Viscosity index improver with improved shear-resistance and solubility after shear
The invention relates to a poly alkyl(meth)acrylate polymer comprising a combination of polybutadiene-based monomers having different average molecular weight, lubricant compositions comprising the polymer, a method for manufacturing the polymer and the use of the polymer as a viscosity index improver in a lubricating oil composition.
1. A poly alkyl(meth)acrylate polymer, obtained by polymerizing a monomer composition comprising:
(a) from 15 to 35% by weight of one or more esters of a (meth)acrylic acid and a first hydroxylated hydrogenated polybutadiene having a number-average molecular weight of from 500 to less than 3,000 g/mol, based on the total weight of the monomer composition;
(b) from 1 to 15% by weight of one or more esters of a (meth)acrylic acid and a second hydroxylated hydrogenated polybutadiene having a number-average molecular weight of from 3,000 to 10,000 g/mol, based on the total weight of the monomer composition;
(c) from 5 to 90% by weight of one or more C 1 -C 30 alkyl(meth)acrylates, based on the total weight of the monomer composition,
wherein the total weight of monomers (a) and (b) is at least 25% by weight, based on the total weight of the monomer composition, and
wherein the total weight of monomers (a), (b) and (c) is at least 35% by weight, based on the total weight of the monomer composition.
2. The polyalkyl(meth)acrylate polymer according to claim 1 , wherein the weight ratio of component (a) to component (b) is 1 or more, and the polyalkyl(meth)acrylate polymer has a molar degree of branching f branch of 1 to 4.5 mol %.
3. The polyalkyl(meth)acrylate polymer according to claim 1 , wherein the first hydroxylated hydrogenated polybutadiene has a number-average molecular weight of from 1,000 to 2,750 g/mol, and the second hydroxylated hydrogenated polybutadiene has a number-average molecular weight of 3,500 to 7,000 g/mol.
4. The polyalkyl(meth)acrylate polymer according to claim 1 , wherein the monomer composition comprises as component (a) from 15 to 35% by weight, of one or more esters of (meth)acrylic acid and the first hydroxylated hydrogenated polybutadiene, based on the total weight of the monomer composition, and as component (b) from 3 to 15% by weight of one or more esters of (meth)acrylic acid and the second hydroxylated hydrogenated polybutadiene, based on the total weight of the monomer composition.
5. The polyalkyl(meth)acrylate polymer according to claim 1 , wherein the monomer composition comprises as component (c) a mixture of one or more C 1-4 alkyl (meth)acrylates and one or more C 10-18 alkyl (meth)acrylates.
6. The polyalkyl(meth)acrylate polymer according to claim 1 , wherein the monomer composition comprises as component (d) from 0.1 to 65% by weight of one or more monomers having from 8 to 17 carbon atoms selected from a group consisting of styrene and substituted styrenes having an alkyl substituent in the side chain, based on the total weight of the monomer composition.
7. The polyalkyl(meth)acrylate polymer according to claim 1 , wherein the monomer composition comprises
(a) from 20 to 30% by weight of one or more esters of (meth)acrylic acid and a first hydroxylated hydrogenated polybutadiene having a number-average molecular weight of from 1,000 to 2,750 g/mol, based on the total weight of the monomer composition;
(b) from 2 to 10% by weight of one or more esters of (meth)acrylic acid and a second hydroxylated hydrogenated polybutadiene having a number-average molecular weight of from 3,500 to 7,000 g/mol, based on the total weight of the monomer composition;
(c) from 7 to 68% by weight of one or more C 1-4 alkyl (meth)acrylates and from 0.2 to 8% by weight of one or more C.sub.10-18 alkyl (meth)acrylates, based on the total weight of the monomer composition; and (d) from 0.2 to 65% by weight of one or more styrene monomers having from 8 to 17 carbon atoms, based on the total weight of the monomer composition; and
(d) from 0.2 to 65% by weight of one or more monomers having 8 to 17 carbon atoms selected from the group consisting of styrene and substituted styrenes having an alkyl substituent in the side chain based on the total weight of the monomer composition, and the polyalkyl(meth)acrylate polymer has a molar degree of branching f branch of 1 to 4.5 mol %.
8. The polyalkyl(meth)acrylate polymer according to claim 1 , having a weight average molecular weight (M w ) of 15,000 to 350,000 g/mol.
9. A method for manufacturing a polyalkyl(meth)acrylate polymer, the method comprising the steps of: (a) providing a monomer composition according to claim 1 ; and (b) initiating radical polymerization in the monomer composition.
10. An additive for a lubricant composition for improving the viscosity index and the shear-resistance of the lubricant, the additive comprising the polyalkyl(meth)acrylate polymer according to claim 1 .
11. A composition comprising: (a) a base oil; and (b) a polyalkyl(meth)acrylate polymer according to claim 1 .
12. The composition according to claim 11 , wherein the base oil is a polyalphaolefin base oil, an API Group III base oil, a mixture of a polyalphaolefin base oil with an API Group III base oil, or a mixture of API Group III base oils.
13. The composition according to claim 11 , comprising 40 to 80% by weight base oil, and from 20 to 60% by weight of the polymer, based on the total weight of the composition.
14. The composition according to claim 11 , comprising from 50 to 99.5% by weight base oil, and from 0.5 to 50% by weight of the polymer, based on the total weight of the composition.
15. The polyalkyl(meth)acrylate polymer according to claim 1 , wherein the weight ratio of component (a) to component (b) is from 3.5 to 6.
16. The polyalkyl(meth)acrylate polymer according to claim 1 , wherein the first hydroxylated hydrogenated polybutadiene has a number-average molecular weight of from 1,750 to 2,250 g/mol, and the second hydroxylated hydrogenated polybutadiene has a number-average molecular weight of from 4,500 to 5,000 g/mol.
17. The polyalkyl(meth)acrylate polymer according to claim 1 , wherein the monomer composition comprises as component (a) from 20 to 30% by weight of one or more esters of (meth)acrylic acid and the first hydroxylated hydrogenated polybutadiene, based on the total weight of the monomer composition, and as component (b) from 4 to 10% by weight of one or more esters of (meth)acrylic acid and the second hydroxylated hydrogenated polybutadiene, based on the total weight of the monomer composition.
18. The polyalkyl(meth)acrylate polymer according to claim 1 , wherein the monomer composition comprises as component (d) from 0.2 to 60% by weight of one or more styrene monomers having from 8 to 17 carbon atoms, based on the total weight of the monomer composition.
19. The polyalkyl(meth)acrylate polymer according to claim 1 , having a weight average molecular weight (M w ) of from 60,000 to 150,000 g/mol.
20. The composition according to claim 11 , comprising from 50 to 70% by weight base oil, and from 30 to 50% by weight of the polymer, based on the total weight of the composition.