Poly(meth)acrylate copolymers with branched C17 alkyl chains and their use in lubricant oil compositions
The presently claimed invention is directed to poly(meth)acrylate copolymers containing alkyl(meth)acrylate comonomer with branched C17 alkyl group. The invention is further related to lubricating oil compositions comprising poly(meth)acrylate copolymers containing alkyl(meth) acrylate comonomer with branched C17 alkyl group as viscosity index improving component.
1. A poly(meth)acrylate copolymer that is obtained by polymerizing a mixture comprising:
(A) C17 alkyl (meth)acrylate, where C17 alkyl chain is branched with a mean degree of branching between 2.0 and 4.0,
(B) methyl methacrylate and/or methyl acrylate, and
(C) alkyl methacrylate and/or alkyl acrylate with a linear or branched C2 to C30 alkyl chain.
2. The copolymer of claim 1 , wherein the C17 alkyl chain is branched with a mean degree of branching between 2.8 and 3.7.
3. The copolymer of claim 1 , wherein the copolymer has a weight average molecular weight M W of from 10,000 to 800,000 determined by gel permeation chromatography according to DIN 55672-1.
4. The copolymer of claim 1 , wherein the amount of comonomer (A) is from 5 to 80 wt.-%, based on the total weight of the poly(meth)acrylate copolymer.
5. The copolymer of claim 1 , wherein the amount of comonomer (B) is from 5 to 40 wt.-%, based on the total weight of the poly(meth)acrylate copolymer.
6. The copolymer of claim 1 , wherein the amount of comonomer (C) is from 15 to 80 wt.-%, based on the total weight of the poly(meth)acrylate copolymer.
7. The copolymer of claim 1 , wherein the linear or branched C2 to C30 alkyl chain is selected from the group consisting of ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl, sec-butyl, tert-butyl, pentyl, hexyl, heptyl, octyl, 2-ethylhexyl, 2-propyl heptyl, nonyl, decyl, stearyl, lauryl, octadecyl, heptadecyl, nonadecyl, eicosyl, henicosyl, docosyl, tricosyl, tetracosyl, pentacosyl, hexacosyl, hexacosyl, octacosyl, nonacosyl, triacontyl and behenyl.
8. A concentrate composition for use in lubricating oils comprising:
(i) diluent, and
(ii) from 30 to 70 wt.-% of the poly(meth)acrylate copolymer according to claim 1 .
9. A lubricating oil composition comprising:
(a) a base oil,
(b) the poly(meth)acrylate copolymer according to claim 1 , and
(c) additives.
10. The lubricating oil composition of claim 9 , comprising
0.1 to 30 wt.-% of the poly(meth)acrylate copolymer according to claim 1 ,
70 to 99.9 wt.-% base oil, and
0.05 to 20 wt.-% of additives.
11. The lubricating oil composition of claim 9 wherein the additives comprise at least one additive selected from the group consisting of antioxidants, oxidation inhibitors, corrosion inhibitors, friction modifiers, metal passivators, rust inhibitors, anti-foamants, viscosity index enhancers, additional pour-point depressants, dispersants, detergents, further extreme-pressure agents and anti-wear agents.
12. The lubricating oil composition of claim 9 , having shear stability index as measured according to ASTM D7109 and as calculated by ASTM D6022 of less than 50.
13. The lubricating oil composition of claim 9 , having high temperature high shear viscosity at 100° C. from 4.00 to 6.00 mPas, as measured according to ASTM D5481.
14. An automatic transmission fluid, a manual transmission fluid, an hydraulic fluid, a grease, a gear fluid, a metal-working fluid, a crankcase engine oil or shock absorber fluid comprising the lubricating oil composition of claim 9 .
15. A method for improving the shear stability of a lubricating oil, wherein said method comprises adding the poly(meth)acrylate copolymer according to claim 1 to a lubricating oil composition comprising a base oil and additives.