Lighting device
A lighting device is specified. The lighting device comprises a phosphor having the general molecular formula (MA) a (MB) b (MC) c (MD) d (TA) e (TB) f (TC) g (TD) h (TE) i (TF) j (XA) k (XB) l (XC) m (XD) n :E. In this case, MA is selected from a group of monovalent metals, MB is selected from a group of divalent metals, MC is selected from a group of trivalent metals, MD is selected from a group of tetravalent metals, TA is selected from a group of monovalent metals, TB is selected from a group of divalent metals, TC is selected from a group of trivalent metals, TD is selected from a group of tetravalent metals, TE is selected from a group of pentavalent elements, TF is selected from a group of hexavalent elements, XA is selected from a group of elements which comprises halogens, XB is selected from a group of elements which comprises O, S and combinations thereof, XC=N and XD=C and E=Eu, Ce, Yb and/or Mn. The following furthermore hold true: a+b+c+d=t; e+f+g+h+i+j=u; k+l+m+n=v; a+2b+3c+4d+e+2f+3g+4h+5i+6j−k−2l−3m−4n=w; 0.8≤t≤1; −3.5≤u≤4; 3.5≤v≤4; (−0.2)≤w≤0.2 and 0≤m<0.875 v and/or v≥l>0.125 v.
1. A lighting device comprising a phosphor having the general molecular formula:
(MA) a (MB) b (TA) e (TB) f (TC) g (TD) h (XB) l (XC) m :E,
wherein
MA is selected from a group of monovalent metals which comprises Li, Na, K, Rb, Cs, Cu, Ag and combinations thereof,
MB is selected from a group of divalent metals which comprises Mg, Ca, Sr, Ba, Zn, Mn, Eu, Yb, Ni, Fe, Co and combinations thereof,
TA is selected from a group of monovalent metals which comprises Li, Na, Cu, Ag and combinations thereof,
TB is selected from a group of divalent metals which comprises Mg, Zn, Mn, Eu, Yb, Ni and combinations thereof,
TC is selected from a group of trivalent metals which comprises B, Al, Ga, In, Y, Fe, Cr, Sc, rare earths and combinations thereof,
TD is selected from a group of tetravalent metals which comprises Si, Ge, Sn, Mn, Ti, Zr, Hf, Ce and combinations thereof,
XB is selected from a group of elements which comprises O, S and combinations thereof,
XC=N
E=Eu, Ce, Yb and/or Mn
a+b=t
e+f+g+h=u
l+m=v
a+2b+e+2f+3g+4h−2l−3m=w
0.8≤t≤1
3.5≤u≤4
3.5≤v≤4
(−0.2)≤w≤0.2 and
0≤m<0.875 v and/or v≥l>0.125 v.
2. The lighting device as claimed in claim 1 , wherein the phosphor has a crystal structure in which TA, TB, TC and/or TD are surrounded by XB and/or XC and the resultant structural units are linked via common corners and edges to form a three-dimensional spatial network having cavities or channels and MA and/or MB are/is arranged in the cavities or channels.
3. The lighting device as claimed in claim 1 , wherein the following hold true for the phosphor:
a+b=1
e+f+g+h=4
l+m=4
a+2b+e+2f+3g+4h−2l−3m=0 and
m<3.5.
4. The lighting device as claimed in claim 1 , wherein
MB is selected from a group of divalent metals which comprises Mg, Ca, Sr, Ba, Eu and combinations thereof,
TA is selected from a group of monovalent metals which comprises Li, Na, Cu, Ag and combinations thereof,
TC is selected from a group of trivalent metals which comprises B, Al, Ga, In and combinations thereof,
TD is selected from a group of tetravalent metals which comprises Si, Ge, Sn, Mn, Ti and combinations thereof, and
XB=O.
