IP Library Granted Patent US 11,861,437
Granted Patent B2
US 11,861,437 · App. 16/223,021 · Granted Jan 2, 2024

Chemical and physical sensing with a reader and RFID tags

Inventors: Timothy Manning Swager (Newton, MA); Joseph Michael Azzarelli (Cambridge, MA); Jens Bomholdt Ravnsbæk (Fredericia, DK); Katherine Andrea Mirica (Waltham, MA)
Assignee: Massachusetts Institute of Technology
G06K19/0716G01N33/0075G06K19/0717G06K19/0723G06K19/07749G06K19/07788G08C17/02G01N27/04G06F3/014
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Quick Facts
Patent No.
US 11,861,437
App. No.
16/223,021
Granted
Jan 2, 2024
Kind
B2
Abstract

A method of detecting a stimulus can include detecting an output from a radio frequency identification tag including a sensor. A smartphone-based sensing strategy can use chemiresponsive nanomaterials integrated into the circuitry of commercial Near Field Communication tags to achieve non-line-of-sight, portable, and inexpensive detection and discrimination of gas phase chemicals (e.g., ammonia, hydrogen peroxide, cyclohexanone, and water) at part-per-thousand and part-per-million concentrations.

Claims (15)

1. A method of detecting a stimulus comprising detecting an output from a radio frequency device having a circuit and including a sensor portion and a chemiresponsive sensor material, the chemiresponsive sensor material closing the circuit, the sensor portion configured to change a detectable property of the circuitry when the stimulus contacts or interacts with the radio frequency device, wherein the detectable property change alters the output of the radio frequency device.

2. The method of claim 1 , wherein the stimulus includes an aldehyde.

3. The method of claim 1 , wherein the stimulus includes an ester.

4. The method of claim 1 , wherein the stimulus includes an alkyl group.

5. The method of claim 1 , wherein the stimulus includes a chemical relevant to occupational safety.

6. The method of claim 1 , wherein the stimulus includes a mold.

7. The method of claim 1 , wherein the stimulus includes an environmental pollutant.

8. The method of claim 1 , wherein the stimulus includes light.

9. The method of claim 1 , wherein the stimulus includes a biologically relevant analyte.

10. The method of claim 1 , wherein the stimulus includes molecules found in a biologically-relevant sample.

11. The method of claim 1 , wherein the sensor material include a sensing material selected from the group consisting of a metal, an organic material, a dielectric material, a semiconductor material, a polymeric material, a biological material, a nanowire, a semiconducting nanoparticle, a nanotube, a nanofiber, a carbon fiber, a carbon particle, carbon paste, or conducting ink, organic electronics materials, doped conjugated polymers, inorganic materials, biological molecule receptors, cells, antibodies, aptamers, nucleic acids, functionalized biological molecules, and combinations thereof.

12. A tag for detecting a stimulus comprising a radio frequency device having a circuit and including a sensor portion and a sensor material, the sensor material closing the circuit, the sensor portion configured to change a detectable property of the circuitry when the radio frequency device contacts or interacts with the stimulus, wherein the detectable property change alters an output of the radio frequency device, wherein the sensor portion includes a circuit, and wherein the sensor portion is configured to activate the circuit or deactivate the circuit when contacted or having interacted with the stimulus.

13. A system for detecting a stimulus comprising a radio frequency device having a circuit and including a sensor portion and a chemiresponsive sensor material, the chemiresponsive sensor material closing the circuit, the sensor portion configured to change a detectable property of the circuitry when the radio frequency device contacts or interacts with the stimulus, wherein the detectable property change alters an output of the radio frequency device, and a detector detecting the output from the radio frequency device.

14. The tag of claim 12 , wherein the sensor material include a chemiresponsive sensing material selected from the group consisting of a metal, an organic material, a dielectric material, a semiconductor material, a polymeric material, a biological material, a nanowire, a semiconducting nanoparticle, a nanotube, a nanofiber, a carbon fiber, a carbon particle, carbon paste, or conducting ink, organic electronics materials, doped conjugated polymers, inorganic materials, biological molecule receptors, cells, antibodies, aptamers, nucleic acids, functionalized biological molecules, and combinations thereof.

15. The system of claim 13 , wherein the sensor material include a sensing material selected from the group consisting of a metal, an organic material, a dielectric material, a semiconductor material, a polymeric material, a biological material, a nanowire, a semiconducting nanoparticle, a nanotube, a nanofiber, a carbon fiber, a carbon particle, carbon paste, or conducting ink, organic electronics materials, doped conjugated polymers, inorganic materials, biological molecule receptors, cells, antibodies, aptamers, nucleic acids, functionalized biological molecules, and combinations thereof.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 20, 2020
From: SWAGER, TIMOTHY MANNING; AZZARELLI, JOSEPH MICHAEL; RAVENSBAEK, JENS BOMHOLDT; MIRICA, KATHERINE ANDREA
To: MASSACHUSETTS INSTITUTE OF TECHNOLOGY
Reel/Frame 052436/0523 →
CONFIRMATORY LICENSE Recorded Apr 3, 2019
From: MASSACHUSETTS INSTITUTE OF TECHNOLOGY
To: NATIONAL SCIENCE FOUNDATION
Reel/Frame 048788/0551 →
Continuity (4)
Continuation 15426027 · Feb 6, 2017
Continuation 14528856 · Oct 30, 2014
Provisional Application 61897613 · Oct 30, 2013
Related Publication 20190340480A1 · Nov 7, 2019