Carbon nanotube electron emitter, method of manufacturing the same and X-ray source using the same
View Patent ↗The present disclosure provides a method of manufacturing a carbon nanotube electron emitter, including: forming a carbon nanotube film; performing densification by dipping the carbon nanotube film in a solvent; cutting an area of the carbon nanotube film into a pointed shape or a line shape; and fixing the cutting area of the carbon nanotube film arranged between at least two metal members to face upwards with lateral pressure.
1. A method of manufacturing a carbon nanotube electron emitter, comprising:
forming a carbon nanotube film;
performing densification by dipping the carbon nanotube film in a solvent;
cutting an area of the carbon nanotube film into a pointed shape or a line shape; and
fixing the cutting area of the carbon nanotube film arranged between at least two metal members to face upwards with lateral pressure.
2. The method of manufacturing a carbon nanotube electron emitter of claim 1 ,
wherein the forming of the carbon nanotube film includes:
mixing distilled water, sodium dodecyl sulfate (SDS), and carbon nanotubes (CNTs) and dispersing the mixed solution; and
filtering the mixed solution through an anodic aluminum oxide membrane (AAO membrane) and drying it in the form of a film, and
the carbon nanotubes CNTs are single-walled CNTs (SWCNTs) or multiwalled CNTs (MWCNTs).
3. The method of manufacturing a carbon nanotube electron emitter of claim 1 ,
wherein the solvent includes at least any one of isopropyl alcohol (IPA), ethanol, and nitric acid, and
the densification includes:
dipping the carbon nanotube film in the IPA for a predetermined period of time and then primarily drying the carbon nanotube film by heating; and
dipping the primarily dried carbon nanotube film in at least one of the ethanol and the nitric acid and then secondarily drying the carbon nanotube film by heating.
4. The method of manufacturing a carbon nanotube electron emitter of claim 1 , further comprising:
before or after the densification,
performing carbonization by adding a carbon-based material into the carbon nanotube film and then performing heat treatment thereto.
5. The method of manufacturing a carbon nanotube electron emitter of claim 4 ,
wherein the carbon-based material includes at least one of graphite adhesive, carbon paste, and carbon nanotube (CNT) paste, and
the carbonization includes:
adding the carbon-based material into the carbon nanotube film; and
performing heat treatment to the carbon-based material-added carbon nanotube film at a high temperature in a vacuum for a predetermined period of time.
6. A method of manufacturing a carbon nanotube electron emitter, comprising:
forming a carbon nanotube film;
cutting an area of the carbon nanotube film into a pointed shape or a line shape;
performing densification by dipping the cut carbon nanotube film in a solvent; and
fixing the cutting area of the carbon nanotube film arranged between at least two metal members to face upwards with lateral pressure.
7. A method of manufacturing a carbon nanotube electron emitter, comprising:
forming a carbon nanotube film;
performing carbonization by adding a carbon-based material into the carbon nanotube film and then performing heat treatment thereto;
cutting an area of the carbon nanotube film into a pointed shape or a line shape; and
fixing the cutting area of the carbon nanotube film arranged between at least two metal members to face upwards with lateral pressure.
8. A carbon nanotube electron emitter, comprising:
a carbon nanotube film which is densified with a solvent or carbonized by adding a carbon-based material; and
at least two metal members arranged on respective sides of the carbon nanotube film and fixing the carbon nanotube film,
wherein an area of the carbon nanotube film is cut into a pointed shape or a line shape, and
wherein the metal members fix the cutting area of the carbon nanotube film to face upwards with lateral pressure.
9. The carbon nanotube electron emitter of claim 8 ,
wherein in the carbon nanotube electron emitter,
multiple carbon nanotube films are arranged in an array type and the metal member is arranged between the carbon nanotube films.
10. The carbon nanotube electron emitter of claim 8 ,
wherein the solvent includes at least any one of isopropyl alcohol (IPA), ethanol, and nitric acid, and
the densified carbon nanotube film is dipped in the solvent and then dried, and in the densified carbon nanotube film, a space between carbon nanotubes is reduced by removing sodium dodecyl sulfate (SDS) remaining between the carbon nanotubes, and, thus, bonding strength between the carbon nanotubes is increased.
11. The carbon nanotube electron emitter of claim 8 ,
wherein the carbon-based material includes at least one of graphite adhesive, carbon paste, and carbon nanotube (CNT) paste, and
the carbonized carbon nanotube film is prepared by performing heat treatment to the carbon-based material-added carbon nanotube film at a high temperature in a vacuum for a predetermined period of time, and in the carbonized carbon nanotube film, the added carbon-based material fills a space between carbon nanotubes, and, thus, bonding strength between the carbon nanotubes is increased.