Multi-functional flow modifier for chemical coating compositions
A multi-functional flow modifier that also serves as a wetting agent, gloss control additive, and rheology modifier is contemplated. The flow modifier itself is a mixture of polyurethane masterbatch and hydroxyl acrylic resin (free from any styrene components/resins), curatives, anti-corrosion pigments, degassers, and anti-oxidants. The flow modifier may be introduced to finished coating compositions by way of a silica carrier.
1. A multi-functional, flow additive composition comprising:
70 to 80 wt. % of hydroxyl acrylic resin that is free from styrene;
5.0 to 20 wt. % of a polyurethane masterbatch including a triazine-based phenol cured by a blocked cycloaliphatic, aliphatic, or aromatic polyisocyanate;
1.0 to 2.0 wt. % of a curative, 0.5 to 5.0 wt. % of an anti-corrosion pigment;
0.5 to 5.0 wt. % of a degassing agent;
0.5 to 5.0 wt. % of an antioxidant;
0.01 to 5.0 wt. % of a combination of polyethylene and polyester hydroxyl resins; and
wherein the curative is selected so that it is not effective to harden the flow additive composition.
2. The flow additive composition according to claim 1 wherein the flow additive composition further comprises 0.001 to 0.025 wt. % of 12-hydroxy-9-cis-octadecenoic acid and 0.004 to 0.040 wt. % of glass flakes.
3. The flow additive composition according to claim 1 wherein the flow additive composition is provided on a silica carrier.
4. The flow additive composition according to claim 3 wherein a ratio of silica carrier to flow additive composition is provided at between 1:5 and 1:4.
5. The flow additive composition according to claim 4 wherein the silica carrier is selected from the group consisting of: (3-aminopropyl) trimethoxysilane, silicon dioxide, and combinations thereof.
6. The flow additive composition according to claim 4 wherein the flow additive composition is provided as particles each having a size of less than 5 micrometers.
7. The flow additive composition according to claim 6 wherein the particles each have a size of greater than 100 nanometers.
8. The flow additive composition according to claim 1 wherein the polyurethane masterbatch also includes a secondary triazine-based component and wherein the polyurethane masterbatch is cured by a blocked aliphatic polyisocyanate.
9. A chemical coating composition comprising at least one finished coating component provided at a weight ratio of 98 parts or more of the finished coating component and between 0.05 to 2 parts of the flow additive composition of claim 1 .
10. The chemical coating composition of claim 9 wherein the finished coating component includes a thermosetting resin and at least one additive selected from the group consisting of: 12-hydroxy-9-cis-octadecenoic acid, glass flakes, tetramethoxy glycoluril, pigments, waxes, hardening catalysts, and any combination of two or more thereof.
11. The chemical coating composition of claim 10 wherein the finished coating component forms a fusion powder coating film when the chemical coating composition is cured.
12. The chemical coating composition according to claim 9 wherein the finished coating component includes a resin and a liquid carrier that is removed from a final, coating film when the chemical coating composition is cured.