IP Library › Granted Patent US 10,551,732
Granted Patent B2
US 10,551,732 · App. 16/220,351 · Granted Feb 4, 2020

Extreme ultraviolet mask blank production system with thin absorber and manufacturing system therefor

Inventors: Vinayak Vishwanath Hassan (Santa Clara, CA); Majeed A. Foad (Sunnyvale, CA); Cara Beasley (Scotts Valley, CA); Ralf Hofmann (Soquel, CA)
Assignee: Applied Materials, Inc.
G03F1/24G03F1/22G03F1/54
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Quick Facts
Patent No.
US 10,551,732
App. No.
16/220,351
Granted
Feb 4, 2020
Kind
B2
Abstract

An extreme ultraviolet (EUV) mask blank production system includes: a substrate handling vacuum chamber for creating a vacuum; a substrate handling platform, in the vacuum, for transporting an ultra-low expansion substrate loaded in the substrate handling vacuum chamber; and multiple sub-chambers, accessed by the substrate handling platform, for forming an EUV mask blank includes: a multi-layer stack, formed above the ultra-low expansion substrate, for reflecting an extreme ultraviolet (EUV) light, and an absorber layer, formed above the multi-layer stack, for absorbing the EUV light at a wavelength of 13.5 nm includes the absorber layer has a thickness of less than 80 nm and less than 2% reflectivity.

Claims (24)

1. An extreme ultraviolet (EUV) mask blank comprising:

an ultra-low expansion substrate;

a multi-layer stack over the ultra-low expansion substrate; and

an absorber layer, over the multi-layer stack, with a thickness of less than 80 nm and less than 2% reflectivity of an extreme ultraviolet (EUV) light at a wavelength of 13.5 nm, wherein the absorber layer includes a single layer of Nickel (Ni), Platinum (Pt), Silver (Ag), Zinc (Zn), Tin (Sn), Gold (Au), Lead (Pb), Indium (In), Hafnium (Hf), Cadmium (Cd), Bismuth (Bi), Antimony (Sb), or Tellurium (Te); and

an anti-reflective coating on the absorber layer, the anti-reflective coating selected from

tantalum oxynitride and tantalum boron oxide.

2. The extreme ultraviolet (EUV) mask blank of claim 1 , further comprising a capping layer formed on the multi-layer stack, the capping layer comprising at least one material selected from the group consisting of titanium nitride, boron carbide, and silicon carbide.

3. The extreme ultraviolet (EUV) mask blank of claim 1 , further comprising an additional multi-layer stack formed between the ultra-low expansion substrate and the absorber layer.

4. The extreme ultraviolet (EUV) mask blank of claim 1 , further comprising an additional multi-layer stack formed directly on a planarization layer and the multi-layer stack formed on the additional multi-layer stack.

5. The extreme ultraviolet (EUV) mask blank of claim 1 , wherein the absorber layer includes a single layer of Tin (Sn).

6. The extreme ultraviolet (EUV) mask blank of claim 1 , wherein the absorber layer includes a single layer of Lead (Pb).

7. The extreme ultraviolet (EUV) mask blank of claim 1 , wherein the absorber layer includes a single layer of Bismuth (Bi), Antimony (Sb), or Tellurium (Te).

8. The extreme ultraviolet (EUV) mask blank of claim 1 , wherein the absorber layer is in a range of 10 nm to 83 nm thick.

9. An extreme ultraviolet (EUV) mask blank system comprising:

an ultra-low expansion substrate;

a multi-layer stack over the ultra-low expansion substrate; and

an absorber layer, over the multi-layer stack, with a thickness of less than 80 nm and less than 2% reflectivity of an extreme ultraviolet (EUV) light at a wavelength of 13.5 nm, wherein the absorber layer includes a single layer of Nickel (Ni), Platinum (Pt), Silver (Ag), Zinc (Zn), Tin (Sn), Gold (Au), Lead (Pb), Indium (In), Hafnium (Hf), Cadmium (Cd), Bismuth (Bi), Antimony (Sb), or Tellurium (Te); and

a capping layer formed on the multi-layer stack, the capping layer comprising at least one material selected from the group consisting of titanium nitride, boron carbide, and silicon carbide.

10. The extreme ultraviolet (EUV) mask blank of claim 9 , further comprising an additional multi-layer stack formed between the ultra-low expansion substrate and the absorber layer.

11. The extreme ultraviolet (EUV) mask blank of claim 9 , further comprising an additional multi-layer stack formed directly on a planarization layer and the multi-layer stack formed on the additional multi-layer stack.

12. The extreme ultraviolet (EUV) mask blank of claim 9 , wherein the absorber layer includes a single layer of Tin (Sn).

13. The extreme ultraviolet (EUV) mask blank of claim 9 , wherein the absorber layer includes a single layer of Lead (Pb).

14. The extreme ultraviolet (EUV) mask blank of claim 9 , wherein the absorber layer includes a single layer of Bismuth (Bi), Antimony (Sb), or Tellurium (Te).

15. The extreme ultraviolet (EUV) mask blank of claim 9 , wherein the absorber layer is in a range of 10 nm to 83 nm thick.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 23, 2019
From: HASSAN, VINAYAK VISHWANATH; FOAD, MAJEED A.; BEASLEY, CARA; HOFMANN, RALF
To: APPLIED MATERIALS, INC.
Reel/Frame 050461/0118 →
Continuity (4)
Continuation 15438248 · Feb 21, 2017
Continuation 14620114 · Feb 11, 2015
Provisional Application 62023496 · Jul 11, 2014
Related Publication 20190130731A1 · May 2, 2019