5. The lighting device as claimed in claim 1 , wherein the phosphor has the general molecular formula (MA) a (MB) b (TA) e (TD) h (XB) l (XC) m :E, wherein
MA is selected from a group of monovalent metals which comprises Li, Na, K, Rb, Cs, Cu, Ag and combinations thereof,
MB is selected from a group of divalent metals which comprises Mg, Ca, Sr, Ba, Zn, Mn, Eu, Yb, Ni, Fe, Co and combinations thereof,
TA is selected from a group of monovalent metals which comprises Li, Na, Cu, Ag and combinations thereof,
TD is selected from a group of tetravalent metals which comprises Si, Ge, Sn, Mn, Ti, Zr, Hf, Ce and combinations thereof,
XB is selected from a group of elements which comprises O, S and combinations thereof,
XC=N,
E=Eu, Ce, Yb and/or Mn,
a+b=t,
e+h=u,
l+m=v,
a+2b+e+4h−2l−3m=w
0.8≤t≤1
3.5≤u≤4
3.5≤v≤4
(−0.2)≤w≤0.2
0≤m<0.875 v and/or v≥l>0.125 v.
6. The lighting device as claimed in claim 5 , wherein
MA is selected from a group of monovalent metals which comprises Li, Na, K, Rb, Cs and combinations thereof,
MB is selected from a group of divalent metals which comprises Mn, Eu, Yb and combinations thereof,
TA is selected from a group of monovalent metals which comprises Li, Na and combinations thereof,
TD is selected from a group of tetravalent metals which comprises Si, Ge, Sn, Mn, Ti and combinations thereof, and
XB=O.
7. The lighting device as claimed in claim 5 , wherein
a+b=1;
e+h=4;
l+m=4;
a+2b+e+4h−2l−3m=0 and m<3.5 or l>0.5.
8. The lighting device as claimed in claim 1 , wherein phosphor has the general molecular formula (MA) a (MB) b (TA) e (TC) g (TD) h (XB) l (XC) m :E wherein
MA is selected from a group of monovalent metals which comprises Li, Na, K, Rb, Cs, Cu, Ag and combinations thereof,
MB is selected from a group of divalent metals which comprises Mg, Ca, Sr, Ba, Zn, Mn, Eu, Yb, Ni, Fe, Co and combinations thereof,
TA is selected from a group of monovalent metals which comprises Li, Na, Cu, Ag and combinations thereof,
TC is selected from a group of trivalent metals which comprises B, Al, Ga, In, Y, Fe, Cr, Sc, rare earths and combinations thereof,
TD is selected from a group of tetravalent metals which comprises Si, Ge, Sn, Mn, Ti, Zr, Hf, Ce and combinations thereof,
XB is selected from a group of elements which comprises O, S and combinations thereof,
E=Eu, Ce, Yb and/or Mn
XC=N
a+b=t
e+g+h=u
l+m=v
a+2b+e+3g+4h−2l−3m=w
0.8≤t≤1
3.5≤u≤4
3.5≤v≤4
(−0.2)≤w≤0.2 and 0≤m<0.875 v and/or v≥l>0.125 v.
9. The lighting device as claimed in claim 8 , wherein
MB is selected from a group of divalent metals which comprises Mg, Ca, Sr, Ba, Eu and combinations thereof,
TC is selected from a group of trivalent metals which comprises B, Al, Ga and combinations thereof,
TD is selected from a group of tetravalent metals which comprises Si, Ge and combinations thereof,
XB=O,
a+b=1
e+g+h=4
l+m=4
a+2b+e+3g+4h−2l−3m=0 and m<3.5 or l>0.5.
10. The lighting device as claimed in claim 8 , wherein
MA is selected from a group of monovalent metals which comprises Li, Na, K and combinations thereof,
MB is selected from a group of divalent metals which comprises Mg, Ca, Sr, Ba, Eu and combinations thereof,
TA=Li,
TC=Al,
TD=Si,
XB=O,
a+b=1
e+g+h=4
l+m=4
a+2b+e+3g+4h−2l−3m=0 and m<3.5 or l>0.5.
11. The lighting device as claimed in claim 1 , wherein the lighting device is a conversion light-emitting diode, comprising
a primary radiation source configured to emit an electromagnetic primary radiation during operation of the diode,
a conversion element comprising the phosphor, said conversion element being arranged in the beam path of the electromagnetic primary radiation, wherein the phosphor is configured at least partly to convert the electromagnetic primary radiation into an electromagnetic secondary radiation during operation of the lighting device.