Adhesive material and pressure-bonded print
An adhesive material contains a styrene resin, a (meth)acrylate resin, and an oxidatively polymerizable compound, wherein the adhesive material has a sea-island structure that includes a sea portion containing the styrene resin and an island portion containing the (meth)acrylate resin, and the glass transition temperature of the (meth)acrylate resin is at least 30° C. lower than the glass transition temperature of the styrene resin.
1. An adhesive material comprising:
a binder resin; and
an oxidatively polymerizable compound, wherein
the binder resin includes a styrene resin and a (meth)acrylate resin,
a content proportion of a total mass of the styrene resin and the (meth)acrylate resin is 85 mass % when a total mass of the binder resin is considered to be 100 mass %,
the adhesive material has a sea-island structure that includes a sea portion containing the styrene resin and an island portion containing the (meth)acrylate resin,
a glass transition temperature of the (meth)acrylate resin is at least 30° C. lower than a glass transition temperature of the styrene resin, and
an amount of the oxidatively polymerizable compound is in a range of 5 parts by mass to 30 parts by mass relative to 100 parts by mass of a total amount of the styrene resin, the (meth)acrylate resin, and the oxidatively polymerizable compound.
2. The adhesive material according to claim 1 , wherein the oxidatively polymerizable compound is selected from the group consisting of a phenol derivative in which an aliphatic hydrocarbon group having an ethylenic double bond is bonded to a phenol and a drying oil.
3. Adhesive material according to claim 2 , wherein the oxidatively polymerizable compound is a drying oil.
4. The adhesive material according to claim 3 , wherein
a complex modulus of the adhesive material at 60° C. is in a range of 5×10 6 Pa to 5×10 8 Pa, which is measured by a rheometer under a condition that the adhesive material is pressured at 30 MPa and left to stand for 5 hours.
5. The adhesive material according to claim 4 , wherein the adhesive material is used to produce a pressure-bonded print.
6. The adhesive material according to claim 4 , wherein a content of the allyl group is from 1 mmol % to 20 mmol %.
7. The adhesive material according to claim 1 , wherein a mass ratio of the (meth)acrylate resin to the styrene resin is 0.25 or more and less than 1.5.
8. The adhesive material according to claim 7 , wherein the amount of the oxidatively polymerizable compound is in a range of 10 parts by mass to 20 parts by mass.
9. The adhesive material according to claim 1 , wherein a complex modulus of the adhesive material at 60° C. is in the range of 5×10 6 Pa to 5×10 8 Pa, which is measured by a rheometer under a condition that the adhesive material is pressured at 30 MPa and left to stand for 5 hours.
10. The adhesive material according to claim 1 , wherein the adhesive material is used to produce a pressure-bonded print.
11. The adhesive material according to claim 1 , wherein the (meth)acrylate resin comprises a monomer having an allyl group.
12. The adhesive material according to claim 11 , wherein a content of the allyl group in the (meth)acrylate resin is from 1 mmol % to 20 mmol %.
13. The adhesive material according to claim 11 , wherein a content of the allyl group in the styrene resin is from 1 mmol % to 20 mmol %.
14. The adhesive material according to claim 1 , wherein the styrene resin comprises a monomer having an allyl group.
15. A pressure-bonded print comprising:
two substrates; and
the adhesive material according to claim 1 disposed between the two substrates.
16. The pressure-bonded print according to claim 15 , wherein the oxidatively polymerizable compound used in the adhesive material is selected from the group consisting of a phenol derivative in which an aliphatic hydrocarbon group having an ethylenic double bond is bonded to a phenol and a drying oil.
17. The pressure-bonded print according to claim 15 , wherein a mass ratio of the (meth)acrylate resin to the styrene resin is 0.25 or more and less than 1.5 in the adhesive material, and
an amount of the oxidatively polymerizable compound is in a range of 5 parts by mass to 30 parts by mass relative to 100 parts by mass of a total amount of the styrene resin, the (meth)acrylate resin, and the oxidatively polymerizable compound.
18. The pressure-bonded print according to claim 15 , wherein a complex modulus of the adhesive material at 60° C. is in a range of 5×10 6 Pa to 5×10 8 Pa, which is measured by a rheometer under a condition that the adhesive material is pressured at 30 MPa and left to stand for 5 hours.
19. A pressure-bonded print comprising:
a folded substrate; and
the adhesive material according to claim 1 disposed on the folded inside of the substrate.