Polyethylene compositions and films made therefrom
Provided herein are polyethylene compositions with broad orthogonal composition distribution. The polyethylene compositions may comprise at least 65 wt % ethylene-derived units and from 0 to 35 wt % of C 3 to C 12 olefin comonomer-derived units, and furthermore may exhibit a reversed comonomer index (RCI,m) of 100 kg/mol or greater, a Tw 1 -Tw 2 value of from −16 to −38° C., and an Mw 1 /Mw 2 value of at least 0.9, such as 0.9 to 4. Also provided are processes for making the polyethylene compositions, as well as films made from the polyethylene compositions. Such films may feature superior film stiffness for a given polyethylene composition density, and accordingly such films in some embodiments have average MD/TD modulus and density satisfying the following equation: Avg. Modulus≥1.2*(C1*Density−C2), where C1 and C2 are constants, such as C1=2,065,292 and C2=1,872,345.
1. A polyethylene composition comprising at least 65 wt % ethylene derived units and from 0 to 35 wt % of C 3 -C 12 olefin comonomer derived units, based upon the total weight of the polyethylene composition, wherein the polyethylene composition has:
a) an RCI,m of 125 kg/mol or greater;
b) an internal unsaturation as measured by 1H NMR less than 0.30 total internal unsaturations per thousand carbon atoms;
c) a Tw 1 -Tw 2 value of from −16 to −38° C.;
d) an Mw 1 /Mw 2 value within the range from 0.9 to 4; and
one or more of the following:
e) a density of from 0.890 g/cm3 to 0.940 g/cm 3 ;
f) a melt index (MI) of from 0.1 g/10 min to 30 g/10 min;
g) a melt index ratio (I 21 /I 2 ) of from 10 to 90;
h) an M w /M n of from 2 to 12;
i) an M z /M w of from 2.2 to 5.0;
j) an M z /M n of from 10 to 40; and
k) a g′ (vis) of 0.990 or less.
2. The polyethylene composition of claim 1 , wherein the polyethylene composition comprises from 0.5 to 20 wt % of the C 3 -C 12 olefin comonomer derived units, based upon the total weight of the polyethylene composition.
3. The polyethylene composition of claim 1 , wherein the polyethylene composition has a Tw 1 -Tw 2 value of from −23 to −36° C.
4. The polyethylene composition of claim 1 , wherein the polyethylene composition has a Tw 1 -Tw 2 value of from −23 to −33° C.
5. The polyethylene composition of claim 1 , wherein the polyethylene composition has an Mw 1 /Mw 2 value of from 1.25 to 4.
6. The polyethylene composition of claim 1 , wherein the polyethylene composition has a melt index (MI) of from 0.1 g/10 min to 6 g/10 min.
7. The polyethylene composition of claim 1 , wherein the polyethylene composition has a melt index ratio (I 21 /I 2 ) of from 20 to 45.
8. The polyethylene composition of claim 1 , wherein the polyethylene composition has an M w /M n of from 5 to 10.
9. The polyethylene composition of claim 1 , wherein the polyethylene composition has a g′(vis) of 0.989 or less.
10. The polyethylene composition of claim 1 , wherein the polyethylene composition has a density of from 0.912 g/cm3 to 0.922 g/cm3.
11. The polyethylene composition of claim 1 , wherein the internal unsaturation of the polyethylene composition as measured by 1 H NMR is less than 0.20 total internal unsaturations per thousand carbon atoms.
12. The polyethylene composition of claim 1 , wherein the internal unsaturation of the polyethylene composition as measured by 1 H NMR is less than 0.10 total internal unsaturations per thousand carbon atoms.
13. A film made from the polyethylene composition of claim 1 , wherein the film has:
i) a relationship between MD/TD modulus and density that satisfies the following equation:
Avg. Modulus≥1.2*(2,065,292*Density−1,872,345); and
ii) a seal initiation temperature at 1 N of ≤98.0° C.
14. The film of claim 13 , wherein the film is a blown film or cast film.
15. The film of claim 13 , wherein the seal initiation temperature at 1 N is ≤97.0° C.
16. The film of claim 13 , wherein the seal initiation temperature at 1 N is ≤95.0° C.
17. The film of claim 13 , wherein the seal initiation temperature at 5 N is ≤102.0° C.
18. The film of claim 13 , wherein the seal initiation temperature at 5 N is ≤100.0° C.
19. The film of claim 13 , wherein the seal initiation temperature at 5 N is ≤99.0° C.
20. The film of claim 13 , wherein the film exhibits an average 1% secant MD/TD modulus of 35,000 psi or greater.
21. The film of claim 13 , wherein the film exhibits an average 1% secant MD/TD modulus of 40,000 psi or greater.
22. The film of claim 13 , wherein the film has a dart drop impact resistance of 200 g/mil or greater.