Liquid electrophotographic ink composition
Herein is described a liquid electrostatic ink composition comprising a carrier liquid, a resin, a colorant selected from a magenta colorant, a cyan colorant and a black colorant, an amine-containing basic dispersant having a total base number (TBN) in the range of about 10 to about 65 mgKOH/g material, the amine-containing basic dispersant present in an amount from about 5 wt. % to about 40 wt. % by total weight of colorant.
1. A method of producing a liquid electrophotographic (LEP) ink composition, the method comprising:
first combining:
a colorant selected from the group consisting of a magenta colorant, a cyan colorant and a black colorant, and wherein the colorant is selected from the group consisting of diketopyrrolopyrrole, perinone, phthalein, pyranthrone, pyrazoloquinazolinone, pyrroledione, and benzimidazolone; and
an amine-containing basic dispersant having a total base number (TBN) in the range of about 10 to about 65 mgKOH/g material, the amine-containing basic dispersant present in an amount from about 5 wt. % to about 40 wt. % by total weight of colorant,
to form colorant particles comprising the combined colorant and basic dispersant; and
grinding a resin and the colorant particles in the presence of a carrier liquid.
2. The method according to claim 1 , wherein the amine-containing basic dispersant has a TBN in the range of about 15 to about 50 mg/KOH/g material.
3. The method according to claim 1 , wherein the dispersant is of formula (I)
wherein R 1 , R 2 and R 3 are selected from the group consisting of an amine-containing head group, a hydrocarbon tail group, and hydrogen; wherein at least one of R 1 , R 2 and R 3 comprises a hydrocarbon tail group; and wherein at least one of R 1 , R 2 and R 3 comprises an amine-containing head group.
4. The method according to claim 3 , wherein:
R 1 is of formula (II)
P-L- formula (II),
wherein P is or comprises polyisobutylene and L is selected from the group consisting of a single bond, (CH 2 ) n , wherein n is from 0 to 5, —O— and —NH—;
R 2 is H; and
R 3 is of formula (III)
(CH 2 ) m [(CH 2 ) o NH(CH 2 ) p ] q (CH 2 ) r —NH 2 formula (III),
wherein m is at least 1, o is 0, 1 or 2, p is 1 or 2, q is 0 to 10, and r is 0 to 10.
5. The method according to claim 4 , wherein L is —CH 2 —, R 2 is H, m is 1, and q is 0 to 10.
6. The method according to claim 1 , wherein the basic dispersant comprises a polyisobutylene succinimide polyethylene amine non-ionic dispersant.