Copolymer for binders for nonaqueous battery electrodes, slurry for nonaqueous battery electrodes, nonaqueous battery electrode, and nonaqueous battery
A copolymer for binders, which is capable of reducing the internal resistance of a battery, while ensuring sufficient binding properties between active materials and between an active material and a collector in a nonaqueous battery electrode; a composition for binders; a slurry for nonaqueous battery electrodes; a nonaqueous battery electrode; and a nonaqueous battery. This copolymer for binders is a copolymer for binders (P) of a monomer mixture (M) that contains at least a monomer (A) represented by general formula (1) and a (meth)acrylate salt monomer (B); and an amount of structure derived from the monomer (A) based on the copolymer for binders (P) is set to 0.5 to 20.0% by mass. (In the formula, each of R 1 and R 2 independently represents a hydrogen atom or an alkyl group having 1 to 5 carbon atoms.)
1. A copolymer for binders for nonaqueous battery electrodes,
wherein the copolymer for binders (P) is a copolymer of a monomer mixture (M) that comprises at least a monomer (A) represented by general formula (1) and a (meth)acrylate salt monomer (B);
an amount of structure derived from the monomer (A) is set to 0.5 to 20.0% by mass based on the copolymer for binders (P), and
an amount of structure derived from the monomer (B) is 75.0 to 99.0% by mass based on the copolymer for binders (P),
wherein R 1 and R 2 each independently represent a hydrogen atom or an alkyl group having 1 to 5 carbon atoms,
wherein the structure derived from the monomer (B) is a structure represented by general formula (2),
wherein R 3 represents a hydrogen atom or a methyl group, and A represents Na, K or NH 4 , and
wherein the copolymer is a component of the binders in the nonaqueous battery electrodes.
2. The copolymer for binders for nonaqueous battery electrodes according to claim 1 ,
wherein the monomer mixture (M) further comprises an ethylenically unsaturated monomers (C) having a polar functional group, and
a structure derived from ethylenically unsaturated monomer (C) has a polar functional group.
3. The copolymer for binders for nonaqueous battery electrodes according to claim 1 ,
wherein the monomer (A) is N-vinylformamide or N-vinylacetamide.
4. The copolymer for binders for nonaqueous battery electrodes according to claim 1 ,
wherein the weight average molecular weight of the copolymer for binders (P) is in the range of 1,000,000 to 10,000,000.
5. The copolymer for binders for nonaqueous battery electrodes according to claim 2 ,
wherein an amount of structure derived from the monomer (C) is 0.5 to 15.0% by mass based on the copolymer for binders (P).
6. A slurry for nonaqueous battery electrodes comprising the copolymer for binders for nonaqueous battery electrodes according to claim 1 , and an electrode active material.
7. The slurry for nonaqueous battery electrodes according to claim 6 ,
wherein the electrode active material is a negative electrode active material.
8. The slurry for nonaqueous battery electrodes according to claim 6 ,
wherein an amount of the copolymer for binders for nonaqueous battery electrodes is 0.1 to 5 parts by mass with respect to 100 parts by mass of the electrode active material.
9. A nonaqueous battery electrode comprising
a current collector, and
an electrode active material layer formed on the current collector,
wherein the electrode active material layer comprises the copolymer for binders for nonaqueous battery electrodes according to claim 1 .
10. The nonaqueous battery electrode according to claim 9 ,
wherein the electrode active material is a negative electrode active material.
11. A nonaqueous battery comprising
the nonaqueous battery electrode according to claim 9 .