Aqueous solution containing aluminum ions, lactate ions, and phosphate ions, and a method for their production
The invention relates to an aqueous solution containing aluminum ions, characterized in that the solution contains aluminum ions in a proportion of 0.5-15% (converted, if necessary, to Al 3+ ) based on the total mass of the solution, as well as anions of lactic acid (lactate ions) and of phosphoric acid (phosphate ions), and has the theoretical composition Al 3+ A (C 3 H 5 O 3 − ) x.A S M− y.A (H 2 PO 4 − ) z.A (OH) − (3A-x.A-M.y.A-z.A) , wherein S is the anion of an acid with the charge M, x is a value in the range of 0.5-2.8, y is a value in the range of 0-1.5, and z is a value in the range of 0.01-1.5.
1. An aqueous solution comprising aluminum ions, wherein the solution comprises aluminum ions in a proportion of 1.5% -15% by weight (converted to Al 3+ ) based on the total mass of the solution, as well as anions of lactic acid (lactate ions) and of phosphoric acid (phosphate ions), wherein the molar proportion of the lactate ions is in the range of 0.01-2.99 times the molar proportion of Al 3+ , and the molar proportion of phosphate ions is in the range of 0.01-2.99 times the molar proportion of Al 3+ .
2. The aqueous solution according to claim 1 , wherein the solution further comprises an anion of at least a third acid.
3. The aqueous solution according to claim 2 , wherein the third acid is selected from a group consisting of an amino acid, carboxylic acid, citric acid, tartaric acid, malic acid, oxalic acid, glycolic acid, succinic acid, gluconic acid, glycine, acetic acid, sulfuric acid, and combinations thereof.
4. The aqueous solution according to claim 1 , wherein the solution comprises at least one additional cation, wherein the cation is selected from a group consisting of alkali metal ions, alkali earth ions, ammonium ions, cations of one or a plurality of transition or rare earth metals, and combinations thereof.
5. The aqueous solution according to claim 4 , wherein the cation is selected from a group consisting of Na + , K + , Ca 2+ , Mg 2+ , Zr 2+ , NH 4 + , and combinations thereof.
6. The aqueous solution according to claim 1 , wherein the solution comprises clusters which include the compound
Al 3+ A (C 3 H 5 O 3 − ) x⋅A S M− y⋅A (H 2 PO 4 − ) z⋅A (OH) − (3A-x⋅A-M⋅y⋅A-z⋅A) ,
wherein S is an anion of an optionally present third acid with the charge M,
x is a value in the range of 0.01-2.99,
y is a value in the range of 0-2.8, and
z is a value in the range of 0.05-2.9.
7. The aqueous solution according to claim 6 , wherein (3A-x⋅A-M⋅y⋅A-z⋅A) is >0.
8. The aqueous solution according to claim 6 , wherein x is a value in the range of 1.0-1.5.
9. The aqueous solution according to claim 6 , wherein y is a value in the range of 0-1.0.
10. The aqueous solution according to claim 6 , wherein z is a value in the range of 0.3-1.25.
11. The aqueous solution according to claim 1 , wherein the solution is stable in a temperature range of 0° C.-80° C.
12. The aqueous solution according to claim 11 , wherein the solution is stable in storage at a temperature of <30° C. for a period >one month.
13. The aqueous solution according to claim 11 , wherein the solution is stable in storage at a temperature of <10° C. for a period >12 months.
14. A method for creating an aqueous solution, wherein the solution comprises aluminum ions in a proportion of 1.5%-15% by weight (converted to Al 3+ ) based on the total mass of the solution, as well as anions of lactic acid (lactate ions) and of phosphoric acid (phosphate ions), wherein the molar proportion of the lactate ions is in the range of 0.01-2.99 times the molar proportion of Al 3+ and the molar proportion of phosphate ions is in the range of 0.01-2.99 times the molar proportion of Al 3+ , said method comprising the following steps:
a) providing water in a reaction vessel;
b) adding a basic aluminum salt into the reaction vessel while stirring;
c) adding a lactic acid and/or a lactate and, in parallel or offset in time, adding a phosphoric acid and/or a phosphate;
d) stirring the resulting mixture, wherein the sequence for performing the steps b) and c) is discretionary.
15. The method according to claim 14 , wherein clusters of the compound Al 3+ A (C 3 H 5 O 3 − ) x⋅A S M− y⋅A (H 2 PO 4 − ) z⋅A (OH) − ( 3 A-x⋅A-M⋅y⋅A-z⋅A) are created,
wherein S is an anion of an optionally present third acid with the charge M,
x is a value in the range of 0.01-2.99,
y is a value in the range of 0-2.8, and
z is a value in the range of 0.05-2.9.
16. The method according to claim 14 , wherein step c) is performed at a temperature >25° C.
17. The method of claim 16 wherein step c) is performed at a temperature at 60-70° C.
18. The method of claim 16 wherein step c) is performed under reflux.
19. The method according to claim 14 , further comprising a filtration step after step c).
20. The method of claim 14 , wherein the basic aluminum salt is selected from a group consisting of Al carbonate, Al hydroxide, Al oxide, an aluminate, and combinations thereof.