Semiconductor device having buried gate structure and method for fabricating the same

1. A semiconductor device, comprising:

a substrate;

a first source/drain region and a second source/drain region spaced apart from each other by a trench in the substrate; and

a gate structure in the trench,

wherein the gate structure includes:

a gate dielectric layer being a single layer and covering a bottom and sidewalls of the trench,

a first gate electrode positioned over the gate dielectric layer; and

a second gate electrode positioned over the first gate electrode,

wherein the gate dielectric layer includes:

a first portion covering a portion of the trench between the first source/drain region and the second source/drain region; and

a second portion including a dipole inducing portion containing a dipole inducing chemical species that contacts the second gate electrode,

wherein the dipole inducing portion is in direct contact with a sidewall of the second gate electrode and has a thickness that is less than a thickness of the gate dielectric layer, and

wherein the first portion of the gate dielectric is dipole-free.

2. The semiconductor device of claim 1 , wherein the second portion of the gate dielectric layer includes:

a third portion that contains the dipole inducing chemical species; and

a fourth portion that does not contain the dipole inducing chemical species,

where the third portion contacts the second gate electrode, and the fourth portion contacts the first source/drain region and the second source/drain region.

3. The semiconductor device of claim 1 , wherein the first portion of the gate dielectric layer does not include the dipole inducing chemical species.

4. The semiconductor device of claim 1 , wherein the dipole inducing chemical species includes a lanthanum atom, and the first portion of the gate dielectric layer does not include a lanthanum atom.

5. The semiconductor device of claim 1 , wherein the second portion of the gate dielectric layer includes a silicon oxide containing a lanthanum atom, and the first portion of the gate dielectric layer includes a silicon oxide that does not contain a lanthanum atom.

6. The semiconductor device of claim 1 , wherein the second portion of the gate dielectric layer includes:

a lanthanum atom-containing silicon oxide; and

a lanthanum atom-free silicon oxide that does not contain a lanthanum atom, and

the lanthanum atom-containing silicon oxide is in contact with the second gate electrode, and the lanthanum atom-free silicon oxide is in contact with the first and second source/drain regions.

7. The semiconductor device of claim 1 , wherein the first gate electrode and the second gate electrode include a metal nitride.

8. The semiconductor device of claim 1 , wherein the first gate electrode includes a metal, and the second gate electrode includes a metal nitride, and

the gate structure further includes a metal nitride barrier formed between the first gate electrode and the first portion of the gate dielectric layer.

9. The semiconductor device of claim 1 , wherein the first gate electrode includes a metal-based material, and the second gate electrode includes an N-type doped polysilicon.

10. The semiconductor device of claim 1 , wherein an upper portion of the first gate electrode includes the dipole inducing chemical species.

11. The semiconductor device of claim 10 , wherein a lower portion of the first gate electrode and the second gate electrode do not contain the dipole inducing chemical species.

12. The semiconductor device of claim 1 , wherein an upper portion of the first gate electrode includes a lanthanum atom.

13. The semiconductor device of claim 1 , wherein an upper portion of the first gate electrode includes a lanthanum atom-containing titanium nitride, a lanthanum atom-containing tungsten, or a stack thereof.

14. The semiconductor device of claim 1 , further comprising:

an anti-oxidation barrier formed between the first gate electrode and the second gate electrode.

15. The semiconductor device of claim 14 , wherein the anti-oxidation barrier includes a metal nitride.

16. The semiconductor device of claim 14 , wherein the anti-oxidation barrier includes the dipole inducing chemical species.

17. The semiconductor device of claim 14 , wherein the anti-oxidation barrier includes a lanthanum atom-containing titanium nitride.

18. The semiconductor device of claim 1 , further comprising:

a fin region formed below the trench,

wherein the gate dielectric layer and the first gate electrode cover a top surface and sidewalls of the fin region.

19. The semiconductor device of claim 1 , wherein the first portion of the gate dielectric layer is formed of silicon oxide without dipole, and the second portion of the gate dielectric layer is formed of the silicon oxide containing the dipole inducing species.

20. A semiconductor device, comprising:

a substrate comprising a source and a drain region;

a trench formed in the substrate between the source region and the drain region;

a channel defined between the source region and the drain region along a surface profile of the trench;

a single silicon oxide layer formed on the trench and the channel;

a first gate electrode formed over the single silicon oxide layer and filled in a lower portion of the trench; and

a second gate electrode formed over the first gate electrode and partially filled in an upper portion of the trench,

wherein the single silicon oxide layer includes lanthanum atoms diffused into or formed in the single silicon oxide layer,

wherein the lanthanum atoms are provided only in a dipole inducing portion of the single silicon oxide layer horizontally overlapping with the source and drain regions, and

wherein the lanthanum atoms are in direct contact with a sidewall of the second gate electrode,

wherein the dipole inducing portion of the single silicon oxide layer has a thickness that is less than the thickness of the single silicon oxide layer, and

wherein a portion of the single silicon oxide layer that does not overlap with the source and drain regions is dipole-free.