IP Library Granted Patent US 11,130,893
Granted Patent B2
US 11,130,893 · App. 16/142,492 · Granted Sep 28, 2021

Heat transfer fluid

Inventor: Wissam Rached (Chaponost, FR)
Assignee: ARKEMA FRANCE
C09K5/045C08J9/146C10M171/008F25B31/002F25B45/00C09K2205/122C09K2205/126C09K2205/22C09K2205/40C09K2205/43C10M2203/003C10M2203/065C10M2209/043C10M2209/1033C10N2020/101C10N2040/30
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Quick Facts
Patent No.
US 11,130,893
App. No.
16/142,492
Granted
Sep 28, 2021
Kind
B2
Abstract

Compositions which are based on tetrafluoropropene and more particularly relates to compositions including 60% to 90% by weight of 2,3,3,3-tetrafluoropropene and 10% to 40% by weight of at least one compound selected from difluoroethane and difluoromethane, which can be used as a heat transfer fluid. The compositions may include 60% to 79% by weight of 2,3,3,3-tetrafluoropropene and 21% to 40% by weight of a compound selected from difluoroethane and difluoromethane.

Claims (16)

1. A method of replacing R-404A in a heat pump or air conditioner, the method comprising replacing a first heat transfer fluid of R-404A with a second heat-transfer fluid comprising a composition consisting of 60% to 65% by weight of 2,3,3,3-tetrafluoropropene and 35% to 40% by weight of difluoromethane, and optionally a stabilizer.

2. The method as claimed in claim 1 , wherein the composition consists of 60% by weight of 2,3,3,3-tetrafluoropropene and 40% of difluoromethane, and optionally a stabilizer.

3. The method as claimed in claim 1 , wherein the composition further contains the stabilizer.

4. The method as claimed in claim 3 , wherein the stabilizer is selected from the group consisting of nitromethane, ascorbic acid, terephthalic acid, azoles, phenolic compounds, epoxides, phosphites, phosphates, phosphonates, thiols and lactones.

5. The method as claimed in claim 3 , wherein stabilizer represents at most 5% by weight relative to the composition.

6. The method as claimed in claim 1 , wherein the second heat-transfer fluid further contains a lubricant.

7. The method as claimed in claim 6 , wherein the lubricant is selected from the group consisting of mineral oil, alkylbenzene, polyalkylene glycol and polyvinyl ether.

8. The method as claimed in claim 1 , wherein the composition consists of 65% by weight of 2,3,3,3-tetrafluoropropene and 35% of difluoromethane, and optionally a stabilizer.

9. A method of replacing R407C in a heat pump or air conditioner, the method comprising replacing a first heat transfer fluid of R407C with a second heat-transfer fluid comprising a composition consisting of 60% to 65% by weight of 1234yf and 35% to 40% by weight of R32, and optionally a stabilizer.

10. The method as claimed in claim 9 , wherein the composition consists of 60% by weight of 2,3,3,3-tetrafluoropropene and 40% of difluoromethane, and optionally a stabilizer.

11. The method as claimed in claim 9 , wherein the composition consists of 65% by weight of 2,3,3,3-tetrafluoropropene and 35% of difluoromethane, and optionally a stabilizer.

12. The method as claimed in claim 9 , wherein the composition further contains the stabilizer.

13. The method as claimed in claim 12 , wherein the stabilizer is selected from the group consisting of nitromethane, ascorbic acid, terephthalic acid, azoles, phenolic compounds, epoxides, phosphites, phosphates, phosphonates, thiols and lactones.

14. The method as claimed in claim 12 , wherein stabilizer represents at most 5% by weight relative to the composition.

15. The method as claimed in claim 9 , wherein the second heat-transfer fluid further contains a lubricant.

16. The method as claimed in claim 15 , wherein the lubricant is selected from the group consisting of mineral oil, alkylbenzene, polyalkylene glycol and polyvinyl ether.

Assignments (2)
CHANGE OF ADDRESS Recorded Jul 4, 2025
From: ARKEMA FRANCE
To: ARKEMA FRANCE
Reel/Frame 071814/0739 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 16, 2019
From: RACHED, WISSAM
To: ARKEMA FRANCE
Reel/Frame 048028/0576 →
Priority Claims (2)
FR 08.56817 · Oct 8, 2008 · national
FR 08.56836 · Oct 9, 2008 · national
Continuity (4)
Continuation 15396855 · Jan 3, 2017
Continuation 14873855 · Oct 2, 2015
Continuation 13122606
Related Publication 20190203094A1 · Jul 4, 2019
Cited By (4)
US 12,291,666 US 12,292,213 US 12,416,431 US 12,421,436