Low sulfur marine fuel compositions
Heavy hydrotreated gas oil compositions are provided, along with marine fuel oil compositions and marine gas oil compositions that include a substantial portion of a hydrotreated heavy atmospheric gas oil. The hydrotreated heavy atmospheric gas oil can correspond to a gas oil with a relatively low viscosity and an elevated paraffin content in a narrow boiling range which results in a relatively high cloud point and/or pour point.
1. A method for forming a marine gas oil composition, comprising:
blending a first fraction comprising a T10 distillation point of 300° C. or more, a T90 distillation point of 440° C. or less, a kinematic viscosity at 40° C. of 10.5 cSt to 16 cSt, a sulfur content of 0.03 wt % to 0.6 wt %, a pour point of 15° C. or more, a cloud point of 18° C. or more, and a paraffin content of 22 wt % or more,
with one or more additional fractions having a kinematic viscosity at 40° C. of 2.0 cSt or less, a cloud point of −20° C. or less, a pour point of −40° C. or less, and an aromatics content of 20 wt % or more,
to form a marine gas oil composition comprising a sulfur content of 0.05 wt % to 0.6 wt % relative to a weight of the marine gas oil composition, the marine gas oil composition comprising at least 30 wt % of the first fraction and at least 10 wt % of the one or more additional fractions.
2. The method of claim 1 , wherein the marine gas oil composition further comprises 20 wt % or more of a hydrocracked gas oil, the hydrocracked gas oil comprising a kinematic viscosity at 40° C. of 4.0 cSt to 10 cSt, a cetane index of 45 or more, a pour point of 15° C. or less, and a cloud point of 18° C. or less.
3. The method of claim 2 , wherein the marine gas oil comprises 70 wt % or more of a combination of the first fraction and the hydrocracked gas oil.
4. The method of claim 1 , wherein the marine gas oil composition comprises a pour point of 9° C. or more; or wherein the marine gas oil composition comprises a cold filter plugging point of 15° C. to 20° C.; or a combination thereof.
5. The method of claim 1 , wherein the marine gas oil composition further comprises 100 wppm to 1000 wppm of a pour point depressant, a cold flow additive, or a combination thereof.
6. The method of claim 5 , wherein the marine gas oil composition comprises a pour point of −12° C. or less, or −18° C. or less; or wherein the marine gas oil composition comprises a cold filter plugging point of 5° C. to 15° C., or a combination thereof.
7. The method of claim 1 , wherein the first fraction comprises a wax end point of 30° C. to 45° C.; or wherein the first fraction comprises a cetane index of 50 or more; or wherein the first fraction comprises a sulfur content of 0.1 wt % to 0.6 wt %; or wherein the first fraction comprises a viscosity index of 80 or more; or a paraffins content of 30 wt % or more; or a combination thereof.
8. The method of claim 1 , wherein 40 wt % or more of the paraffins in the first fraction, relative to a weight of paraffins in the first fraction, comprise n-paraffins; or wherein the first fraction comprises 14 wt % or more n-paraffins relative to a weight of the composition; or a combination thereof.
9. The method of claim 1 , wherein the one or more additional fractions comprise an aromatics content of 50 wt % or more, or a cloud point of −50° C. or less, or a pour point of −60° C. or less, or a combination thereof.
10. The method of claim 1 , wherein at least one of the one or more additional fractions comprises i) a cloud point of −50° C. or less, ii) a pour point of −60° C. or less, iii) a kinematic viscosity at 40° C. of 1.0 cSt or less, iv) a cetane index of 25 or less, or v) a combination of two or more of i)-iv).
11. The method of claim 1 , wherein at least one of the one or more additional fractions comprises an aromatics content of 50 wt % or more.
12. The method of claim 1 , wherein the first fraction comprises a kinematic viscosity at 50° C. of 11.5 cSt or less.
13. A marine gas oil composition comprising:
at least 30 wt % of a first fraction comprising a T10 distillation point of 300° C. or more, a T90 distillation point of 440° C. or less, a kinematic viscosity at 40° C. of 10.5 cSt to 16 cSt, a sulfur content of 0.03 wt % to 0.6 wt %, a pour point of 15° C. or more, a cloud point of 18° C. or more, and a paraffin content of 22 wt % or more; and
at least 20 wt % of a hydrocracked gas oil comprising a kinematic viscosity at 40° C. of 4.0 cSt to 10 cSt, a cetane index of 45 or more, a pour point of 15° C. or less, and a cloud point of 18° C. or less,
the marine gas oil comprising 70 wt % or more of a combination of the first fraction and the hydrocracked gas oil,
the marine gas oil composition comprising a cetane index of 50 or more and a sulfur content of 0.05 wt % to 0.6 wt % relative to a weight of the marine gas oil composition.
14. The marine gas oil composition of claim 13 , wherein the marine gas oil composition comprises a pour point of 9° C. or more; or wherein the marine gas oil composition comprises a cold filter plugging point of 15° C. to 20° C.; or a combination thereof.
15. The marine gas oil composition of claim 13 , wherein the marine gas oil composition further comprises at least 10 wt % of one or more additional fractions, the one or more additional fractions comprising a kinematic viscosity at 40° C. of 2.0 cSt or less, a cloud point of −20° C. or less, a pour point of −40° C. or less, and an aromatics content of 20 wt % or more.
16. The marine gas oil composition of claim 15 , wherein the marine gas oil composition further comprises 100 wppm to 1000 wppm of a pour point depressant, a cold flow additive, or a combination thereof, and
wherein the marine gas oil composition comprises a pour point of −12° C. or less, or −18° C. or less, or wherein the marine gas oil composition comprises a cold filter plugging point of 5° C. to 15° C., or a combination thereof.
17. The marine gas oil composition of claim 15 , wherein the one or more additional fractions comprise an aromatics content of 50 wt % or more, or a cloud point of −50° C. or less, or a pour point of −60° C. or less, or a combination thereof.
18. The marine gas oil composition of claim 15 , wherein at least one of the one or more additional fractions comprises i) a cloud point of −50° C. or less, ii) a pour point of −60° C. or less, iii) a kinematic viscosity at 40° C. of 1.0 cSt or less, iv) a cetane index of 25 or less, or v) a combination of two or more of i)-iv).
19. The marine gas oil composition of claim 13 , wherein the first fraction comprises a wax end point of 30° C. to 45° C.; or wherein the first fraction comprises a cetane index of 50 or more (or 60 or more); or wherein the first fraction comprises a sulfur content of 0.1 wt % to 0.6 wt %; or wherein the first fraction comprises a viscosity index of 80 or more; or a paraffins content of 30 wt % or more; or a combination thereof.
20. The marine gas oil composition of claim 13 , wherein 40 wt % or more of the paraffins in the first fraction, relative to a weight of paraffins in the first fraction, comprise n-paraffins; or wherein the first fraction comprises 14 wt % or more n-paraffins relative to a weight of the composition; or a combination thereof.
21. The marine gas oil composition of claim 13 , wherein the marine gas oil has a clear and bright appearance.
22. The marine gas oil of claim 13 , wherein the first fraction comprises a kinematic viscosity at 50° C. of 11.5 cSt or less.