IP Library Granted Patent US 10,566,167
Granted Patent B2
US 10,566,167 · App. 16/138,118 · Granted Feb 18, 2020

Carbon nanotube electron emitter, method of manufacturing the same and X-ray source using the same

Inventors: Cheol Jin Lee (Seoul, KR); Sang Heon Lee (Seoul, KR); Jun-Soo Han (Uijeongbu-si, KR)
Assignee: Korea University Research and Business Foundation
H01J1/304C01B32/15H01J9/025H01J35/065H01J2201/30469
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Quick Facts
Patent No.
US 10,566,167
App. No.
16/138,118
Granted
Feb 18, 2020
Kind
B2
Abstract

The present disclosure provides a method of manufacturing a carbon nanotube electron emitter, including: forming a carbon nanotube film; performing densification by dipping the carbon nanotube film in a solvent; cutting an area of the carbon nanotube film into a pointed shape or a line shape; and fixing the cutting area of the carbon nanotube film arranged between at least two metal members to face upwards with lateral pressure.

Claims (47)

1. A method of manufacturing a carbon nanotube electron emitter, comprising:

forming a carbon nanotube film;

performing densification by dipping the carbon nanotube film in a solvent;

cutting an area of the carbon nanotube film into a pointed shape or a line shape; and

fixing the cutting area of the carbon nanotube film arranged between at least two metal members to face upwards with lateral pressure.

2. The method of manufacturing a carbon nanotube electron emitter of claim 1 ,

wherein the forming of the carbon nanotube film includes:

mixing distilled water, sodium dodecyl sulfate (SDS), and carbon nanotubes (CNTs) and dispersing the mixed solution; and

filtering the mixed solution through an anodic aluminum oxide membrane (AAO membrane) and drying it in the form of a film, and

the carbon nanotubes CNTs are single-walled CNTs (SWCNTs) or multiwalled CNTs (MWCNTs).

3. The method of manufacturing a carbon nanotube electron emitter of claim 1 ,

wherein the solvent includes at least any one of isopropyl alcohol (IPA), ethanol, and nitric acid, and

the densification includes:

dipping the carbon nanotube film in the IPA for a predetermined period of time and then primarily drying the carbon nanotube film by heating; and

dipping the primarily dried carbon nanotube film in at least one of the ethanol and the nitric acid and then secondarily drying the carbon nanotube film by heating.

4. The method of manufacturing a carbon nanotube electron emitter of claim 1 , further comprising:

before or after the densification,

performing carbonization by adding a carbon-based material into the carbon nanotube film and then performing heat treatment thereto.

5. The method of manufacturing a carbon nanotube electron emitter of claim 4 ,

wherein the carbon-based material includes at least one of graphite adhesive, carbon paste, and carbon nanotube (CNT) paste, and

the carbonization includes:

adding the carbon-based material into the carbon nanotube film; and

performing heat treatment to the carbon-based material-added carbon nanotube film at a high temperature in a vacuum for a predetermined period of time.

6. A method of manufacturing a carbon nanotube electron emitter, comprising:

forming a carbon nanotube film;

cutting an area of the carbon nanotube film into a pointed shape or a line shape;

performing densification by dipping the cut carbon nanotube film in a solvent; and

fixing the cutting area of the carbon nanotube film arranged between at least two metal members to face upwards with lateral pressure.

7. A method of manufacturing a carbon nanotube electron emitter, comprising:

forming a carbon nanotube film;

performing carbonization by adding a carbon-based material into the carbon nanotube film and then performing heat treatment thereto;

cutting an area of the carbon nanotube film into a pointed shape or a line shape; and

fixing the cutting area of the carbon nanotube film arranged between at least two metal members to face upwards with lateral pressure.

8. A carbon nanotube electron emitter, comprising:

a carbon nanotube film which is densified with a solvent or carbonized by adding a carbon-based material; and

at least two metal members arranged on respective sides of the carbon nanotube film and fixing the carbon nanotube film,

wherein an area of the carbon nanotube film is cut into a pointed shape or a line shape, and

wherein the metal members fix the cutting area of the carbon nanotube film to face upwards with lateral pressure.

9. The carbon nanotube electron emitter of claim 8 ,

wherein in the carbon nanotube electron emitter,

multiple carbon nanotube films are arranged in an array type and the metal member is arranged between the carbon nanotube films.

10. The carbon nanotube electron emitter of claim 8 ,

wherein the solvent includes at least any one of isopropyl alcohol (IPA), ethanol, and nitric acid, and

the densified carbon nanotube film is dipped in the solvent and then dried, and in the densified carbon nanotube film, a space between carbon nanotubes is reduced by removing sodium dodecyl sulfate (SDS) remaining between the carbon nanotubes, and, thus, bonding strength between the carbon nanotubes is increased.

11. The carbon nanotube electron emitter of claim 8 ,

wherein the carbon-based material includes at least one of graphite adhesive, carbon paste, and carbon nanotube (CNT) paste, and

the carbonized carbon nanotube film is prepared by performing heat treatment to the carbon-based material-added carbon nanotube film at a high temperature in a vacuum for a predetermined period of time, and in the carbonized carbon nanotube film, the added carbon-based material fills a space between carbon nanotubes, and, thus, bonding strength between the carbon nanotubes is increased.

Assignments (3)
CHANGE OF NAME Recorded Nov 3, 2025
From: LUMINAX CO., LTD.
To: LMX CO., LTD.
Reel/Frame 072761/0451 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 11, 2023
From: KOREA UNIVERSITY RESEARCH AND BUSINESS FOUNDATION
To: LUMINAX CO., LTD.
Reel/Frame 063281/0959 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 1, 2018
From: LEE, CHEOL JIN; LEE, SANG HEON; HAN, JUN-SOO
To: KOREA UNIVERSITY RESEARCH AND BUSINESS FOUNDATION
Reel/Frame 047384/0837 →
Priority Claims (1)
KR 10-2017-0121577 · Sep 21, 2017 · national
Continuity (1)
Related Publication 20190088437A1 · Mar 21, 2019