Catalytic system and process for the production of light olefins from ethanol
The present invention relates to a catalytic system for the preparation of light olefins through the dehydration of alcohols, including at least one catalyst and at least one co-catalyst, wherein the catalyst is selected from among catalysts for the catalytic dehydration of ethanol and with the co-catalyst selected from among oxy-ketonization reaction catalysts, wherein the catalyst:co-catalyst mass ratio is within a range of 0.5:0.125 to 2:10, and preferably within a range of 1:0.25 to 1:5.
1. A catalytic system for the preparation of light olefins from ethanol, which comprises at least one ethanol-dehydration catalyst and at least one acetaldehyde-to-acetone catalyst,
wherein the ethanol-dehydration catalyst:acetaldehyde-to-acetone catalyst mass ratio is within a range of 1:0.5 to 1:5,
wherein the catalytic system exhibits an ethene selectivity of at least 97.2%,
wherein the ethanol-dehydration catalyst comprises gamma alumina,
wherein the acetaldehyde-to-acetone catalyst comprises at least one of Y 2 O 3 , ZrO 2 , and La-ZrO 2 , and
wherein the catalytic system, when present during a continuous operation of a preparation of light olefins, exhibits a reaction conversion of 99%, without deactivation, for a period more than five times longer than a useful life of the ethanol dehydration catalyst when used alone.
2. The catalytic system as recited in claim 1 , wherein the catalytic system is a physical mixture of the ethanol-dehydration catalyst and acetaldehyde-to-acetone catalyst.
3. The catalytic system as recited in claim 1 , wherein the catalytic system is a physical mixture of the ethanol-dehydration catalyst with the acetaldehyde-to-acetone catalyst presented as pellets of each one of the components in isolation, or a pellet made from a mixture of the two components laid out in sequential layers or beds, mixed or not, or in the form of powder, wherein the particles contain both the ethanol-dehydration catalyst and the acetaldehyde-to-acetone catalyst or individual particles of each one of the components.
4. The catalytic system as recited in claim 1 , wherein the ethanol-dehydration catalyst:acetaldehyde-to-acetone catalyst mass ratio is within a range of 1:0.5 to 1:3.
5. A process for the production of light olefins from ethanol, the process comprising contacting the catalytic system as recited in claim 1 with a flow of alcohol, hydrated or not, in a reactor, at a temperature between 200° C. and 800° C. and a pressure between 1 bar and 60 bar.
6. The process as recited in claim 5 , wherein temperature variations occur between 360° C. and 470° C.
7. The process as recited in claim 5 , wherein pressure variations occur between 1 bar and 20 bar.
8. The process as recited in claim 5 , wherein the alcohol is a hydrated alcohol having a water:alcohol mass ratio of between 0.25:1 and 5:1.
9. The process as recited in claim 5 , wherein the reaction occurs in a Plug Flow Reactor (PFR), fixed or fluid bed, batch or a Continuous-Stirred Tank Reactor (CSTR), being adiabatic or not.
10. The process as recited in claim 5 , wherein the catalytic system operates continuously, maintaining the reaction conversion at 99%, without deactivation, for a period more than five times longer than the useful life of the dehydration catalyst when used alone.
11. The process as recited in claim 5 , wherein the hydrated alcohol has a water:alcohol mass ratio of between 1:1 and 3:1.