Method for separation of acids and sugars to reduce energy consumption
The present disclosure relates to a method for separating sugars and acids with reduced energy consumption, including a step of diffusively dialyzing a first acid hydrolysate obtained by saccharifying biomass with an acid solution, thereby preparing a second acid hydrolysate wherein the concentration of the acid solution contained in the acid hydrolysate is decreased; and a step of electrolyzing the second acid hydrolysate, thereby separating sugars from the acid solution, which is advantageous in that less energy is consumed, the separated acid solution can be recycled directly without further treatment due to high concentration and loss of sugars can be minimized.
1. A method for separating sugars and acids with reduced energy consumption, comprising:
diffusively dialyzing a first acid hydrolysate obtained by saccharifying biomass with an acid solution, thereby preparing a second acid hydrolysate wherein the concentration of the acid solution comprised in the acid hydrolysate is decreased; and
electrolyzing the second acid hydrolysate, thereby separating sugars from the acid solution,
wherein the diffusion dialysis is performed using a diffusion dialyzer in which an acid hydrolysate inflow tank and a water tank are separated by an anion-exchange membrane and the reaction is performed continuously as the first acid hydrolysate is added to the acid hydrolysate inflow tank and water is added to the water tank, and
wherein a mesh is provided at a center of the acid hydrolysate inflow tank.
2. The method for separating sugars and acids with reduced energy consumption according to claim 1 , wherein the electrolysis is performed using an electrolyzer in which a cathode tank and an anode tank are separated by an anion-exchange membrane, the second acid hydrolysate wherein the concentration of the acid solution is decreased due to the diffusion dialysis is added to the cathode tank and water or an acid solution is added to the anode tank.
3. The method for separating sugars and acids with reduced energy consumption according to claim 1 , wherein the concentration of the acid solution in the second acid hydrolysate is decreased by 50-80% as compared to the concentration of the acid solution in the first acid hydrolysate the due to the diffusion dialysis.
4. The method for separating sugars and acids with reduced energy consumption according to claim 1 , wherein the concentration of the sugars separated by the electrolysis is 0.1-200 g/L.
5. The method for separating sugars and acids with reduced energy consumption according to claim 1 , wherein the content of the final acid solution present in the sugars separated by the electrolysis is 1 wt % or lower.
6. The method for separating sugars and acids with reduced energy consumption according to claim 1 , wherein the acid solution separated by the electrolysis is used directly for the saccharification of biomass.
7. The method for separating sugars and acids with reduced energy consumption according to claim 1 , wherein a biofuel is produced by fermenting the sugars separated by the electrolysis.
8. The method for separating sugars and acids with reduced energy consumption according to claim 1 , wherein hydrogen gas and oxygen gas are produced during the electrolysis.
9. The method for separating sugars and acids with reduced energy consumption according to claim 1 , wherein the biomass is grass biomass, wood biomass, starch biomass, seaweed biomass or organic waste.
10. The method for separating sugars and acids with reduced energy consumption according to claim 1 , wherein the acid solution is sulfuric acid.
11. The method for separating sugars and acids with reduced energy consumption according to claim 1 , wherein the biomass is pretreated with the acid solution having an acid concentration of 1-80%.
12. The method for separating sugars and acids with reduced energy consumption according to claim 1 , wherein the separated sugar is one or more selected from a group consisting of a polysaccharide selected from a group consisting of cellulose, hemicellulose, chitin, chitosan and derivatives thereof; a monosaccharide selected from a group consisting of glucose, xylose, galactose, fructose, mannose and arabinose; and a dimer or an oligomer consisting of at least one monosaccharide selected from the group consisting of glucose, xylose, galactose, fructose, mannose and arabinose.
13. A method for separating sugars and acids with reduced energy consumption, comprising:
diffusively dialyzing a first acid hydrolysate obtained by saccharifying biomass with an acid solution, at 23-25° C. using a diffusion dialyzer equipped with an ion-exchange membrane, thereby preparing a second acid hydrolysate wherein the concentration of the acid solution comprised in the acid hydrolysate is decreased; and
electrolyzing the second acid hydrolysate using an electrolyzer by applying a voltage of 4-6 V at 38-42° C., thereby separating sugars from the acid solution;
wherein the diffusion dialysis is performed using the diffusion dialyzer in which an acid hydrolysate inflow tank and a water tank are separated by an anion-exchange membrane and the reaction is performed continuously as the first acid hydrolysate is added to the acid hydrolysate inflow tank and water is added to the water tank and,
wherein a mesh is provided at a center of the acid hydrolysate inflow tank.