Composition including quantum dot, manufacturing method quantum dot and color filter
A photosensitive resin composition includes: (A) a binder resin; (B) a photopolymerizable monomer; (C) a photopolymerization initiator; (D) a quantum dot surface-modified with a compound having a thiol group at one terminal end and an alkoxy group, a cycloalkyl group, a carboxyl group, or a hydroxy group at the other terminal end; and (E) a solvent. A curable composition includes: (A′) a resin; (B′) a quantum dot surface-modified with a compound represented by Chemical Formula 1 or Chemical Formula 2; and (C′) a solvent. A method of manufacturing the surface-modified quantum dot, and a color filter manufactured using the photosensitive resin composition or the curable composition are also disclosed.
1. A curable composition comprising:
(A′) a resin;
(B′) a quantum dot surface-modified with a compound represented by Chemical Formula 1 or Chemical Formula 2; and
(C′) a solvent:
wherein, in Chemical Formula 1 and Chemical Formula 2,
R 1 is a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C1 to C20 alkoxy group, a substituted or unsubstituted C3 to C20 cycloalkyl group, a substituted or unsubstituted C6 to C20 aryl group, or a substituted or unsubstituted lactone ring,
L 1 and L 2 are independently a single bond, a substituted or unsubstituted C1 to C20 alkylene group, a substituted or unsubstituted C1 to C20 oxyalkylene group, or a combination thereof, and
n is an integer of 1 or 2, and
wherein the curable composition comprises 1 wt % to 30 wt % of the resin, 1 wt % to 40 wt % of the surface-modified quantum dot, and 20 wt % to 80 wt % of the solvent based on the total amount of the curable composition, and
wherein the curable composition further comprises a diffusion agent.
2. The curable composition of claim 1 , wherein the lactone ring is a 5-membered ring or a 6-membered ring.
3. The curable composition of claim 1 , wherein in Chemical Formula 2, L 2 is a C1 to C20 alkylene group substituted with a thiol group.
4. The curable composition of claim 1 , wherein the substituted or unsubstituted C1 to C20 oxyalkylene group is a substituted or unsubstituted oxymethylene group, a substituted or unsubstituted oxyethylene group, or a combination thereof.
5. The curable composition of claim 4 , wherein the oxymethylene group is represented by Chemical Formula 3 and the oxyethylene group is represented by Chemical Formula 4:
wherein, in Chemical Formula 3 and Chemical Formula 4,
m is an integer of 1 to 5.
6. The curable composition of claim 1 , wherein Chemical Formula 1 is represented by one of Chemical Formula 1-1 to Chemical Formula 1-7 and Chemical Formula 2 is represented by Chemical Formula 2-1:
in Chemical Formula 1-3 to Chemical Formula 1-6, m is an integer of 1 to 5,
7. The curable composition of claim 1 , wherein the surface-modified quantum dot has a core-shell structure wherein the shell comprises Zn, and the thiol group at the terminal end of the compound represented by Chemical Formula 1 or Chemical Formula 2 is bonded with Zn of the shell.
8. The curable composition of claim 1 , wherein the quantum dot has a maximum fluorescence wavelength in a wavelength range of 500 nm to 680 nm.
9. The curable composition of claim 1 , wherein the solvent comprises propylene glycol monomethylether acetate, dipropylene glycol methylether acetate, ethanol, ethylene glycoldimethylether, ethylene diglycolmethylethylether, diethylene glycoldimethylether, dimethyl acetamide, 2-butoxyethanol, N-methylpyrrolidine, N-ethylpyrrolidine, propylene carbonate, γ-butyrolactone, or a combination thereof.
10. The curable composition of claim 1 , wherein the resin comprises at least one of a binder resin and an reactive unsaturated compound.
11. The curable composition of claim 10 , wherein the binder resin comprises an acryl-based resin, an epoxy resin, or a combination thereof.
12. The curable composition of claim 1 , wherein the diffusion agent is included in an amount of 0.1 wt % to 20 wt % based on the total amount of the curable composition.
13. The curable composition of claim 1 , wherein the diffusion agent comprises barium sulfate, calcium carbonate, titanium dioxide, zirconia, or a combination thereof.
14. The curable composition of claim 1 , wherein the curable composition further comprises a polymerization initiator.
15. The curable composition of claim 14 , wherein the polymerization initiator comprises a cation initiator.
16. The curable composition of claim 1 , wherein the curable composition further comprises malonic acid; 3-amino-1,2-propanediol; a silane-based coupling agent; a leveling agent; a fluorine-based surfactant; a polymerization inhibitor; or a combination thereof.
17. A method of manufacturing a pixel for a color filter, comprising:
coating the curable composition of claim 1 on a substrate utilizing an inkjet spraying method to form a pattern; and
curing the pattern.
18. A color filter comprising a pixel for a color filter manufactured according to the method of manufacturing the pixel of claim 17 .