Fuel cell
The invention relates to metal supported solid oxide fuel cells (SOFC), fuel cell stacks containing the same, methods of their manufacture and use thereof. The SOFC of the invention utilises an extended electrolyte and barrier layers to prevent specific types of corrosion of the metal substrate. This new coating approach reduces the rate of degradation of the fuel cells and improves system reliability when operated over long durations.
1. A metal supported solid oxide fuel cell (SOFC) comprising;
a metal substrate supporting the solid oxide fuel cell, wherein the metal substrate is not an electrochemically active layer;
an electrolyte layer adjacent the metal substrate; and
at least one gasket through which fluids are delivered to and/or from the metal supported solid oxide fuel cell;
wherein the electrolyte layer provides a non-porous protective coating adjacent the metal substrate preventing corrosion of the metal substrate; and
wherein at least a portion of the electrolyte layer is positioned between the metal substrate and the gasket.
2. The fuel cell of claim 1 , wherein the electrolyte layer is positioned on the metal substrate in regions proximate to the gasket.
3. The fuel cell of claim 2 , wherein at least a portion of the electrolyte layer is positioned on the metal substrate in regions that are equal to or less than 2mm from the gasket.
4. The fuel cell of claim 3 , wherein at least a portion of the electrolyte layer is positioned on the metal substrate in regions that are equal to or less than 1mm from the gasket.
5. The fuel cell of claim 2 , wherein the electrolyte layer coats an air side of the metal substrate, covering the region between the gasket and an electrochemically active region of the SOFC.
6. The fuel cell of claim 1 , wherein the electrolyte layer comprises a cerium-gadolinium oxide.
7. The fuel cell of claim 6 , wherein the cerium-gadolinium oxide further comprises cobalt.
8. The fuel cell of claim 1 , wherein the gasket comprises corrosion promoting agents.
9. The fuel cell of claim 8 , wherein corrosion promoting agents are selected from: group I elements, group VII elements, silicon, sulfur, or combinations thereof.
10. A fuel stack comprising two or more of the fuel cells according to claim 1 .
11. A method of making a fuel cell of claim 1 , comprising the steps of:
i) providing the metal substrate;
ii) applying the protective, non-porous coating comprising the electrolyte layer to the metal substrate; and
iii) applying a gasket to the fuel cell adjacent the metal substrate;
wherein the protective, non-porous coating is applied to at least part of those regions proximate to the gasket.
12. The method of claim 11 , wherein the coating in step (ii) is applied as the same coating that forms the main electrolyte layer between an anode layer and a cathode layer of the SOFC.
13. The fuel cell of claim 1 , wherein the electrolyte layer is positioned over a whole surface of the metal substrate such that it is positioned between an electrochemically active layer of the SOFC and the metal substrate.
14. The fuel cell of claim 1 , wherein the electrolyte layer is the same electrolyte layer as that used to form an electrolyte layer-between an anode and a cathode of the SOFC.
15. The fuel cell of claim 1 , wherein the electrolyte layer comprises:
a first electrolyte layer positioned over a whole surface of the SOFC metal substrate such that the first electrolyte layer is positioned between an electrochemically active layer of the SOFC and the metal substrate; and
a second electrolyte layer that is the same electrolyte layer as that used to form an electrolyte layer between an anode and a cathode of the SOFC; and wherein
the second electrolyte layer extends between the anode and the cathode to cover the first electrolyte layer.
16. The fuel cell of claim 1 , wherein the electrolyte layer has a thickness of greater than >2μm.