Spandex having improved unwinding properties and enhanced adhesive properties with hot melt adhesive and method for preparing same
The present invention relates to a method for preparing spandex having improved unwinding properties and enhanced adhesive properties with a hot melt adhesive and, more specifically, to a method for preparing spandex by means of adding a polystyrene polymer to a polyurethane-urea solution which is a spinning solution. Therefore, when spandex is unwound, irregular ballooning, tension spikes and the like can be effectively improved and other physical properties are unaffected. And the adhesive properties with a hot melt adhesive are enhanced.
1. A spandex having improved unwinding properties and enhanced adhesive properties with a hot melt adhesive,
wherein a polystyrene-based polymer having a number average molecular weight of 70,000 to 120,000 is added to a polyurethane-urea spinning stock solution in an amount of 3 wt. % to 5 wt. % with respect to a solid content of the polyurethane-urea spinning stock solution, and which is used for hygiene purposes,
wherein the spandex has no more than 0.4 g of fluctuation in the 5 th unload force among the physical properties of yarn as measured at 200% elongation with evaluation conducted based on ASTM D 2731-72 standard,
wherein the spandex has a 20% or higher decrease in unwinding tension value on average that has been measured by making a yarn of the spandex and treated in an oven at a temperature of 60° C. and relative humidity of 30% for 3 days, cooled at room temperature for 12 hours, and the tension value during unwinding at a speed of 100 m/min of 100 g of an inner layer of the yarn excluding a bobbin weight was measured whereby unwinding properties are evaluated by installing a guide for fixing the yarn at a position spaced 30 cm from the bobbin holder, and measuring tension and a winding device capable of controlling speed,
wherein the spandex has adhesive properties of the spandex increased by 10% or more compared to when the polystyrene-based polymer is not added, the adhesive properties of the spandex measured as a creep percentage defined by equation (1) and by performing an evaluation method comprising (i) elongating a laminate portion to a maximum and fixed on a plastic plate of 30 cm in width and 50 cm in length, (ii) marking portions 100 mm at a left side and a right side of a central portion, and (iii) cutting the marked portions to measure the length of the portion sticking out of the spandex
Creep percentage=[200−(length of the portion sticking out)]/200×100 Equation (1).
2. A method for manufacturing spandex having improved unwinding properties and enhanced adhesive properties with a hot melt adhesive comprising the steps of:
preparing a polyurethane-urea spinning stock solution;
preparing a spinning solution by adding a polystyrene-based polymer having a number average molecular weight of 70,000 to 120,000 in a slurry state to a polyurethane-urea spinning stock solution in an amount of 3 wt. % to 5 wt. % with respect to a solid content of the polyurethane-urea spinning stock solution; and
spinning and winding the spinning solution,
wherein the spandex is used for hygiene purposes and has no more than 0.4 g of fluctuation in the 5 th unload force among the physical properties of a yarn as measured at 200% elongation with evaluation conducted based on ASTM D 2731-72 standard, and
wherein the spandex has a 20% or higher decrease in unwinding tension value on average that has been measured by making the yarn of the spandex and treated in an oven at a temperature of 60° C. and relative humidity of 30% for 3 days, cooled at room temperature for 12 hours, and the tension value during unwinding at a speed of 100 m/min of 100 g of an inner layer of the yarn excluding a bobbin weight measured by installing a guide for fixing the yarn at a position spaced 30 cm from a fixed bobbin holder, and measuring tension and a winding device capable of controlling speed,
wherein adhesive properties of the spandex is increased by 10% or more compared to when the polystyrene-based polymer is not added, the adhesive properties of the spandex measured as a creep percentage defined by equation (1) and by performing an evaluation method comprising (i) elongating a laminate portion to a maximum and fixed on a plastic plate of 30 cm in width and 50 cm in length, (ii) marking portions 100 mm at a left side and a right side of a central portion, and (iii) cutting the marked portions to measure the length of the portion sticking out of the spandex
Creep percentage=[200−(length of the portion sticking out)]/200×100 Equation (1).