Protective water reversible clear coating for substrates
A protective, sacrificial, water-reversible, coating composition for the protection of substrates comprised of water, a volatile base, a film-forming acrylic polymer in a water dispersion form, a compatabilizing polymer, specifically poly (2-ethyl-2-oxazoline), a poly acidic polymer (pH specific in terms of its solubility), wherein said coating is both water applied and water reversible or re-soluble under specific pH conditions.
1. A composition comprising: a pigment or a coloring agent, an aqueous medium, a volatile base, an acrylic film-forming polymer, a compatibilizing polymer selected from the group consisting of: poly (2-ethyl-2-oxazoline), poly (2-methyl-2-oxazoline), poly (2-isopropyl-2-oxazoline), and combinations thereof, and a poly acidic polymer, wherein said composition comprises between 0.1 and 10% by weight of the poly acidic polymer, 20-50% by weight of the compatibilizing polymer, and between 30 and 60% by weight of the acrylic film-forming polymer and wherein said composition is capable of being applied to a substrate using aqueous means and removed from said same substrate using an aqueous buffer at a specific pH.
2. The composition according to claim 1 , wherein the composition further comprises one or more of the following: a UV stabilizer, a coalescence material, a de-foaming agent, an anti-microbial agent, an agent to protect from temperature swings, and a flattening agent.
3. The composition according to claim 1 , wherein said acrylic film-forming polymer is selected from the group consisting of: acrylic emulsions, styrene/acrylic emulsions, and combinations thereof.
4. The composition according to claim 1 , wherein said acrylic film-forming polymer is present as an aqueous dispersion.
5. The composition according to claim 1 , wherein said poly acidic polymer is an acrylic copolymer having a carboxylic acid group capable of salt formation.
6. The composition according to claim 1 , further comprising an anti-corrosive agent.
7. The composition according to claim 6 , wherein the anti-corrosive agent is selected from the group consisting of: methylamine, dimethyl amine, ethylamine, propyl amine, cyclohexylamine, triethylentetramine (TETA), hexamethylentetramine (EMTA), monoethanolamine (MEA), triethanolamine (TEA), dimethylethanolamine (DMEA), methyldiethanolamine (MDEA), 2-(methyl(phenyl)amino)ethanol, 2,2′-(phenylazanediyl)diethanol, 2-(phenylamino)ethanol, mono-carboxylate salts, oligo-carboxylate salts, poly-carboxylate salts, triazoles, benzotriazole, tannates, inorganic inhibitors, chromates, silicates, stannates, zinc oxide, a salt of organo-nitrogens, and combinations thereof.
8. A method of coating a substrate with a removable composition comprising:
a. forming a composition according to claim 1 ,
b. coating said substrate with said composition, and
c. allowing said composition to dry.
9. The method of claim 8 wherein said dried composition is capable of being removed at a pH of greater than 6.0 in an aqueous buffer.
10. The method of claim 8 , wherein said coating is applied as a first layer of a first composition, said method further comprising:
d. applying a second layer of a second composition comprising: an aqueous medium, a volatile base, an acrylic film-forming polymer, a compatibilizing polymer, and a poly acidic polymer, and wherein said second composition comprises different concentrations of components or different components wherein the second composition is capable of being applied to a substrate using aqueous means and removed from said same substrate using an aqueous buffer at a specific pH by removing said composition, and
e. wherein said first and second compositions are capable of being re-solubilized at a different pH.
11. The method of claim 10 , wherein said first layer is capable of being re-solubilized at a pH of about 1.0 unit greater than said second adjacent layer in an aqueous medium, or wherein said first layer is capable of being removed at a pH of about 8.0 or more and wherein said second layer is capable of being removed at a pH of about 7.0 in an aqueous medium.
12. The method of claim 8 , further comprising applying a non-pH reversible coating applied to the substrate prior to the application of the first layer of said first composition.
13. The method of claim 10 , further comprising applying a third layer of a third composition comprising: water, a volatile base, an acrylic film-forming polymer, a compatibilizing polyoxazoline polymer, and a poly acidic material, provided that each outer adjacent layer is removed at a pH of about 1.0 unit less than an adjacent inner layer.
14. A composition comprising latex-based aqueous paint, a poly acidic polymer, a compatibilizing polyoxazoline polymer selected from the group consisting of: poly (2-ethyl-2-oxazoline), poly (2-methyl-2-oxazoline), poly (2-isopropyl-2-oxazoline), and combinations thereof, and one or more of the following: a UV stabilizer, a coalescence material, a de-foaming agent, an anti-microbial agent, an agent to protect from temperature swings, an anti-corrosive agent, and a flattening agent;
wherein the composition comprises the latex-based aqueous paint present between 30 and 60% by weight, the compatibilizing polymer is present at between 20 and 50% by weight, and the poly acidic polymer is present at between 0.1 and 10% by weight.
15. The composition of claim 14 , wherein the composition is removable with an aqueous buffer.
16. The composition of claim 14 , wherein said poly acidic polymer is an acrylic copolymer having a carboxylic acid group capable of salt formation.
17. The composition of claim 15 , wherein the aqueous buffer is a buffer having a concentration of at least 0.5M and a pH of between 6 and 10.
18. A composition comprising: a pigment or a coloring agent, an aqueous medium, an acrylic film-forming polymer, a compatibilizing polymer selected from the group consisting of: poly (2-ethyl-2-oxazoline), poly (2-methyl-2-oxazoline), poly (2-isopropyl-2-oxazoline), and combinations thereof, and a polyacidic polymer, wherein said composition comprises between 0.1% and 10% by weight of the poly acidic polymer, between 20% and 50% by weight of the compatibilizing polymer, and between 30% and 60% by weight of the acrylic film-forming polymer and, wherein the acrylic film-forming polymer is immiscible with the poly acidic polymer, absent the compatibilizing polymer, and a volatile base to adjust pH, wherein said composition forms a film on a substrate to which it is applied, said film being made up of the pigment or coloring agent, the aqueous medium, the acrylic film-forming polymer, the compatibilizing polymer, and the poly acidic polymer.
19. The composition of claim 18 wherein said poly acidic polymer is an acrylic copolymer having a carboxylic acid group capable of salt formation.