IP Library Granted Patent US 10,744,491
Granted Patent B2
US 10,744,491 · App. 16/110,070 · Granted Aug 18, 2020

Crystalline transition metal molybdotungstate process data system

Inventors: Stuart R. Miller (Arlington Heights, IL); Susan C. Koster (Carpentersville, IL)
Assignee: UOP LLC
B01J23/8885B01J21/04B01J21/08B01J21/12B01J23/002B01J23/885B01J35/002B01J37/0009B01J37/03B01J37/031B01J37/04B01J37/08B01J37/20C10G11/04C10G29/16C10G45/08C10G45/50C10G45/60C10G47/06B01J2523/00B01J2523/68B01J2523/69B01J2523/845B01J2523/847
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Quick Facts
Patent No.
US 10,744,491
App. No.
16/110,070
Granted
Aug 18, 2020
Kind
B2
Abstract

A hydroprocessing catalyst has been developed. The catalyst is a crystalline transition metal molybdotungstate material or metal sulfides derived therefrom, or both. The hydroprocessing using the crystalline transition metal molybdotungstate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking. A data system comprising at least one processor; at least one memory storing computer-executable instructions; and at least one receiver configured to receive data of at least one unit or stream in fluid communication with and downstream from or upstream to a conversion process comprising at least one reaction catalyzed by the catalyst or a metal sulfide decomposition product of the catalyst has been developed.

Claims (32)

1. A conversion process data system comprising:

(a) at least one processor;

(b) at least one memory storing computer-executable instructions; and

(c) at least one receiver configured to receive data of at least one unit or stream in fluid communication with and downstream from, or upstream to, a conversion process comprising at least one reaction catalyzed by at least one metal sulfide resulting from the decomposition by sulfidation of a material comprising a crystalline transition metal molybdotungstate material having the formula:

MMo x W y O z

where ‘M’ is a metal selected from Mn, Fe, Co, Ni, V, Cu, Zn, Sn, Sb, Ti, Zr, and mixtures thereof; ‘x+y’ varies between 0.4 to 2.5; ‘x’ varies from 0.0001 to 0.75; ‘z’ is a number which satisfies the sum of the valency of M, x and y; the material is further characterized by a x-ray powder diffraction pattern showing peaks at the d-spacings listed in Table A:

TABLE A

d(Å)

I/I0 (%)

6.20

s

3.52

vs

3.12

vs

2.74

vs

2.41

s

2.33

s

2.09

vs

1.93

m.

2. The system of claim 1 further comprising an Input/Output device to collect the data, or evaluate the date, or correlate the data, or any combination thereof.

3. The system of claim 1 further comprising a transmitter to transmit a signal to the conversion process.

4. The system of claim 3 wherein the signal comprises instructions.

5. The system of claim 4 wherein the signal comprises instructions regarding an adjustment to a parameter.

6. The system of claim 1 further comprising collecting data from multiple systems wherein one system is the parameter data system.

7. The system of claim 1 wherein the processor is configured to generate predictive information or quantitative information.

8. The system of claim 1 wherein the at least one unit or stream is not in direct fluid communication with the conversion process.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 1, 2020
From: MILLER, STUART R.; KOSTER, SUSAN C.
To: UOP LLC
Reel/Frame 053100/0463 →
Continuity (2)
Provisional Application 62550207 · Aug 25, 2017
Related Publication 20190060881A1 · Feb 28, 2019