting of O, N, S, Si, and P, and a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring,

R a and R b are each independently selected from the group consisting of a C 6 -C 60 aryl group, a fluorenyl group, a C 2 -C 60 heterocyclic group containing at least one heteroatom selected from the group consisting of O, N, S, Si, and P, a C 1 -C 50 alkyl group, a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring, and a C 2 -C 20 alkenyl group, and

the aryl group, arylene group, fluorenyl group, fluorenylene group, heterocyclic group, fused ring group, alkyl group, alkenyl group, alkynyl group, alkoxyl group and aryloxyl group are each optionally further substituted with one or more substituents selected from the group consisting of deuterium, halogen, a silane group substituted or unsubstituted with a C 1 -C 20 alkyl group or a C 6 -C 20 aryl group, a siloxane group, a boron group, a germanium group, a cyano group, a nitro group, a C 1 -C 20 alkylthio group, a C 1 -C 20 alkoxyl group, a C 1 -C 20 alkyl group, a C 2 -C 20 alkenyl group, a C 2 -C 20 alkynyl group, a C 6 -C 20 aryl group, a C 6 -C 20 aryl group substituted with deuterium, a fluorenyl group, a C 2 -C 20 heterocyclic group containing at least one heteroatom selected from the group consisting of O, N, S, Si, and P, a C 3 -C 20 cycloalkyl group, a C 7 -C 20 arylalkyl group and a C 8 -C 20 arylalkenyl group.

2. The compound of claim 1 represented by one of the following Formulas 2 to 5:

wherein X, Y, R 1 ˜R 4 , L 1 , Ar 1 , m, n, o and p are the same as defined in claim 1 .

3. The compound of claim 1 , wherein Z is represented by one of the following formulas Z-1 to Z-8:

wherein X, Y, Ar 1 , R 4 and p are the same as defined in claim 1 and p′ is an integer of 0 to 2.

4. The compound of claim 1 represented by one of the following Formulas 2-1 to 5-4:

wherein R 1 ˜R 4 , L 1 , Ar 1 , m, n, o and p are the same as defined for Formula 1 in claim 1 .

5. The compound of claim 1 , wherein Ar 1 is represented by one of the following formulas Ar-1 to Ar-10:

wherein L 2 is the same as L 1 defined in claim 1 ,

Q 1 ˜Q 15 are each independently C(R g ) or N, wherein R g is selected from the group consisting of hydrogen, deuterium, a C 6 -C 20 aryl group, a fluorenyl group, a fused ring group of a C 3 -C 20 aliphatic ring and a C 6 -C 20 aromatic ring, a C 2 -C 20 heterocyclic group containing at least one heteroatom selected from the group consisting of O, N, S, Si, and P, a C 1 -C 20 alkyl group, a C 2 -C 20 alkenyl group, a C 2 -C 20 alkynyl group, and a C 1 -C 30 alkoxyl group,

W 1 is S, O or N(R h ), and W 2 ˜W 4 are each independently S, O, N(R h ) or C(R i )(R j ), wherein R h ˜R j are each independently selected from the group consisting of a C 6 -C 20 aryl group, a C 2 -C 20 heterocyclic group containing at least one heteroatom selected from the group consisting of O, N, S, Si, and P, a C 1 -C 20 alkyl group, a C 2 -C 20 alkenyl group, a C 1 -C 30 alkoxyl group, and a fluorenyl group,

R e is selected from the group consisting of deuterium, halogen, a silane group substituted or unsubstituted with a C 1 -C 20 alkyl group or a C 6 -C 20 aryl group, a siloxane group, a boron group, a germanium group, a cyano group, a nitro group, a C 1 -C 20 alkylthio group, a C 1 -C 20 alkoxyl group, a C 1 -C 20 alkyl group, a C 2 -C 20 alkenyl group, a C 2 -C 20 alkynyl group, a C 6 -C 20 aryl group, a C 6 -C 20 aryl group substituted with deuterium, a fluorenyl group, a C 2 -C 20 heterocyclic group containing at least one heteroatom selected from the group consisting of O, N, S, Si, and P, a C 3 -C 20 cycloalkyl group, a C 7 -C 20 arylalkyl group and a C 8 -C 20 arylalkenyl group, and neighboring R e groups are optionally linked to each other to form a ring, q is an integer of 0 to 5, r is an integer of 0 to 4, s is an integer of 0 to 3, and when each of them is an integer of 2 or more, each of the plurality of R e s may be the same or different from each other,

R f is selected from the group consisting of hydrogen, deuterium, a C 6 -C 20 aryl group, a fluorenyl group, a fused ring group of a C 3 -C 20 aliphatic ring and a C 6 -C 20 aromatic ring, a C 2 -C 20 heterocyclic group containing at least one heteroatom selected from the group consisting of O, N, S, Si, and P, a C 1 -C 20 alkyl group, a C 2 -C 20 alkenyl group, a C 2 -C 20 alkynyl group, and a C 1 -C 30 alkoxyl group.

6. The compound of claim 1 , wherein Formula 1 is any one of the following compounds P 1-1 to P 4-50:

7. An organic electric element comprising a first electrode, a second electrode, and an organic material layer formed between the first electrode and the second electrode, wherein the organic material layer comprises the compound of claim 1 .

8. The organic electric element of claim 7 , wherein the compound is comprised as a single compound or a mixture of two or more different kinds in at least one layer of a hole injection layer, a hole transport layer, an emission-auxiliary layer and a light emitting layer of the organic material layer.

9. The organic electric element of claim 8 , wherein the compound is used as phosphorescent host of the light emitting layer.

10. The organic electric element of claim 7 , wherein the organic material layer is formed by any one of the processes of spin coating, nozzle printing, inkjet printing, slot coating, dip coating or roll-to-roll.

11. An electronic device comprising a display device and a control unit for driving the display device, wherein the display device comprises the organic electric element of claim 7 .

12. The electronic device of claim 11 , wherein the organic electric element is an organic light emitting diode, an organic solar cell, an organic photo conductor, an organic transistor, or an element for monochromatic or white illumination.