All-solid-state lithium-sulfur battery and production method for same
(Problem to be Solved) The present application is to provide an all-solid-state lithium-sulfur battery that experiences little reduction in battery performance even after repeated charging/discharging cycling, does not generate toxic gas when damaged, and does not require addition of equipment or the like for management of moisture or oxygen concentration; and a production method for the all-solid-state lithium-sulfur battery. (Means for Solution) The present invention uses a positive electrode that contains sulfur and a conductive material, a negative electrode that contains lithium metal, and, as an electrolyte layer that is interposed between the positive electrode and the negative electrode, an oxide solid electrolyte to achieve a high-performance all-solid-state lithium-sulfur battery. According to the present invention, after a positive electrode slurry that contains sulfur is applied to a positive electrode side of an oxide solid electrolyte formation body and dried to form a positive electrode, the oxide solid electrolyte molded body is mounted upon a lithium foil that will become a negative electrode and adhered to the lithium foil. Said process allows for efficient assembly of a battery cell that is configured to have an oxide solid electrolyte interposed between a positive electrode and a negative electrode.
1. An all-solid-state lithium-sulfur battery comprising
a positive electrode that contains sulfur and a conductive material but that does not contain an inorganic solid electrolyte,
a negative electrode that contains lithium metal, and
a layer of a solid electrolyte interposed between the positive electrode and the negative electrode, wherein the positive electrode contains sulfur and conductive carbon black in a mass ratio of 70/30 to 95/5, and
the solid electrolyte is an oxide-based solid electrolyte, and
an electroconductive layer is not provided between the positive electrode and the layer of the solid electrolyte.
2. The all-solid-state lithium-sulfur battery according to claim 1 , wherein the oxide-based solid electrolyte is lithium composite oxide.
3. The all-solid-state lithium-sulfur battery according to claim 2 , wherein the lithium composite oxide is lithium-lanthanum-zirconium composite oxide.
4. The all-solid-state lithium-sulfur battery according to claim 3 , wherein the lithium-lanthanum-zirconium composite oxide is a composite oxide further containing one or more elements selected from aluminum, tantalum, niobium, and bismuth.
5. The all-solid-state lithium-sulfur battery according to claim 1 , wherein the positive electrode further contains a binder.
6. The all-solid-state lithium-sulfur battery according to claim 1 , wherein the negative electrode is a lithium foil.
7. The all-solid-state lithium-sulfur battery according to claim 1 , wherein an operating temperature is 110° C. or less.
8. A motor vehicle equipped with an all-solid-state lithium-sulfur battery according to claim 1 .
9. An electric power storage system configured to supply electric power from an all-solid-state lithium-sulfur battery according to claim 1 to an electric power network, or to supply electric power from the electric power network to the all-solid-state lithium-sulfur battery.
10. A production method for an all-solid-state lithium-sulfur battery that comprises a positive electrode that contains sulfur but that does not contain inorganic solid electrolyte, a negative electrode that contains lithium metal, a layer of an oxide-based solid electrolyte interposed between the positive electrode and the negative electrode, the method comprising:
a step of attaching a masking tape with a portion for forming the positive electrode unmasked, at a positive electrode side of an oxide-based solid electrolyte molded body;
a step of forming the positive electrode on the oxide-based solid electrolyte molded body by applying positive electrode slurry containing sulfur and conductive carbon black in a mass ratio of 70/30 to 95/5 onto a portion of the oxide-based solid electrolyte molded body in a portion that is not covered with the masking tape at the positive electrode side, uniformly spreading the slurry, solidifying the slurry by vacuum drying, and then removing the masking tape; and
a step of assembling a cell by mounting a lithium foil on a negative electrode current collector, mounting the oxide-based solid electrolyte molded body such that a negative electrode surface is brought into contact with the lithium foil, and further mounting the positive electrode current collector on the positive electrode.
11. The production method for an all-solid-state lithium-sulfur battery according to claim 10 , wherein the method for comprising heat-treating the lithium foil to bring the lithium foil into close contact with the solid electrolyte molded body, after mounting the oxide-based solid electrolyte molded body such that the negative electrode surface is brought into contact with the lithium foil.
12. The production method for an all-solid-state lithium-sulfur battery according to claim 10 , wherein the oxide-based solid electrolyte is lithium-lanthanum-zirconium composite oxide.
13. The production method for an all-solid-state lithium-sulfur battery according to claim 12 , wherein the lithium-lanthanum-zirconium composite oxide is a composite oxide further containing one or more elements selected from aluminum, tantalum, niobium or bismuth.
14. The production method for an all-solid-state lithium-sulfur battery according to claim 10 , wherein the positive electrode slurry is obtained by adding an organic solvent to a mixture including 70 to 95% by mass of sulfur, and 5 to 30% by mass of conductive carbon black.
15. The production method for an all-solid-state lithium-sulfur battery according to claim 14 , wherein the organic solvent is an organic solvent for a lithium ion battery.
16. The production method for an all-solid-state lithium-sulfur battery according to claim 10 , wherein the positive electrode current collector is a stainless steel foil or an aluminum foil, and the negative electrode current collector is a copper foil.