IP Library › Granted Patent US 11,535,437
Granted Patent B2
US 11,535,437 · App. 16/144,399 · Granted Dec 27, 2022

Gas barrier film

Inventors: Ryoji Ishii (Tokyo, JP); Takeshi Nishikawa (Tokyo, JP); Tadashi Hongo (Tokyo, JP)
Assignee: TOPPAN PRINTING CO., LTD.
B65D65/40B32B9/00B32B27/36C08J7/043C08J7/048C08J7/0423B05D7/04B32B2255/10B32B2255/20B32B2255/26B32B2255/28B32B2307/50B32B2307/7242B32B2307/7244B32B2307/7246B32B2307/734B32B2367/00B32B2439/70B32B2439/80C08J2367/02C08J2367/03C08J2429/04C08J2483/02C08L29/04C08L83/02C08L2201/14C08L2203/16C09D129/04C09D183/02Y10T428/31786
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Quick Facts
Patent No.
US 11,535,437
App. No.
16/144,399
Granted
Dec 27, 2022
Kind
B2
Abstract

A gas barrier film that includes at least a film base material including a polyester resin having a butylene terephthalate unit as a main constituent unit, and one or more metal oxide layers wherein the gas barrier film has a heat shrinkage rate in the machine direction (MD direction) after heating for 30 minutes at 150° C. of 0.6% or more but less than 3.0%, the heat shrinkage rate being represented by the following formula: Heat shrinkage rate={(Length before heating−Length after heating)/Length before heating}×100(%).

Claims (24)

1. A gas barrier film, comprising:

a single layer polyester resin film base material consisting of polybutylene terephthalate or a mixture of polybutylene terephthalate and polyethylene terephthalate with a content of the polybutylene terephthalate in the mixture being 60% mass or more, the polyester resin film base material has a first surface and a second surface, which is opposite to the first surface;

an anchor layer directly on the first surface of the single layer polyester resin film base material;

an AlO x layer or a SiO x layer having a thickness of no less than 5 nm and no greater than 100 nm directly on the anchor layer; and

a gas barrier protective layer on the AlO x layer or on the SiO x layer, the gas barrier protective layer comprises a hydrolysate of a metal alkoxide and polyvinyl alcohol,

wherein the gas barrier film has a heat shrinkage rate in the machine direction (MD direction) after heating for 30 minutes at 150° C. of 0.6% or more but less than 3.0%, the heat shrinkage rate being represented by the following formula:

Heat shrinkage rate={(Length before heating−Length after heating)/Length before heating}×100(%).

2. The gas barrier film of claim 1 , wherein a thickness of the film base material is no less than 6 μm and no greater than 200 μm.

3. The gas barrier film of claim 1 , wherein a puncture strength of the film base material is 8.5 N or more.

4. The gas barrier film of claim 1 , wherein the metal alkoxide is tetraethoxysilane.

5. The gas barrier film of claim 4 , wherein the polyester resin film base material consists of the mixture of polybutylene terephthalate and polyethylene terephthalate.

6. The gas barrier film of claim 5 , wherein the heat shrinkage rate in the machine direction (MD direction) of the gas barrier film is from 0.9% to 2.3%.

7. The gas barrier film of claim 1 , wherein the anchor layer consists of acrylic urethane resin or polyester polyurethane resin.

8. The gas barrier film of claim 1 , wherein the metal alkoxide is tetraethoxysilane and triisopropoxy aluminum.

9. A gas barrier film, comprising:

a single layer polyester resin film base material consisting of polybutylene terephthalate or a mixture of polybutylene terephthalate and polyethylene terephthalate with a content of the polybutylene terephthalate in the mixture being 60% mass or more, the polyester resin film base material has a first surface and a second surface, which is opposite to the first surface;

an anchor layer directly on the first surface of the single layer polyester resin film base material; and

an AlO x layer or a SiO x layer having a thickness of no less than 5 nm and no greater than 100 nm directly on the anchor layer; and

a gas barrier protective layer on the AlO x layer or the SiO x layer; the gas barrier protective layer comprises a hydrolysate of a metal alkoxide and polyvinyl alcohol,

wherein the gas barrier film has a tensile elasticity modulus within a range of 2.0 to 4.0 GPa, and a heat shrinkage rate in the machine direction (MD direction) after heating for 30 minutes at 150° C. of 0.6% or more but less than 3.0%, the heat shrinkage rate being represented by the following formula:

Heat shrinkage rate={(Length before heating−Length after heating)/Length before heating}×100(%).

10. The gas barrier film of claim 9 , wherein the metal alkoxide is tetraethoxysilane.

11. The gas barrier film of claim 9 , wherein the anchor layer consists of acrylic urethane resin or polyester polyurethane resin.

12. The gas barrier film of claim 9 , wherein the metal alkoxide is tetraethoxysilane and triisopropoxy aluminum.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 27, 2018
From: ISHII, RYOJI; NISHIKAWA, TAKESHI; HONGO, TADASHI
To: TOPPAN PRINTING CO., LTD.
Reel/Frame 046999/0102 →
Priority Claims (2)
JP JP2016-074559 · Apr 1, 2016 · national
JP JP2016-195590 · Oct 3, 2016 · national
Continuity (2)
Continuation PCTJP2017012694 · Mar 28, 2017
Related Publication 20190023468A1 · Jan 24, 2019