Graphite material for negative electrode of lithium ion secondary cell and method for producing the same
A graphite material for a negative electrode of a lithium ion secondary cell disclosed herein is substantially configured of a graphite particle in which defects enabling intercalation/deintercalation of lithium ions have been formed on a basal plane and which includes a calcium (Ca) component.
1. A graphite material for a negative electrode of a lithium ion secondary cell, the graphite material being substantially configured of a graphite particle in which defects enabling intercalation/deintercalation of lithium ions have been formed on a basal plane,
wherein the graphite particle comprises a calcium (Ca) component in the basal plane, and
calcium carbonate is included as the calcium component.
2. The graphite material for a negative electrode of a lithium ion secondary cell according to claim 1 , wherein the calcium component is present in the graphite particle in an amount such that the amount of calcium is 0.5 mg/m 2 or more and 15 mg/m 2 or less with respect to a specific surface area of the graphite particle.
3. A lithium ion secondary cell comprising a negative electrode and a positive electrode, the negative electrode comprising a graphite material being substantially configured of a graphite particle in which defects enabling intercalation/deintercalation of lithium ions have been formed on a basal plane,
wherein the graphite particle comprises a calcium (Ca) component in the basal plane, and
calcium carbonate is included as the calcium component.
4. The lithium ion secondary cell according to claim 3 , wherein the calcium component is present in the graphite particle in an amount such that the amount of calcium is 0.5 mg/m 2 or more and 15 mg/m 2 or less with respect to a specific surface area of the graphite particle.
5. A method for producing a graphite material for a negative electrode of a lithium ion secondary cell, the method comprising:
supplying a calcium-containing substance to a surface of a graphite particle; and
supporting a calcium component in a basal plane of the graphite particle by heat treating the graphite particle supplied with the calcium-containing substance on the surface thereof in a temperature range in which the calcium-containing substance and the basal plane can react with each other to generate defects enabling intercalation/deintercalation of lithium ions on the basal plane of the graphite particle.
6. The production method according to claim 5 , including supporting calcium carbonate as the calcium component in the basal plane of the graphite particle by heat-treating the graphite particle supplied with the calcium-containing substance on the surface thereof in the temperature range in a carbon dioxide gas atmosphere.
7. The production method according to claim 6 , wherein the temperature range is about 800° C. to 1000° C.
8. The production method according to claim 5 , wherein the temperature range is about 800° C. to 1000° C.