IP Library Granted Patent US 10,252,114
Granted Patent B1
US 10,252,114 · App. 16/164,661 · Granted Apr 9, 2019

Graphene core for a golf ball with a soft cover

Inventors: Petra Petrich (Escondido, CA); David Bartels (Carlsbad, CA); Hong G. Jeon (Carlsbad, CA); Carl Brown (Temecula, CA)
Assignee: Callaway Golf Company
A63B37/0051A63B37/0031A63B37/0033A63B37/0043A63B37/0045A63B37/0065A63B37/0069A63B37/0074A63B37/0075A63B37/0076A63B37/0092C01B32/182C08F36/06C08K3/042C08L9/00
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Quick Facts
Patent No.
US 10,252,114
App. No.
16/164,661
Granted
Apr 9, 2019
Kind
B1
Abstract

A golf ball with a core comprising polybutadiene and graphene, and a soft cover is disclosed herein. The golf ball has a dual core with an outer core comprising polybutadiene and graphene. The soft cover is preferably composed of a highly neutralized polymer, a first ionomer, a second ionomer, and a paraloid impact modifier.

Claims (31)

1. A golf ball comprising:

an inner core comprising a polybutadiene material;

an outer core comprising polybutadiene material and a graphene material in an amount ranging from 0.1 to 5.0 weight percent of the outer core, wherein the outer core has a flexural modulus ranging from 80 MPa to 95 MPa; and

a cover layer disposed over the outer core, the cover layer comprising 30 to 40 wt % of a highly neutralized polymer, 10 to 20 wt % of a first ionomer, 10 to 20 wt % of a second ionomer, 15 to 25 wt % of a masterbatch comprising from 20 to 50 wt % of a paraloid impact modifier, and 5 to 15 wt % of a color masterbatch;

wherein a dual core comprising the inner core and the outer core has a compression value ranging from 40 to 55.

2. The golf ball according to claim 1 wherein the graphene material ranges from 0.4 to 2.5 weight percent of the outer core.

3. The golf ball according to claim 1 wherein the graphene material ranges from 0.6 to 1.5 weight percent of the outer core.

4. The golf ball according to claim 1 wherein the graphene material has a surface area ranging from 400 m 2 /g to 800 m 2 /g.

5. The golf ball according to claim 1 wherein the cover layer has a Shore D hardness ranging from 35 to 60.

6. The golf ball according to claim 1 wherein the outer core has a tensile modulus ranging from 8 MPa to 10 MPa.

7. The golf ball according to claim 1 wherein the graphene material has a surface area ranging from 15 m 2 /g to 50 m 2 /g.

8. The golf ball according to claim 1 wherein the graphene material has a surface area ranging from 300 m 2 /g to 400 m 2 /g.

9. A golf ball comprising:

an inner core comprising a polybutadiene and a graphene material in an amount ranging from 0.1 to 5.0 weight percent of the inner core;

an outer core comprising a polybutadiene and a graphene material in an amount ranging from 0.1 to 5.0 weight percent of the outer core, wherein the outer core has a flexural modulus ranging from 80 MPa to 95 MPa; and

a cover layer disposed over the outer core, the cover layer comprising 30 to 45 wt % of a highly neutralized polymer, 10 to 20 wt % of a first ionomer, 10 to 20 wt % of a second ionomer, and 15 to 25 wt % of a masterbatch comprising from 20 to 50 wt % of a paraloid impact modifier;

wherein a dual core comprising the inner core and the outer core has a compression value ranging from 40 to 55.

10. The golf ball according to claim 9 wherein the paraloid impact modifier is at least one of acrylonitrile-butadiene-styrene polymer (ABS), methyl methacrylate-butadiene-styrene polymer (MBS) impact-property modifiers for poly(vinyl chloride), and acrylic/methacrylic core-shell modifiers for polycarbonate.

11. The golf ball according to claim 9 wherein the graphene material in the outer core ranges from 0.4 to 2.5 weight percent of the outer core, and wherein the graphene material in the inner core ranges from 0.4 to 2.5 weight percent of the inner core.

