IP Library Granted Patent US 11,367,783
Granted Patent B2
US 11,367,783 · App. 16/104,642 · Granted Jun 21, 2022

Method of manufacturing a semiconductor device

Inventor: Ling-Yen Yeh (Hsinchu, TW)
Assignee: TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD.
H01L29/66818H01L21/3081H01L21/3085H01L29/0673H01L29/42392H01L29/7853H01L21/02238H01L21/02252H01L21/02255H01L21/30604H01L21/311
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Quick Facts
Patent No.
US 11,367,783
App. No.
16/104,642
Granted
Jun 21, 2022
Kind
B2
Abstract

In a method of manufacturing a semiconductor device, a fin structure is formed over a substrate. The fin structure is sculpted to have a plurality of non-etched portions and a plurality of etched portions having a narrower width than the plurality of non-etched portions. The sculpted fin structure is oxidized so that a plurality of nanowires are formed in the plurality of non-etched portions, respectively, and the plurality of etched portions are oxidized to form oxides. The plurality of nanowires are released by removing the oxides.

Claims (76)

1. A method of manufacturing a semiconductor device, comprising:

forming a fin structure over a substrate;

forming a first insulating layer covering a bottom part of the fin structure;

forming a second insulating layer over the first insulating layer;

sculpting a side face of the fin structure protruding from the second insulating layer to have a plurality of non-etched portions and a plurality of etched portions having a narrower width than the plurality of non-etched portions;

oxidizing the sculpted fin structure so that a plurality of nanowires are formed in the plurality of non-etched portions, respectively, and the plurality of etched portions are oxidized to form oxide, wherein adjacent nanowires are connected by the oxide; and

releasing the plurality of nanowires by removing the oxide,

wherein the sculpting the fin structure includes:

(i) forming a cover layer on the side face and a top face of the fin structure, the cover layer being in contact with the second isolation insulating layer;

(ii) etching the second insulating layer to expose a part of the side face of the fin structure corresponding to one of the plurality of etched portions;

(iii) etching the exposed portion of the side face, while a part of the side face and the top of the fin structure is covered by the cover layer, to form the one of the plurality of etched portions; and

(iv) after (iii), further etching the second insulating layer, and removing the cover layer.

2. The method of claim 1 , wherein in (iii) the exposed portion is a portion between a bottom of the cover layer formed on the side face of the fin structure and an upper surface of the second insulating layer.

3. The method of claim 1 , wherein (i) to (iv) are repeated twice or more to form the plurality of etched portions.

4. The method of claim 3 , wherein (i) to (iv) are repeated from a portion corresponding to an uppermost one of the plurality of etched portions to a portion corresponding to a bottommost one of the plurality of etched portions.

5. The method of claim 1 , wherein the fin structure includes a hard mask layer on the top of the fin structure, and the cover layer is formed on the hard mask layer.

6. The method of claim 1 , wherein the first insulating layer includes silicon oxide.

7. The method of claim 5 , wherein the channel cover layer includes one of SiN, SiCN, SiON and SiC.

8. The method of claim 1 , wherein:

the fin structure includes a channel region and source/drain regions, and

during the sculpting, the source/drain regions are covered by a source/drain cover layer.

9. The method of claim 8 , wherein the source/drain cover layer and the channel cover layer are made of the same material.

10. The method of claim 8 , wherein the source/drain cover layer and the channel cover layer are made of different material from each other.

11. The method of claim 8 , wherein the source/drain cover layer includes one of SiN, SiCN, SiON and SiC.

12. The method of claim 8 , further comprising:

after the sculpting, forming a sacrificial gate structure to cover the sculpted tin structure;

removing the source/drain cover layer;

forming source/drain epitaxial layers over the source/drain regions of the fin structure;

covering the source/drain epitaxial layers with a dielectric layer; and

removing the sacrificial gate structure, wherein:

after the sacrificial gate structure is removed, the oxidizing and the releasing are performed, and

a gate dielectric layer is formed over each of the released nanowires and a gate electrode layer is formed over the gate dielectric layer.

13. The method of claim 12 , wherein a fin cover layer is disposed between the sacrificial gate structure and the sculpted fin structure.

14. The method of claim 8 , wherein:

during the sculpting, the oxidizing and the releasing, the source/drain regions are covered by the source/drain cover layer, and

the method further comprises, after the releasing:

forming a sacrificial gate structure over the released nanowires;

removing the source/drain cover layer;

forming source/drain epitaxial layers over the source/drain regions of the fin structure;

covering the source/drain epitaxial layers with a dielectric layer;

removing the sacrificial gate structure; and

forming a gate dielectric layer over each of the nanowires and forming a gate electrode layer over the gate dielectric layer.

15. The method of claim 1 , wherein the oxidizing is performed by one of thermal oxidation, plasma oxidation and chemical oxidation.

16. A method of manufacturing a semiconductor device, comprising:

forming a fin structure over a substrate;

forming an isolation insulating layer covering a bottom part of the fin structure;

forming a first sacrificial gate structure over the fin structure;

forming sidewall spacers on opposing side faces of the first sacrificial gate structure;

removing the first sacrificial gate structure leaving the sidewall spacers;

sculpting a side face of a channel region of the fin structure protruding from the isolation insulating layer to have a plurality of non-etched portions and a plurality of etched portions having a narrower width than the plurality of non-etched portions;

oxidizing the sculpted fin structure so that a plurality of nanowires are formed in the plurality of non-etched portions, respectively, and the plurality of etched portions are oxidized to form oxide, wherein adjacent nanowires are connected by the oxide; and

releasing the plurality of nanowires by removing the oxide,

wherein the sculpting the fin structure includes:

(i) forming an insulating layer over the isolation insulating layer;

(ii) forming a cover layer on the side face and a top face of the fin structure and on the insulating layer;

(iii) etching the insulating layer to expose a part of the side face of the fin structure corresponding to one of the plurality of etched portions;

(iv) etching the exposed portion of the side face, while a part of the side face and the top of the fin structure is covered by the cover layer, to form the one of the plurality of etched portions; and

(v) after (iv), further etching the insulating layer, and removing the cover layer.

17. The method of claim 16 , wherein the fin structure includes a hard mask layer on the top of the fin structure, and the cover layer is formed on the hard mask layer.

18. The method of claim 16 , further comprising forming a source/drain cover layer after the sidewall spacers are formed,

wherein during the sculpting, source/drain regions of the tri structure are covered by the source/drain cover layer.

19. A method of manufacturing a semiconductor device, comprising:

forming a fin structure over a substrate;

forming a first sacrificial gate structure over the fin structure;

forming sidewall spacers on opposing side faces of the first sacrificial gate structure;

removing the first sacrificial gate structure leaving the sidewall spacers;

sculpting a channel region of the fin structure to have a plurality of non-etched portions and a plurality of etched portions having a narrower width than the plurality of non-etched portions;

forming a second sacrificial gate structure over the sculpted fin structure;

forming a source/drain epitaxial layer over a source/drain region of the fin structure;

covering the source/drain epitaxial layer;

removing the second sacrificial gate structure;

oxidizing the sculpted fin structure so that a plurality of nanowires are formed in the plurality of non-etched portions, respectively; and the plurality of etched portions are oxidized to form oxide; and

releasing the plurality of nanowires by removing the oxide.

20. The method of claim 19 , wherein:

the fin structure incudes a hard mask layer thereon, and

the first sacrificial gate structure is formed over the fin structure with the hard mask layer.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 5, 2019
From: YEH, LING-YEN
To: TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD.
Reel/Frame 048810/0491 →
Continuity (1)
Related Publication 20200058772A1 · Feb 20, 2020