Separator for fuel cell, manufacturing method thereof, and fuel cell having such a separator
A lamellar structure graphite foil is used as a material for a separator for a fuel cell, and a hydrophobic layer is formed by impregnation on flow-field channels of the graphite foil. Such a separator is manufactured by forming the flow field channel by etching the graphite foil formed with the mask pattern thereon and forming a hydrophobic layer by impregnation. According to such a separator, performance of a fuel cell stack is enhanced and the manufacturing process of a separator is simplified.
1. A method for manufacturing a fuel cell having a separator for the fuel cell that is capable of closely contacting either an anode or a cathode of a membrane electrode assembly (MEA) of the fuel cell and interposing a fluid diffusion layer, the separator having a flow field channel for allowing a fluid to flow between the separator and the fluid diffusion layer, the method comprising:
preparing a graphite foil of a predetermined size;
forming a mask pattern on the graphite foil corresponding to the flow field channel;
forming the flow field channel on the graphite foil by etching the graphite foil formed with the mask pattern thereon;
forming a hydrophobic layer on an interior side of the flow field channel by impregnation; and
removing the mask pattern from the graphite foil,
wherein the flow field channel is defined by ribs and is formed as a groove,
wherein the hydrophobic layer is only formed on an interior side of the groove,
wherein the graphite foil comprises a stainless steel layer therewithin, and
wherein the stainless steel layer has a portion that is directly contacting the hydrophobic layer.
2. The method as claimed in claim 1 , wherein the forming of the mask pattern on the graphite foil comprises:
coating the graphite foil with a dry film resist;
exposing the coated graphite foil; and
developing the dry film resist on the graphite foil by moving a spray nozzle of a spray-type developing apparatus thereover.
3. The method as claimed in claim 2 , wherein the forming of the hydrophobic layer on the interior side of the flow field channel by impregnation comprises:
forming the hydrophobic layer on the graphite foil attached with the mask pattern and formed with the flow field channel; and
drying the graphite foil formed with the hydrophobic layer, in a temperature range of 50° C.−90° C.
4. The method as claimed in claim 3 , wherein, in the forming of the hydrophobic layer on the graphite foil, a hydrophobic solution is spray coated on a surface of the graphite foil, or the graphite foil is dipped in the hydrophobic solution.
5. The method as claimed in claim 1 , wherein the forming of the mask pattern on the graphite foil comprises attaching a mask on the graphite foil, the mask being provided with a pattern corresponding to the flow field channel and being made of rubber or stainless steel.
6. The method as claimed in claim 5 , wherein the forming of the hydrophobic layer on the interior side of the flow field channel by impregnation comprises:
forming the hydrophobic layer on the graphite foil attached with the mask pattern and formed with the flow field channel; and
drying the graphite foil formed with the hydrophobic layer, in a temperature range of 50° C.−90° C.
7. The method as claimed in claim 6 , wherein, in the forming of the hydrophobic layer on the graphite foil, a hydrophobic solution is spray coated on a surface of the graphite foil, or the graphite foil is dipped in the hydrophobic solution.
8. The method as claimed in claim 1 , wherein the forming of the flow field channel on the graphite foil comprises at least one of sandblasting and ultrasonic etching.
9. The method as claimed in claim 8 , wherein the forming of the hydrophobic layer on the interior side of the flow field channel by impregnation comprises:
forming the hydrophobic layer on the graphite foil attached with the mask pattern and formed with the flow field channel; and
drying the graphite foil formed with the hydrophobic layer, in a temperature range of 50° C.−90° C.
10. The method as claimed in claim 9 , wherein, in the forming of the hydrophobic layer on the graphite foil, a hydrophobic solution is spray coated on a surface of the graphite foil, or the graphite foil is dipped in the hydrophobic solution.
11. The method as claimed in one of claim 1 , wherein the forming of the hydrophobic layer on the interior side of the flow field channel by impregnation comprises:
forming the hydrophobic layer on the graphite foil attached with the mask pattern and formed with the flow field channel; and
drying the graphite foil formed with the hydrophobic layer, in a temperature range of 50° C.−90° C.
12. The method as claimed in claim 11 , wherein, in the forming of the hydrophobic layer on the graphite foil, a hydrophobic solution is spray coated on a surface of the graphite foil, or the graphite foil is dipped in the hydrophobic solution.
13. The method as claimed in claim 1 , wherein:
the flow field channel is formed on each of front and rear sides of the separator;
the mask pattern comprises a front mask pattern and a rear mask pattern;
at least one pair of aligning holes are formed at each of the front and rear mask patterns;
at least one aligning hole is formed through the graphite foil corresponding to the at least one pair of aligning holes of the mask patterns; and
the at least one pair of aligning holes of the mask patterns and the at least one aligning holes of the graphite foil are aligned by using at least one pair of aligning bars corresponding thereto.
14. The method as claimed in claim 13 , wherein the at least one pair of aligning holes and the at least one pair of aligning bars respectively comprise a plurality of pairs thereof, corresponding to different sizes.