12. The golf ball according to claim 9 wherein the outer core has a tensile modulus ranging from 8 MPa to 10 MPa.

13. The golf ball according to claim 9 wherein the graphene material has a surface area ranging from 15 m 2 /g to 50 m 2 /g.

14. The golf ball according to claim 9 wherein the graphene material has a surface area ranging from 300 m 2 /g to 400 m 2 /g.

15. The golf ball according to claim 9 wherein the graphene material has a surface area ranging from 400 m 2 /g to 800 m 2 /g.

16. A golf ball comprising:

an inner core comprising a polybutadiene and a graphene material in an amount ranging from 0.1 to 5.0 weight percent of the inner core;

an outer core comprising a polybutadiene and a graphene material in an amount ranging from 0.1 to 5.0 weight percent of the outer core, wherein the outer core has a flexural modulus ranging from 80 MPa to 95 MPa;

a mantle layer; and

a cover layer disposed over the mantle layer, the cover layer comprising 30 to 40 wt % of a highly neutralized polymer, 10 to 20 wt % of a first ionomer, 10 to 20 wt % of a second ionomer, 3- to 20 wt % of a paraloid impact modifier;

wherein the cover layer has a thickness ranging from 0.025 inch to 0.055 inch;

wherein the cover layer has a Shore D hardness ranging from 35 to 60;

wherein a dual core comprising the inner core and the outer core has a compression value ranging from 40 to 55.

Assignments (7)
SECURITY INTEREST Recorded May 17, 2023
From: TOPGOLF CALLAWAY BRANDS CORP.; OGIO INTERNATIONAL, INC.; TOPGOLF INTERNATIONAL, INC.; TRAVISMATHEW, LLC; WORLD GOLF TOUR, LLC
To: BANK OF AMERICA, N.A.
Reel/Frame 063692/0009 →
SECURITY AGREEMENT Recorded May 16, 2023
From: TOPGOLF CALLAWAY BRANDS CORP. (FORMERLY CALLAWAY GOLF COMPANY); OGIO INTERNATIONAL, INC.; TOPGOLF INTERNATIONAL, INC.; TRAVISMATHEW, LLC; WORLD GOLF TOUR, LLC
To: BANK OF AMERICA, N.A, AS COLLATERAL AGENT
Reel/Frame 063665/0176 →
RELEASE (REEL 048172 / FRAME 0001) Recorded Mar 17, 2023
From: BANK OF AMERICA, N.A.
To: TOPGOLF CALLAWAY BRANDS CORP. (F/K/A CALLAWAY GOLF COMPANY); OGIO INTERNATIONAL, INC.
Reel/Frame 063622/0187 →
CHANGE OF NAME Recorded Jan 25, 2023
From: CALLLAWAY GOLF COMPANY
To: TOPGOLF CALLAWAY BRANDS CORP.
Reel/Frame 062512/0585 →
SECURITY INTEREST Recorded Jan 23, 2019
From: CALLAWAY GOLF COMPANY; CALLAWAY GOLF SALES COMPANY; CALLAWAY GOLF BALL OPERATIONS, INC.; OGIO INTERNATIONAL, INC.; CALLAWAY GOLF INTERACTIVE, INC.; CALLAWAY GOLF INTERNATIONAL SALES COMPANY; TRAVISMATHEW, LLC
To: BANK OF AMERICA, N.A.
Reel/Frame 048110/0352 →
SECURITY AGREEMENT Recorded Jan 4, 2019
From: CALLAWAY GOLF COMPANY; OGIO INTERNATIONAL, INC.
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 048172/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 18, 2018
From: PETRICH, PETRA; BARTELS, DAVID; JEON, HONG G.; BROWN, CARL
To: CALLAWAY GOLF COMPANY
Reel/Frame 047223/0371 →
Continuity (6)
Continuation In Part 16054703 · Aug 3, 2018
Continuation 15705011 · Sep 14, 2017
Continuation In Part 15436169 · Feb 17, 2017
Provisional Application 62401034 · Sep 28, 2016
Provisional Application 62693220 · Jul 2, 2018
Provisional Application 62695645 · Jul 9, 2018
Cited By (1)
US 12,623,121