Cathode active material for lithium secondary battery and lithium secondary battery comprising the same
The present invention relates to a cathode active material composition for a lithium secondary battery and a lithium secondary battery including the same, and more particularly, to a cathode active material composition for a lithium secondary battery, including a mixture of particles which are different in Ni composition and size and prepared at the same heat treatment temperature, and a lithium secondary battery including the same. According to the present invention, optimal capacity manifestation temperatures of a coarse particle and a fine particle may be adjusted to be similar by adjusting an Ni content of the coarse particle and the fine particle, and thus, a lithium secondary battery having enhanced output and lifetime may be manufactured.
1. A cathode active material composition including particle 1 represented by Chemical Formula 1 below and particle 2 represented by Chemical Formula 2 below:
Li a1 Ni x1 Co y1 Mn z1 M 1-x1-y1-z1 O 2 [Chemical Formula 1]
Li a2 Ni x2 Co y2 Mn z2 M 1-x2-y2-z2 O 2 [Chemical Formula 2]
(where 0.8≤x1≤0.99, 0.8≤x2≤0.98, 0.5≤a1≤1.5, 0.5≤a2≤1.5, 0.0≤y1≤0.3, 0.0≤y2≤0.3, 0.0≤z1≤0.3, 0.0≤z2≤0.3, 0.0≤1−x1−y1−z1≤0.3, 0.0≤1−x2−y2−z2≤0.3, and
M is one or more elements selected from the group consisting of B, Ba, Ce, Cr, F, Mg, Al, Cr, V, Ti, Fe, Zr, Zn, Si, Y, Nb, Ga, Sn, Mo, W, P, Sr, and combination thereof),
wherein a size of the particle 1 represented by Chemical Formula 1 is greater than a size of the particle 2 represented by Chemical Formula 2,
wherein x1 and x2 satisfy the condition of 0.01≤(x1−x2)<0.1, and
wherein the particle 2 is mixed in a ratio of 5 to 40 wt % with respect to a total weight of the cathode active material composition.
2. The cathode active material composition of claim 1 , wherein
the size of the particle 1 represented by Chemical Formula 1 is 6 um to 30 um and the size of the particle 2 represented by Chemical Formula 2 is 1 um to 6 um.
3. A lithium secondary battery comprising a cathode active material composition according to claim 2 .
4. A lithium secondary battery comprising a cathode active material composition according to claim 1 .
5. A method for preparing a cathode active material composition, the method comprising:
preparing a first precursor represented by Chemical Formula 3 below and a second precursor represented by Chemical Formula 4 below and mixing the first and second precursors to prepare a precursor composition;
Ni x1 Co y1 Mn z1 M 1-x1-y1-z1 ( OH ) 2 [Chemical Formula 3]
Ni x2 Co y2 Mn z2 M 1-x2-y2-z2 ( OH ) 2 [Chemical Formula 4]
(where 0.8≤x1≤0.99, 0.8≤x2≤0.98, 0.0≤y1≤0.3, 0.0≤z1≤0.3, 0.0≤1−x1−y1−z1≤0.3, 0.0≤y2≤0.3, 0.0≤z2≤0.3, and 0.0≤1−x2−y2−z2≤0.3,
M is one or more elements selected from the group consisting of B, Ba, Ce, Cr, F, Mg, Al, Cr, V, Ti, Fe, Zr, Zn, Si, Y, Nb, Ga, Sn, Mo, W, P, Sr, and combinations thereof),
wherein x1 and x2 satisfy the condition of 0.01≤(x1−x2)<0.1,
wherein in the mixing of the precursor composition, the second precursor is mixed in a ratio of 5 to 40 wt % with respect to a total weight of the precursor composition, and
wherein the size of the first precursor particle represented by the chemical formula 3 is larger than the size of the second precursor particle represented by the chemical formula 4;
mixing a lithium compound and the precursor composition and performing a first heat-treatment on the mixture at a first temperature;
mixing one or more elements selected from the group consisting of B, Ba, Ce, Cr, F, Mg, Al, Cr, V, Ti, Fe, Zr, Zn, Si, Y, Nb, Ga, Sn, Mo, W, P, Sr, and combinations thereof to the mixture of the lithium compound and the precursor composition and performing a second heat-treatment on the mixture at a second temperature; and
rinsing the second heat-treated mixture with distilled water and drying the rinsed mixture.
6. The method of claim 5 , wherein
a size of the first precursor particle represented by Chemical Formula 3 above is 6 um to 30 um, and a size of the second precursor particle represented by Chemical Formula 4 above is 1 um to 6 um.