Polymers having N-vinyl amide and hydroxyl moieties, their compositions and the uses thereof
The invention relates to polymers derived at least from one: (A) one N-vinyl amide unit, and (B) one hydroxyl-containing acrylate unit, and to polymers derived at least from: (A) N-vinyl-2-caprolactam, and (B) one non-acrylate unit having: (i) at least one hydroxyl group, and/or (ii) at least one functional group convertible to a hydroxyl group wherein at least one group is converted to hydroxyl functionality in the final polymer product. Such polymers may exhibit degradability, e.g., in seawater or soil environments. In preferred embodiments, these polymers and compositions thereof are used in oilfield applications, such as an inhibitor of gas hydrates and/or a kinetic inhibitor of gas hydrates. The polymer can assume alternating, block, and/or random configurations of the repeating units, with at least one ester group. The chemical structure subscripts m, and n may be any integer equal to or greater than 1.
1. A method for preventing, retarding, and/or reducing the formation and/or growth of gas hydrates that comprises:
(I) providing a polymer having the following structure:
wherein m and n are molar ratios, the sum of which equals 100%; and
(II) introducing a composition comprising the polymer into a petroleum-containing fluid, having from about 0.01% to about 3% of the polymer, based on the weight of the water present in the petroleum-containing fluid, wherein the K-value of the polymer ranges from about 5 to about 40.
2. The method according to claim 1 , wherein the Weight ratio of the N-vinyl-2-caprolactam in the polymer ranges from about 5% to about 95% and the weight ratio of the vinyl acetate in the polymer ranges from about 5% to about 95%.
3. The method according to claim 2 , wherein the weight ratio of the N-vinyl-2-caprolactam in the polymer ranges from about 10% to about 0% and the weight ratio of the vinyl acetate in the polymer ranges from about 10% to about 90%.
4. The method according to claim 1 , wherein the molecular weight of the polymer ranges from about 1,500 to about 4,000 Daltons.
5. The method according to claim 1 , wherein the K-value of the polymer ranges from about 10 to about 30.