Rubber composition for paper feed roll and paper feed roll
A rubber composition for a paper feed roll contains at least a polymer component and a softener, has a 30% Mod (−40° C.) of less than or equal to 0.94 MPa, the 30% Mod (−40° C.) representing a modulus in 30% elongation at −40° C., and has an E1 (22° C.)/number of parts by mass of softener of greater than or equal to 0.008 MPa/phr, the E1 (22° C.)/number of parts by mass of softener representing a value of a dynamic modulus of elasticity at 22° C. E1 (22° C.) in temperature variance measurement of dynamic viscoelasticity, divided by the number of parts by mass of the softener relative to 100 parts by mass of the polymer component. These configurations provide a rubber composition for a paper feed roll and a paper feed roll that are excellent in maintainability of a coefficient of friction and wear resistance.
1. A rubber composition for a paper feed roll, the composition comprising at least a polymer component and a softener and having
a 30% Mod (−40° C.) of less than or equal to 0.94 MPa, the 30% Mod (−40° C.) representing a modulus in 30% elongation at −40° C., and
an E1 (22° C.)/number of parts by mass of softener of greater than or equal to 0.008 MPa/phr, the E1 (22° C.)/number of parts by mass of softener representing a value of a dynamic modulus of elasticity at 22° C. E1 (22° C.) in temperature variance measurement of dynamic viscoelasticity, divided by the number of parts by mass of the softener relative to 100 parts by mass of the polymer component.
2. The rubber composition for a paper feed roll according to claim 1 , the composition having
the 30% Mod (−40° C.) of less than or equal to 0.80 MPa and
a T(tan δmax) of less than or equal to −50° C., the T(tan δmax) representing a temperature at which a loss tangent tan δ exhibits a maximum value (tan δmax) in the temperature variance measurement of dynamic viscoelasticity.
3. A rubber composition for a paper feed roll, the composition comprising at least a polymer component and a softener and having
an E1 (−30° C.) of less than or equal to 4.2 MPa, the E1 (−30° C.) representing a dynamic modulus of elasticity at −30° C. in temperature variance measurement of dynamic viscoelasticity, and
an E1 (22° C.)/number of parts by mass of softener of greater than or equal to 0.008 MPa/phr, the E1 (22° C.)/number of parts by mass of softener representing a value of a dynamic modulus of elasticity at 22° C. E1 (22° C.) in the temperature variance measurement of dynamic viscoelasticity, divided by the number of parts by mass of the softener relative to 100 parts by mass of the polymer component.
4. The rubber composition for a paper feed roll according to claim 3 , the composition having
the E1 (−30° C.) of less than or equal to 3.8 MPa and
a T(tan δmax) of less than or equal to −50° C., the T(tan δmax) representing a temperature at which a loss tangent tan δ exhibits a maximum value (tan δmax) in the temperature variance measurement of dynamic viscoelasticity.
5. The rubber composition for a paper feed roll according to claim 1 , wherein the polymer component contains an ethylene-propylene-diene copolymer.
6. The rubber composition for a paper feed roll according to claim 5 , wherein the ethylene-propylene-diene copolymer contains greater than or equal to 52% by mass and less than or equal to 70% by mass of an ethylene component unit and greater than or equal to 2.8% by mass and less than or equal to 5.5% by mass of a diene component unit.
7. The rubber composition for a paper feed roll according to claim 1 , the composition comprising greater than or equal to 45 parts by mass and less than or equal to 110 parts by mass of the softener relative to 100 parts by mass of the polymer component.
8. The rubber composition for a paper feed roll according to claim 7 , wherein the softener is at least one of a paraffin-based petroleum blended oil, a poly-α-olefin, and a long-chain alkyl carbonate each having a kinematic viscosity at 40° C. of greater than or equal to 10 mm 2 /s and less than or equal to 60 mm 2 /s.
9. The rubber composition for a paper feed roll according to claim 8 , wherein the softener is at least one of a poly-α-olefin and a long-chain alkyl carbonate each having a kinematic viscosity at 40° C. of greater than or equal to 10 mm 2 /s and less than or equal to 30 mm 2 /s.
10. The rubber composition for a paper feed roll according to claim 1 , the composition comprising, as a cross-linking agent, greater than or equal to 1 part by mass and less than or equal to 2.8 parts by mass of sulfur relative to 100 parts by mass of the polymer component.
11. A paper feed roll comprising a rubber layer formed of the rubber composition for a paper feed roll according to claim 1 .
12. The rubber composition for a paper feed roll according to claim 3 , wherein the polymer component contains an ethylene-propylene-diene copolymer.
13. The rubber composition for a paper feed roll according to claim 12 , wherein the ethylene-propylene-diene copolymer contains greater than or equal to 52% by mass and less than or equal to 70% by mass of an ethylene component unit and greater than or equal to 2.8% by mass and less than or equal to 5.5% by mass of a diene component unit.
14. The rubber composition for a paper feed roll according to according to claim 3 , the composition comprising greater than or equal to 45 parts by mass and less than or equal to 110 parts by mass of the softener relative to 100 parts by mass of the polymer component.
15. The rubber composition for a paper feed roll according to claim 14 , wherein the softener is at least one of a paraffin-based petroleum blended oil, a poly-α-olefin, and a long-chain alkyl carbonate each having a kinematic viscosity at 40° C. of greater than or equal to 10 mm 2 /s and less than or equal to 60 mm 2 /s.
16. The rubber composition for a paper feed roll according to claim 15 , wherein the softener is at least one of a poly-α-olefin and a long-chain alkyl carbonate each having a kinematic viscosity at 40° C. of greater than or equal to 10 mm 2 /s and less than or equal to 30 mm 2 /s.
17. The rubber composition for a paper feed roll according to according to claim 3 , the composition comprising, as a cross-linking agent, greater than or equal to 1 part by mass and less than or equal to 2.8 parts by mass of sulfur relative to 100 parts by mass of the polymer component.
18. A paper feed roll comprising a rubber layer formed of the rubber composition for a paper feed roll according to according to claim 3 .