Cathode active material of lithium secondary battery
The present invention relates to a cathode active material for a lithium secondary battery, and more particularly, to a cathode active material for a lithium secondary battery, which includes a core portion and a shell portion surrounding the core portion, in which a total content of cobalt in the core portion and the shell portion is 5 to 12 mol %, and the content of cobalt in the core portion and the shell portion is adjusted to be within a predetermined range. In the cathode active material precursor and the cathode active material for a secondary battery prepared using the same according to the present invention, optimal capacity of a lithium secondary battery may be increased by adjusting the cobalt content in the particles of the cathode active material, and life characteristics may be enhanced by improving stability.
1. A cathode active material for a lithium secondary battery, the cathode active material comprising:
a core portion and a shell portion surrounding the core portion, that together form a particle,
wherein a total content of cobalt in the core portion and the shell portion is 5 to 12 mol %, and
wherein the content of cobalt in the entire particle is W, the content of cobalt in the shell portion is 0.2 W to 1.0 W,
wherein the particle comprises nickel and the content of nickel in the shell portion is 60 mol % or more,
wherein the particle comprises cobalt and the content of cobalt in the shell portion is more than 20 mol %,
wherein when the particle comprises manganese, the content of manganese in the shell portion is less than 20 mol %,
wherein a diameter of the entire particle D is 1 μm to 25 μm,
wherein a thickness of the shell portion is adjusted within a range of 0.01 D to 0.3 D relative to the diameter of the entire particle D by adjusting the total content of cobalt in the core portion and the shell portion to 5 to 12 mol %, and
wherein the cathode active material for a lithium secondary battery is represented by Chemical Formula 1 below:
Li a Ni x Co y Mn z M 1-x-y-z O 2 [Chemical Formula1]
where 0.9≤a≤1.3, 0.7≤x<1.0, 0.05≤y≤0.12, 0.0≤z≤0.3, and 0.0≤1-x-y-z≤0.3, wherein M is one or more elements selected from among B, Ba, Ce, Cr, F, Mg, Al, Cr, V, Ti, Fe, Zr, Zn, Si, Y, Nb, Ga, Sn, Mo, W, P, Sr, Ge, and Cu.
2. The cathode active material of claim 1 , wherein a density of cobalt in the core portion and a density of cobalt in the shell portion are not equal.